Using the Ozawa method to study the thermally initiated curing kinetics of vinyl ester resin

RSC Advances ◽  
2015 ◽  
Vol 5 (4) ◽  
pp. 2677-2683 ◽  
Author(s):  
Hui-Wang Cui ◽  
Katsuaki Suganuma ◽  
Hiroshi Uchida

1,1-Bis(t-hexylperoxy)-3,3,5-trimethyl cyclohexane was introduced to thermally initiate the curing of vinyl ester resin, and a dynamic differential scanning calorimetry method was applied to investigate the thermally initiated curing procedures.

2014 ◽  
Vol 988 ◽  
pp. 31-35
Author(s):  
Jia Le Song ◽  
Chan Chan Li ◽  
Zhi Mi Zhou ◽  
Chao Qiang Ye ◽  
Wei Guang Li

Curing kinetics of MEP-15/593 system and MEP-15/593/660 system is studied by means of differential scanning calorimetry (DSC). Curing kinetic parameters are evaluated and the relationship between diluent 660 and the curing properties is investigated. The results show that the diluent 660 can not only reduce viscosity and activation energy, but also improve the degree of cure and conversion ratio.


2013 ◽  
Vol 702 ◽  
pp. 119-122
Author(s):  
Teng Fei Shen ◽  
Fa Chao Wu ◽  
Ying Juan Sun

A series of novel azo-containing twin liquid crystalline (LC) epoxy monomers were cured with anhydrides without extra catalyst and the curing kinetics was investigated by non-isothermal differential scanning calorimetry (DSC) technique. The effect of Azo group on the Curing Kinetics of Epoxy/anhydride System was investigated and the result showed that Azo group served as a catalyst to accelerate the curing reaction. The curing mechanism was confirmed by the UV-Vis spectrum.


2006 ◽  
Vol 447 (2) ◽  
pp. 131-140 ◽  
Author(s):  
Chanchira Jubsilp ◽  
Siriporn Damrongsakkul ◽  
Tsutomu Takeichi ◽  
Sarawut Rimdusit

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