High selectivity chemiluminescence sensor for determination of puerarin in diet foods/weight loss promoters based on novel rhodanine and monodisperse molecularly imprinted microspheres

2010 ◽  
Vol 2 (10) ◽  
pp. 1506 ◽  
Author(s):  
Lei Ge ◽  
Ping Dai ◽  
Shenguang Ge ◽  
Jinghua Yu
2014 ◽  
Vol 936 ◽  
pp. 843-849 ◽  
Author(s):  
Gui Feng Lin ◽  
Yan Hong Wang ◽  
Guo Chen Li ◽  
Wen Bai ◽  
Hong Zhang ◽  
...  

Molecularly imprinted microspheres for recognition of chlorpyrifos were prepared by thermal initiation and precipitation polymerization, and were characterized using scanning electron microscope and infrared spectroscopy. Binding characteristics of the microspheres were also investigated. Sensitive film electrode of chlorpyrifos was prepared using the microspheres above on the surface of gold electrode by spin coating. Electrochemical sensor was constructed with the electrode prepared above as recognition element, and the response characteristics of the sensor to chlorpyrifos in water were investigated based on constant-current potentiometry. It was shown that a reasonable linear response curve between potential and concentration was obtained from 1.0×10-12mol/L to 2.0×10-8mol/L, with a detection limit of 1.0×10-13mol/L. The suitable pH was 2.2~3.4,and response time was 10 min. The imprinted electrode showed relatively high selectivity to chlorpyrifos and was applied to the analysis of chlorpyrifos in the simulated river samples with recovery rates ranging from 89% to 105%.


RSC Advances ◽  
2016 ◽  
Vol 6 (15) ◽  
pp. 12391-12397 ◽  
Author(s):  
Yanhui Wang ◽  
Huimin Duan ◽  
Leilei Li ◽  
Xiaojiao Wang ◽  
Jianbo Li ◽  
...  

In this paper, a new chemiluminescence sensor possessing high selectivity and sensitivity was established for determination of lysozyme using magnetic graphene oxide–multi-walled carbon nanotube surface molecularly imprinted polymer.


2004 ◽  
Vol 804 (1) ◽  
pp. 25-30 ◽  
Author(s):  
Jia-Ping Lai ◽  
Yue Jiang ◽  
Xi-Wen He ◽  
Jun-Chao Huang ◽  
Feng Chen

RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 34772-34783
Author(s):  
Yanzhuo Zhu ◽  
Honghui Teng ◽  
Dongshu Sun ◽  
Dayu Jiang ◽  
Yongsheng Yan

In this work, a new and simple method was developed for the synthesis of uncovered and high-selectivity spiramycin-based molecularly imprinted microspheres (SP-MIMs) by Pickering emulsion polymerization using spiramycin as templates.


Sensors ◽  
2019 ◽  
Vol 19 (10) ◽  
pp. 2415 ◽  
Author(s):  
Yasuo Yoshimi ◽  
Daichi Oino ◽  
Hirofumi Ohira ◽  
Hitoshi Muguruma ◽  
Ewa Moczko ◽  
...  

It has been shown that the faradic current at an electrode grafted with molecularly imprinted polymer (MIP) is sensitive to the specific target molecule used as the template. This phenomenon is applicable to sensors with very high selectivity, but the sensing mechanism is still a black box. We investigated the size sensitivity of nanoparticles of molecularly imprinted polymers (MIP-NPs) to a specific interaction for determination of the mechanism of the gate effect and its feasibility for new applications. Nanoparticles of poly(methacryloxy ethyl trimethylammonium chloride-co-acrylamide-co-methylenebisacrylamide) imprinted with heparin immobilized on glass beads were synthesized. The diameter of the MIP-NPs of heparin was increased by the presence of the heparin template but was insensitive to chondroitin sulfate C (CSC), the analogue of heparin. The high selectivity of the MIP-NPs was consistent with the selectivity of electrodes grafted with a heparin-imprinted polymer in our previous studies. The quartz crystal microbalance probes immobilizing heparin or CSC were sensitive to MIP-NPs, which indicates that the binding ability of MIP-NP does not discriminate between the template and other glycosaminoglycans. These results indicate that the size of the MIP-NP is sensitive to the matched binding with the template through the imprinted cavity.


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