scholarly journals Oxidative Strong Metal–Support Interactions

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 896
Author(s):  
Xiaorui Du ◽  
Hailian Tang ◽  
Botao Qiao

The discoveries and development of the oxidative strong metal–support interaction (OMSI) phenomena in recent years not only promote new and deeper understanding of strong metal–support interaction (SMSI) but also open an alternative way to develop supported heterogeneous catalysts with better performance. In this review, the brief history as well as the definition of OMSI and its difference from classical SMSI are described. The identification of OMSI and the corresponding characterization methods are expounded. Furthermore, the application of OMSI in enhancing catalyst performance, and the influence of OMSI in inspiring discoveries of new types of SMSI are discussed. Finally, a brief summary is presented and some prospects are proposed.

2020 ◽  
Vol 44 (4) ◽  
pp. 1221-1227 ◽  
Author(s):  
Xuemei Wei ◽  
Zhanwei Ma ◽  
Jinzhi Lu ◽  
Xinyuan Mu ◽  
Bin Hu

A four-fold increase in palladium-based acetylene dicarbonylation activity was obtained at low temperature due to the strong metal–support interaction between Pd and the earth-abundant α-Fe2O3 material.


2019 ◽  
Vol 55 (96) ◽  
pp. 14410-14413 ◽  
Author(s):  
Jiawen Zhao ◽  
Shuang Xu ◽  
Hongjie Wu ◽  
Zhixiong You ◽  
Lidan Deng ◽  
...  

Strong metal–support interaction (SMSI) over Ru/CaAlOx was constructed by utilizing the surface structural reconstruction of Ca–Al layered double hydroxides (LDHs) in aqueous solution and their subsequent hydroxide-to-oxide transformations.


Nano Letters ◽  
2016 ◽  
Vol 16 (7) ◽  
pp. 4528-4534 ◽  
Author(s):  
Shuyi Zhang ◽  
Philipp N. Plessow ◽  
Joshua J. Willis ◽  
Sheng Dai ◽  
Mingjie Xu ◽  
...  

Author(s):  
Liangcai Zhang ◽  
Xinyu Liu ◽  
Hengwei Wang ◽  
Lina Cao ◽  
Chenxi Huang ◽  
...  

Strong metal-support interaction (SMSI) has long been studied in catalytic reactions. Proper utilization of the SMSI effect might not only improve the stability of the catalysts, but also the activity...


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