Organically templated rare earth sulfates with three-dimensional and layered structures

2004 ◽  
Vol 14 (8) ◽  
pp. 1257-1265 ◽  
Author(s):  
Meenakshi Dan ◽  
J. N. Behera ◽  
C. N. R. Rao
Keyword(s):  
Rare Earth ◽  
Three Dimensional ◽  
Layered Structures

scholarly journals Intermetallic REPtZn Compounds with TiNiSi-type Structure

2011 ◽  
Vol 66 (7) ◽  
pp. 671-676 ◽  
Author(s):  
Trinath Mishra ◽  
Rainer Pöttgen
Keyword(s):  
Rare Earth ◽  
Single Crystal ◽  
Coordination Number ◽  
High Frequency ◽  
Three Dimensional ◽  
Type Structure ◽  
Rare Earth Compounds ◽  
Crystal Data ◽  
X Ray Diffraction ◽  
X Ray

The equiatomic rare earth compounds REPtZn (RE = Y, Pr, Nd, Gd-Tm) were synthesized from the elements in sealed tantalum tubes by high-frequency melting at 1500 K followed by annealing at 1120 K and quenching. The samples were characterized by powder X-ray diffraction. The structures of four crystals were refined from single-crystal diffractometer data: TiNiSi type, Pnma, a = 707.1(1), b = 430.0(1), c = 812.4(1) pm, wR2 = 0.066, 602 F2, 21 variables for PrPt1.056Zn0.944; a = 695.2(1), b = 419.9(1), c = 804.8(1) pm, wR2 = 0.041, 522 F2, 21 variables for GdPt0.941Zn1.059; a = 688.2(1), b = 408.1(1), c = 812.5(1) pm, wR2 = 0.041, 497 F2, 22 variables for HoPt1.055Zn0.945; a = 686.9(1), b = 407.8(1), c = 810.4(1) pm, wR2 = 0.061, 779 F2, 20 variables for ErPtZn. The single-crystal data indicate small homogeneity ranges REPt1±xZn1±x. The platinum and zinc atoms build up three-dimensional [PtZn] networks (265 - 269 pm Pt-Zn in ErPtZn) in which the erbium atoms fill cages with coordination number 16 (6 Pt + 6 Zn + 4 Er). Bonding of the erbium atoms to the [PtZn] network proceeds via shorter RE-Pt distances, i. e. 288 - 293 pm in ErPtZn.

scholarly journals Tracing method of Rare Earth Elements in surrounding rock of geological formation based on three-dimensional positioning algorithm

2021 ◽  
Vol 25 (1) ◽  
pp. 21-28
Author(s):  
Yan Lv ◽  
Laijun Lu ◽  
Mengxue Cao
Keyword(s):  
Mass Spectrometry ◽  
Rare Earth ◽  
Mass Spectrum ◽  
Rare Earth Elements ◽  
Earth Element ◽  
Three Dimensional ◽  
Test Sample ◽  
Surrounding Rock ◽  
Geological Formation ◽  
Positioning Algorithm

Because of the interference of mass spectrum and non-mass spectrum, the tracing accuracy of rare earth elements in the surrounding rock of geological formation is low. Pretreatment of test sample reagent, dissolution of test sample residue, characterization of rare earth element doped materials, analysis of mass spectrometry and non-mass spectrometry interference in rare earth element tracking, using three-dimensional positioning algorithm to track rare earth elements in geological strata surrounding rock. In the experiment, five samples of surrounding rock of geological strata are selected as experimental indexes. The experimental results show that the tracking accuracy of four rare earth elements is high.

scholarly journals A Three-Dimensional Magnetic Force SolutionBetween Axially-Polarized Permanent-Magnet Cylinders for Different Magnetic Arrangements

2020 ◽  
Vol 7 ◽  
Keyword(s):  
Experimental Data ◽  
Rare Earth ◽  
Field Strength ◽  
Permanent Magnet ◽  
Magnetic Force ◽  
Three Dimensional ◽  
Method Of Images ◽  
Field Equations ◽  
Rare Earth Magnet ◽  
Finite Sums

A three-dimensional field solution is presented foraxially polarized permanent magnet cylinders. The fieldcomponents are expressed in terms of finite sums of elementaryfunctions and are easily programmable. They can be used todetermine the operating point of rare-earth magnet cylinders.They are also useful for performing rapid parametriccalculations of field strength as a function of materialproperties and dimensions. The field components aredeveloped for different magnet arrangements by taking intoaccount the back iron. Also the method of images is used. Usingthe field equations, three-dimensional analytical expressionsare derived for computing the magnetic force between axiallypolarized permanent-magnet cylinders for different magneticarrangements. The field calculated results are in goodagreement with the experimental data.

Ternary Thallides REMgTl (Re = Y, La – Nd, Sm, Gd – Tm, Lu)

2005 ◽  
Vol 60 (3) ◽  
pp. 265-270 ◽  
Author(s):  
Rainer Kraft ◽  
Rainer Pöttgen
Keyword(s):  
Rare Earth ◽  
Single Crystal ◽  
Rare Earth Metal ◽  
High Frequency ◽  
Three Dimensional ◽  
Earth Metal ◽  
X Ray ◽  
Sample Chamber ◽  
Trigonal Prismatic Coordination ◽  
Trigonal Prismatic

The rare earth metal (RE)-magnesium-thallides REMgTl (RE = Y, La-Nd, Sm, Gd-Tm, Lu) were prepared from the elements in sealed tantalum tubes in a water-cooled sample chamber of a high-frequency furnace. The thallides were characterized through their X-ray powder patterns. They crystallize with the hexagonal ZrNiAl type structure, space group P62m, with three formula units per cell. Four structures were refined from X-ray single crystal diffractometer data: α = 750.5(1), c = 459.85(8) pm, wR2 = 0.0491, 364 F2 values, 14 variables for YMgTl; α = 781.3(1), c = 477.84(8) pm, wR2 = 0.0640, BASF = 0.09(2), 425 F2 values, 15 variables for LaMgTl; α = 774.1(1), c = 473.75(7) pm, wR2 = 0.0405, 295 F2 values, 14 variables for CeMgTl; a = 760.3(1), c = 465.93(8) pm, wR2 = 0.0262, 287 F2 values, 14 variables for SmMgTl. The PrMgTl, NdMgTl, GdMgTl, TbMgTl, and DyMgTl structures have been analyzed using the Rietveld technique. The REMgTl structures contain two cystallographically independent thallium sites, both with tri-capped trigonal prismatic coordination: Tl1Mg3RE6 and Tl2Mg6RE3. Together the magnesium and thallium atoms form three-dimensional [MgTl] networks with Mg-Mg distances of 327 and Mg-Tl distances in the range 299 - 303 pm (data for CeMgTl)

scholarly journals From Two- to Three-Dimensional van der Waals Layered Structures of Boron Crystals: An Ab Initio Study

ACS Omega ◽  
2019 ◽  
Vol 4 (5) ◽  
pp. 8015-8021 ◽  
Author(s):  
Dengfeng Li ◽  
QiQi Tang ◽  
Jia He ◽  
Bolin Li ◽  
Guangqian Ding ◽  
...  
Keyword(s):  
Ab Initio ◽  
Van Der Waals ◽  
Three Dimensional ◽  
Layered Structures ◽  
Ab Initio Study

Hierarchical Two- and Three-Dimensional Microstructures Composed of Rare-Earth Compound Nanotubes

2004 ◽  
Vol 16 (16) ◽  
pp. 1448-1453 ◽  
Author(s):  
M. Yada ◽  
C. Taniguchi ◽  
T. Torikai ◽  
T. Watari ◽  
S. Furuta ◽  
...  
Keyword(s):  
Rare Earth ◽  
Three Dimensional ◽  
Rare Earth Compound

Über das Erdalkalimetall-Lanthanoid-Kupfer-Oxomolybdat (Cu0,22Mg0 ,78)BaNd2Mo4O16/The Alkaline Earth Rare Earth Copper-Oxomolybdate (Cu0.22Mg0.78)BaNd2Mo4O16

1995 ◽  
Vol 50 (4) ◽  
pp. 577-580 ◽  
Author(s):  
H. Szillat ◽  
Hk. Müller-Buschbaum
Keyword(s):  
Crystal Structure ◽  
Rare Earth ◽  
Single Crystals ◽  
Alkaline Earth ◽  
Three Dimensional ◽  
Space Group ◽  
X Ray ◽  
Ray Methods

Single crystals of (Cu0.22Mg0.78)BaNd2Mo4O16 have been prepared by crystallization from melts and investigated by X-ray methods. The compound crystallizes monoclinically, space group C62h - C12/c1, Z = 4, a = 5.351(1), b = 12.891(2), c = 19.391(4) Å,β = 90.899(14)° and is isotypic to CuKHo2Mo4O16. The crystal structure is dominated by BaO10 and NdO8 polyhedra forming a three-dimensional polyhedra network, which is filled by axially distorted (Cu,Mg)O6 octahedra and MoO4 tetrahedra.

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