scholarly journals In-situ observation for growth of hierarchical metal-organic frameworks and their self-sequestering mechanism for gas storage

2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Jung Hyo Park ◽  
Kyung Min Choi ◽  
Hyung Joon Jeon ◽  
Yoon Jung Choi ◽  
Jeung Ku Kang



2016 ◽  
Vol 55 (6) ◽  
pp. 2012-2016 ◽  
Author(s):  
Hamish H.-M. Yeung ◽  
Yue Wu ◽  
Sebastian Henke ◽  
Anthony K. Cheetham ◽  
Dermot O'Hare ◽  
...  


2016 ◽  
Vol 128 (6) ◽  
pp. 2052-2056 ◽  
Author(s):  
Hamish H.-M. Yeung ◽  
Yue Wu ◽  
Sebastian Henke ◽  
Anthony K. Cheetham ◽  
Dermot O'Hare ◽  
...  


ChemInform ◽  
2015 ◽  
Vol 46 (38) ◽  
pp. no-no
Author(s):  
Suvendu Sekhar Mondal ◽  
Arne Thomas ◽  
Hans-Juergen Holdt


Author(s):  
Stephen J. I. Shearan ◽  
Jannick Jacobsen ◽  
Ferdinando Costantino ◽  
Roberto D’Amato ◽  
Dmitri Novikov ◽  
...  


Author(s):  
Ayushi Singh ◽  
Ashish Kumar Singh ◽  
Jian-Qiang Liu ◽  
Abhinav Kumar

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...



Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1291 ◽  
Author(s):  
Isobel Tibbetts ◽  
George Kostakis

Metal-organic frameworks (MOFs) have found uses in adsorption, catalysis, gas storage and other industrial applications. Metal Biomolecule Frameworks (bioMOFs) represent an overlap between inorganic, material and medicinal sciences, utilising the porous frameworks for biologically relevant purposes. This review details advances in bioMOFs, looking at the synthesis, properties and applications of both bioinspired materials and MOFs used for bioapplications, such as drug delivery, imaging and catalysis, with a focus on examples from the last five years.



Chemosphere ◽  
2020 ◽  
pp. 128616 ◽  
Author(s):  
K. Bhuvaneswari ◽  
G. Palanisamy ◽  
T. Pazhanivel ◽  
T. Maiyalagan ◽  
P. Shanmugam ◽  
...  


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 722
Author(s):  
Ioanna Christodoulou ◽  
Tom Bourguignon ◽  
Xue Li ◽  
Gilles Patriarche ◽  
Christian Serre ◽  
...  

In recent years, Metal-Organic Frameworks (MOFs) have attracted a growing interest for biomedical applications. The design of MOFs should take into consideration the subtle balance between stability and biodegradability. However, only few studies have focused on the MOFs’ stability in physiological media and their degradation mechanism. Here, we investigate the degradation of mesoporous iron (III) carboxylate MOFs, which are among the most employed MOFs for drug delivery, by a set of complementary methods. In situ AFM allowed monitoring with nanoscale resolution the morphological, dimensional, and mechanical properties of a series of MOFs in phosphate buffer saline and in real time. Depending on the synthetic route, the external surface presented either well-defined crystalline planes or initial defects, which influenced the degradation mechanism of the particles. Moreover, MOF stability was investigated under different pH conditions, from acidic to neutral. Interestingly, despite pronounced erosion, especially at neutral pH, the dimensions of the crystals were unchanged. It was revealed that the external surfaces of MOF crystals rapidly respond to in situ changes of the composition of the media they are in contact with. These observations are of a crucial importance for the design of nanosized MOFs for drug delivery applications.



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