Crystal-plane-dependent metal–support interaction in Au/TiO2

2015 ◽  
Vol 17 (7) ◽  
pp. 5133-5140 ◽  
Author(s):  
Lichen Liu ◽  
Chengyan Ge ◽  
Weixin Zou ◽  
Xianrui Gu ◽  
Fei Gao ◽  
...  

The metal–support interactions between Au and different TiO2 crystal planes are investigated to identify their crystal-plane-dependent properties.

2020 ◽  
Vol 8 (32) ◽  
pp. 16582-16589 ◽  
Author(s):  
Xulei Sui ◽  
Lei Zhang ◽  
Junjie Li ◽  
Kieran Doyle-Davis ◽  
Ruying Li ◽  
...  

A facile in situ ion-exchanging strategy directly enhances metal–support interactions between Pt and support and promotes HER electrocatalytic performance in acidic media.


2020 ◽  
Vol 44 (4) ◽  
pp. 1221-1227 ◽  
Author(s):  
Xuemei Wei ◽  
Zhanwei Ma ◽  
Jinzhi Lu ◽  
Xinyuan Mu ◽  
Bin Hu

A four-fold increase in palladium-based acetylene dicarbonylation activity was obtained at low temperature due to the strong metal–support interaction between Pd and the earth-abundant α-Fe2O3 material.


2019 ◽  
Vol 55 (4) ◽  
pp. 474-477 ◽  
Author(s):  
Xiuyun Wang ◽  
Lingling Li ◽  
Tianhua Zhang ◽  
Bingyu Lin ◽  
Jun Ni ◽  
...  

We report a new strategy for strengthening metal–support interaction and stabilizing Co nanoparticles at high temperature.


ACS Catalysis ◽  
2017 ◽  
Vol 7 (2) ◽  
pp. 1313-1329 ◽  
Author(s):  
Wei-Wei Wang ◽  
Wen-Zhu Yu ◽  
Pei-Pei Du ◽  
Hui Xu ◽  
Zhao Jin ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 896
Author(s):  
Xiaorui Du ◽  
Hailian Tang ◽  
Botao Qiao

The discoveries and development of the oxidative strong metal–support interaction (OMSI) phenomena in recent years not only promote new and deeper understanding of strong metal–support interaction (SMSI) but also open an alternative way to develop supported heterogeneous catalysts with better performance. In this review, the brief history as well as the definition of OMSI and its difference from classical SMSI are described. The identification of OMSI and the corresponding characterization methods are expounded. Furthermore, the application of OMSI in enhancing catalyst performance, and the influence of OMSI in inspiring discoveries of new types of SMSI are discussed. Finally, a brief summary is presented and some prospects are proposed.


2019 ◽  
Vol 55 (96) ◽  
pp. 14410-14413 ◽  
Author(s):  
Jiawen Zhao ◽  
Shuang Xu ◽  
Hongjie Wu ◽  
Zhixiong You ◽  
Lidan Deng ◽  
...  

Strong metal–support interaction (SMSI) over Ru/CaAlOx was constructed by utilizing the surface structural reconstruction of Ca–Al layered double hydroxides (LDHs) in aqueous solution and their subsequent hydroxide-to-oxide transformations.


2018 ◽  
Vol 6 (45) ◽  
pp. 23078-23086 ◽  
Author(s):  
Yaroslava Lykhach ◽  
Firas Faisal ◽  
Tomáš Skála ◽  
Armin Neitzel ◽  
Nataliya Tsud ◽  
...  

Metal-support interactions at the Pt/Co3O4(111) interface yield Ptδ+ species which control the stability of the supported nanoparticles.


RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 51106-51110 ◽  
Author(s):  
Zhanwei Ma ◽  
Xumao Xiong ◽  
Chengli Song ◽  
Bin Hu ◽  
Weiqiang Zhang

Doping Zr4+ alters the electronic properties of the support. The electronic metal–support interaction produces the upshift of d-band center of Ru nanoparticles, which further influences the catalytic activity of ammonia synthesis.


2017 ◽  
Vol 4 (4) ◽  
pp. 668-674 ◽  
Author(s):  
Pei-Pei Du ◽  
Xiu-Cui Hu ◽  
Xu Wang ◽  
Chao Ma ◽  
Meng Du ◽  
...  

Both copper and palladium in Cu–Pd–Ce–O are oxidized with metal–support interactions of Cu–Ox–Ce and Pd–Ox–Ce species, which are active for CO oxidation.


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