The catalytic efficiency of Fe-porphyrins supported on multi-walled carbon nanotubes in the heterogeneous oxidation of hydrocarbons and sulfides in water

2014 ◽  
Vol 4 (7) ◽  
pp. 1960 ◽  
Author(s):  
Abdolreza Rezaeifard ◽  
Maasoumeh Jafarpour

2021 ◽  
Vol 15 (4) ◽  
pp. 479-485
Author(s):  
Eldar Zeynalov ◽  
◽  
Asgar Huseynov ◽  
Elchin Huseynov ◽  
Nazilya Salmanova ◽  
...  

The article presents simple kinetic approaches to study the effect of multi-walled carbon nanotubes (MWCNTs) additives on the aerobic oxidation of hydrocarbons and to propose real acceptable mechanisms of the process. The aerobic liquid phase low-temperature oxidation of ethylbenzene conducted in the presence of multi-walled carbon nanotubes has been used as a model pattern. Kinetic analysis established the catalytic action associated with the presence of the iron compounds in inner channels of MWCNTs. These compounds are identified as ferric carbides provoking decomposition of the ethylbenzene hydroperoxide and thereby suppressing the competitive route of alky-peroxide radicals addition to the nanocarbon cage. Thus the reaction finally proceeds in the autocatalytic mode.Contradictory conclusions on the effect of CNTs on the oxidation chain processes existing in the literature are associated with the lack of control over nature and content of metal impurities in channels of nanotubes.



2017 ◽  
Vol 41 (16) ◽  
pp. 7987-7991 ◽  
Author(s):  
Saeed Rayati ◽  
Fatemeh Nejabat

A Fe–porphyrin catalyst was anchored covalently onto functionalized multi-walled carbon nanotubes.



Acta Naturae ◽  
2011 ◽  
Vol 3 (1) ◽  
pp. 99-106 ◽  
Author(s):  
E A Smirnova ◽  
A A Gusev ◽  
O N Zaitseva ◽  
E M Lazareva ◽  
G E Onishchenko ◽  
...  


2016 ◽  
Vol 136 (4) ◽  
pp. 180-185 ◽  
Author(s):  
Zaw Lin ◽  
Mitsunobu Yoshida ◽  
Yuki Uesugi ◽  
Karthik Paneer Selvam ◽  
Takeshi Nishikawa ◽  
...  


2003 ◽  
Vol 772 ◽  
Author(s):  
T. Seeger ◽  
G. de la Fuente ◽  
W.K. Maser ◽  
A.M. Benito ◽  
A. Righi ◽  
...  

AbstractCarbon nanotubes (CNT) are interesting candidates for the reinforcement in robust composites and for conducting fillers in polymers due to their fascinating electronic and mechanical properties. For the first time, we report the incorporation of multi walled carbon nanotubes (MWNTs) into silica-glass surfaces by means of partial surface-melting caused by a continuous wave Nd:YAG laser. MWNTs were detected being well incorporated in the silica-surface. The composites are characterized using scanning electron microscopy (SEM) and Raman-spectroscopy. A model for the composite-formation is proposed based on heatabsorption by MWNTs and a partial melting of the silica-surface.



2010 ◽  
Vol 25 (2) ◽  
pp. 181-185 ◽  
Author(s):  
Yu-Chang QING ◽  
Wan-Cheng ZHOU ◽  
Fa LUO ◽  
Dong-Mei ZHU


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