scholarly journals A dissymmetric [Gd2] coordination molecular dimer hosting six addressable spin qubits

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Fernando Luis ◽  
Pablo J. Alonso ◽  
Olivier Roubeau ◽  
Verónica Velasco ◽  
David Zueco ◽  
...  
Keyword(s):  
Hyperfine Interactions ◽  
Magnetic Interaction ◽  
Building Blocks ◽  
Small Scale ◽  
Zero Field ◽  
Spin Qubits ◽  
Paramagnetic Resonance ◽  
Unequally Spaced ◽  
Complete Set ◽  
Resonant Transitions

AbstractArtificial magnetic molecules can host several spin qubits, which could then implement small-scale algorithms. In order to become of practical use, such molecular spin processors need to increase the available computational space and warrant universal operations. Here, we design, synthesize and fully characterize dissymetric molecular dimers hosting either one or two Gadolinium(III) ions. The strong sensitivity of Gadolinium magnetic anisotropy to its local coordination gives rise to different zero-field splittings at each metal site. As a result, the [LaGd] and [GdLu] complexes provide realizations of distinct spin qudits with eight unequally spaced levels. In the [Gd2] dimer, these properties are combined with a Gd-Gd magnetic interaction, sufficiently strong to lift all level degeneracies, yet sufficiently weak to keep all levels within an experimentally accessible energy window. The spin Hamiltonian of this dimer allows a complete set of operations to act as a 64-dimensional all-electron spin qudit, or, equivalently, as six addressable qubits. Electron paramagnetic resonance experiments show that resonant transitions between different spin states can be coherently controlled, with coherence times TM of the order of 1 µs limited by hyperfine interactions. Coordination complexes with embedded quantum functionalities are promising building blocks for quantum computation and simulation hybrid platforms.

Wafer-Level near Zero Field Spin Dependent Charge Pumping: Effects of Nitrogen on 4H-SiC MOSFETs

2020 ◽  
Vol 1004 ◽  
pp. 573-580
Author(s):  
Mark A. Anders ◽  
Patrick M. Lenahan ◽  
Jason T. Ryan
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Measurement System ◽  
Hyperfine Interactions ◽  
Zero Field ◽  
Wafer Level ◽  
Paramagnetic Resonance ◽  
Defect Identification ◽  
Charge Pumping ◽  
Similar Information ◽  
Electron Paramagnetic

In this work, we describe a new way to measure spin dependent charge capture events at MOSFET interfaces called near-zero-field spin dependent charge pumping (NZF SDCP) which yields similar information as conventional electron paramagnetic resonance. We find that NO anneals have a significant effect on the spectra obtained from 4H-SiC MOSFETs. We also likely resolve hyperfine interactions which are important for defect identification. Finally, we fully integrate a NZF SDCP measurement system into a wafer prober for high throughput applications.

scholarly journals Improving the gate fidelity of capacitively coupled spin qubits

2015 ◽  
Vol 1 (1) ◽  
Author(s):  
Xin Wang ◽  
Edwin Barnes ◽  
S Das Sarma
Keyword(s):  
Quantum Computing ◽  
Hyperfine Interactions ◽  
Building Blocks ◽  
Nuclear Spins ◽  
Spin Qubits ◽  
Capacitively Coupled ◽  
Single Qubit ◽  
Control Protocols ◽  
Qubit Gate ◽  
Charge Noise

AbstractCapacitively coupled semiconductor spin qubits hold promise as the building blocks of a scalable quantum computing architecture with long-range coupling between distant qubits. However, the two-qubit gate fidelities achieved in experiments to date have been severely limited by decoherence originating from charge noise and hyperfine interactions with nuclear spins, and are currently unacceptably low for any conceivable multi-qubit gate operations. Here, we present control protocols that implement two-qubit entangling gates while substantially suppressing errors due to both types of noise. These protocols are obtained by making simple modifications to control sequences already used in the laboratory and should thus be easy enough for immediate experimental realisation. Together with existing control protocols for robust single-qubit gates, our results constitute an important step toward scalable quantum computation using spin qubits in semiconductor platforms.

scholarly journals PyroMEMS as Future Technological Building Blocks for Advanced Microenergetic Systems

Micromachines ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 118
Author(s):  
Jean-Laurent Pouchairet ◽  
Carole Rossi
Keyword(s):  
Building Block ◽  
Building Blocks ◽  
Small Scale ◽  
Technological Evolution ◽  
Research Groups ◽  
Function Block ◽  
The Past ◽  
New Methods ◽  
Safety And Reliability ◽  
Electronically Controllable

For the past two decades, many research groups have investigated new methods for reducing the size and cost of safe and arm-fire systems, while also improving their safety and reliability, through batch processing. Simultaneously, micro- and nanotechnology advancements regarding nanothermite materials have enabled the production of a key technological building block: pyrotechnical microsystems (pyroMEMS). This building block simply consists of microscale electric initiators with a thin thermite layer as the ignition charge. This microscale to millimeter-scale addressable pyroMEMS enables the integration of intelligence into centimeter-scale pyrotechnical systems. To illustrate this technological evolution, we hereby present the development of a smart infrared (IR) electronically controllable flare consisting of three distinct components: (1) a controllable pyrotechnical ejection block comprising three independently addressable small-scale propellers, all integrated into a one-piece molded and interconnected device, (2) a terminal function block comprising a structured IR pyrotechnical loaf coupled with a microinitiation stage integrating low-energy addressable pyroMEMS, and (3) a connected, autonomous, STANAG 4187 compliant, electronic sensor arming and firing block.

scholarly journals New Silver(I) Coordination Polymer with Fe4 Single-Molecule Magnets as Long Spacer

2018 ◽  
Vol 4 (4) ◽  
pp. 43 ◽  
Author(s):  
Luca Rigamonti ◽  
Manuela Vaccari ◽  
Fabrizio Roncaglia ◽  
Carlo Baschieri ◽  
Alessandra Forni
Keyword(s):  
Coordination Polymer ◽  
Single Molecule ◽  
Building Blocks ◽  
Zero Field ◽  
Single Molecule Magnets ◽  
Long Distance ◽  
Linear Arrangement ◽  
Thermally Activated ◽  
Supramolecular Architectures ◽  
Donor Nitrogen

In continuation of our work on supramolecular architectures of single-molecule magnets (SMMs) as a promising strategy in developing their magnetic performance, in this paper we report the synthesis and single crystal X-ray structure of the centered triangular tetrairon(III) SMM, [Fe4(PhpPy)2(dpm)6], Fe4 (Hdpm = dipivaloylmethane, H3PhpPy = 2-(hydroxymethyl)-2-(4-(pyridine-4-yl)phenyl)propane-1,3-diol), and its assembly in the coordination polymer {[Fe4(PhpPy)2(dpm)6Ag](ClO4)}n, Fe4Ag, upon reaction with silver(I) perchlorate. Thanks to the presence of the pyridyl rings on the two tripodal ligands, Fe4 behaves as divergent ditopic linker, and due to the Fe4:AgClO4 1:1 ratio, Fe4Ag probably possesses a linear arrangement in which silver(I) ions are linearly coordinated by two nitrogen atoms, forming 1D chains whose positive charge is balanced by the perchlorate anions. The stabilization of such a polymeric structure can be ascribed to the long distance between the two donor nitrogen atoms (23.4 Å) and their donor power. Fe4Ag shows slow relaxation of the magnetization which follows a thermally activated process with Ueff/kB = 11.17(18) K, τ0 = 2.24(17) 10−7 s in zero field, and Ueff/kB = 14.49(5) K, τ0 = 3.88(8) 10−7 s in 1-kOe applied field, in line with what reported for tetrairon(III) SMMs acting as building blocks in polymeric structures.

Concept Design of Very Large Floating Structures and Laboratory-Scale Physical Modelling

2019 ◽  
Author(s):  
Lorenzo Cappietti ◽  
Irene Simonetti ◽  
Ilaria Crema
Keyword(s):  
Numerical Models ◽  
Physical Modelling ◽  
Building Blocks ◽  
Small Scale ◽  
World Population ◽  
Concept Design ◽  
Wave Loads ◽  
Experimental Database ◽  
Floating Structures ◽  
Very Large Floating Structures

Abstract The use of Very Large Floating Structures, VLFS, may represent a strategic approach in order to cope with some of the future societal challenges arising from the impressive growth of the world population. In this article, the motivations of this perspective are briefly discussed, the main issues for the development of VLFS are summarized and a concept structural design based on building-blocks technology is proposed. A small-scale physical model was manufactured and tested in the wave-current flume of the Laboratory of Maritime Engineering, LABIMA, of the Florence University, Italy. The aim of this study is the assessment of the structural feasibility and the effectiveness of the proposed VLFS concept, in terms of resistance to wave loads and control of floating behavior. The experimental measurements provide a first contribution to the necessary knowledge, about load magnitudes and floating behavior, for sizing some of the key structural components. The results appear to support the feasibility of the system in terms of usage of structural materials, technical components and building technologies, available at present, that can withstand the measured loads. Moreover, the acquired experimental database is fundamental in order to validate numerical models, in the perspective of using also such tools as complementary methodology for further improvement of the knowledge of design issues.

scholarly journals Post-rendezvous radar properties of comet 67P/CG from the Rosetta Mission: understanding future Earth-based radar observations and the dynamical evolution of comets

2019 ◽  
Vol 489 (2) ◽  
pp. 1667-1683 ◽  
Author(s):  
Essam Heggy ◽  
Elizabeth M Palmer ◽  
Alain Hérique ◽  
Wlodek Kofman ◽  
M Ramy El-Maarry
Keyword(s):  
Large Scale ◽  
Structural Changes ◽  
Dynamical Evolution ◽  
Textural Properties ◽  
Building Blocks ◽  
Cometary Nucleus ◽  
Small Scale ◽  
Small Bodies ◽  
Radar Observations ◽  
Comet 67P

ABSTRACT Radar observations provide crucial insights into the formation and dynamical evolution of comets. This ability is constrained by our knowledge of the dielectric and textural properties of these small-bodies. Using several observations by Rosetta as well as results from the Earth-based Arecibo radio telescope, we provide an updated and comprehensive dielectric and roughness description of Comet 67P/CG, which can provide new constraints on the radar properties of other nuclei. Furthermore, contrary to previous assumptions of cometary surfaces being dielectrically homogeneous and smooth, we find that cometary surfaces are dielectrically heterogeneous ( εr′≈1.6–3.2), and are rough at X- and S-band frequencies, which are widely used in characterization of small-bodies. We also investigate the lack of signal broadening in CONSERT observations through the comet head. Our results suggest that primordial building blocks in the subsurface are either absent, smaller than the radar wavelength, or have a weak dielectric contrast (Δ εr′). To constrain this ambiguity, we use optical albedo measurements by the OSIRIS camera of the freshly exposed subsurface after the Aswan cliff collapse. We find that the hypothetical subsurface blocks should have |Δ εr′|≳0.15, setting an upper limit of ∼ 1 m on the size of 67P/CG's primordial building blocks if they exist. Our analysis is consistent with a purely thermal origin for the ∼ 3 m surface bumps on pit walls and cliff-faces, hypothesized to be high-centred polygons formed from fracturing of the sintered shallow ice-bearing subsurface due to seasonal thermal expansion and contraction. Potential changes in 67P/CG's radar reflectivity at these at X- and S-bands can be associated with large-scale structural changes of the nucleus rather than small-scale textural ones. Monitoring changes in 67P/CG's radar properties during repeated close-approaches via Earth-based observations can constrain the dynamical evolution of its cometary nucleus.

Sign in / Sign up

Export Citation Format

Share Document