Recent advances in flexible perovskite solar cells

2015 ◽  
Vol 51 (79) ◽  
pp. 14696-14707 ◽  
Author(s):  
B. Susrutha ◽  
Lingamallu Giribabu ◽  
Surya Prakash Singh

Flexible thin-film photovoltaics facilitate the implementation of solar devices into portable, reduced dimension, and roll-to-roll modules. In this review, we describe recent developments in the fabrication of flexible perovskite solar cells that are low cost and highly efficient and can be used for the fabrication of large-area and lightweight solar cell devices.

Author(s):  
F. Bonnín-Ripoll ◽  
Ya. B. Martynov ◽  
R. G. Nazmitdinov ◽  
G. Cardona ◽  
R. Pujol-Nadal

A thorough optical + electrical + Lambertian scattering analysis determines the optimal thickness of a perovskite thin-film solar cell revealing its high efficiency with inorganic HTMs.


2018 ◽  
Vol 6 (28) ◽  
pp. 13751-13760 ◽  
Author(s):  
Chien-Hung Chiang ◽  
Cheng-Chiang Chen ◽  
Mohammad Khaja Nazeeruddin ◽  
Chun-Guey Wu

A new inorganic hole transporting layer, a sputtering made LiCoO2 film, was developed and used in an inverted perovskite solar cell (PSC) and sub-module (PSM).


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Young Yun Kim ◽  
Tae-Youl Yang ◽  
Riikka Suhonen ◽  
Antti Kemppainen ◽  
Kyeongil Hwang ◽  
...  

Abstract Driven by recent improvements in efficiency and stability of perovskite solar cells (PSCs), upscaling of PSCs has come to be regarded as the next step. Specifically, a high-throughput, low-cost roll-to-roll (R2R) processes would be a breakthrough to realize the commercialization of PSCs, with uniform formation of precursor wet film and complete conversion to perovskite phase via R2R-compatible processes necessary to accomplish this goal. Herein, we demonstrate the pilot-scale, fully R2R manufacturing of all the layers except for electrodes in PSCs. Tert-butyl alcohol (tBuOH) is introduced as an eco-friendly antisolvent with a wide processing window. Highly crystalline, uniform formamidinium (FA)-based perovskite formation via tBuOH:EA bathing was confirmed by achieving high power conversion efficiencies (PCEs) of 23.5% for glass-based spin-coated PSCs, and 19.1% for gravure-printed flexible PSCs. As an extended work, R2R gravure-printing and tBuOH:EA bathing resulted in the highest PCE reported for R2R-processed PSCs, 16.7% for PSCs with R2R-processed SnO2/FA-perovskite, and 13.8% for fully R2R-produced PSCs.


2015 ◽  
Vol 3 (28) ◽  
pp. 14631-14641 ◽  
Author(s):  
Shenghao Wang ◽  
Luis K. Ono ◽  
Matthew R. Leyden ◽  
Yuichi Kato ◽  
Sonia R. Raga ◽  
...  

The hybrid deposition method was developed to overcome the difficulties that the vacuum-based techniques face for fabricating perovskite solar cells. Our results provide an explanation of various factors that need optimizing to achieve convenient and reliable fabrication of large-area smooth perovskite thin films for solar cell applications without the use of solvents.


Author(s):  
Hongliang Wang ◽  
Y. Lawrence Yao ◽  
Hongqiang Chen

Laser scribing is an important manufacturing process used to reduce photocurrent and resistance losses and increase solar cell efficiency through the formation of serial interconnections in large-area solar cells. High-quality scribing is crucial since the main impediment to large-scale adoption of solar power is its high-production cost (price-per-watt) compared to competing energy sources such as wind and fossil fuels. In recent years, the use of glass-side laser scribing processes has led to increased scribe quality and solar cell efficiencies; however, defects introduced during the process such as thermal effect, microcracks, film delamination, and removal uncleanliness keep the modules from reaching their theoretical efficiencies. Moreover, limited numerical work has been performed in predicting thin-film laser removal processes. In this study, a nanosecond (ns) laser with a wavelength at 532 nm is employed for pattern 2 (P2) scribing on CdTe (cadmium telluride) based thin-film solar cells. The film removal mechanism and defects caused by laser-induced micro-explosion process are studied. The relationship between those defects, removal geometry, laser fluences, and scribing speeds are also investigated. Thermal and mechanical numerical models are developed to analyze the laser-induced spatiotemporal temperature and pressure responsible for film removal. The simulation can well-predict the film removal geometries, transparent conducting oxide (TCO) layer thermal damage, generation of microcracks, film delamination, and residual materials. The characterization of removal qualities will enable the process optimization and design required to enhance solar module efficiency.


2021 ◽  
Vol 2070 (1) ◽  
pp. 012043
Author(s):  
S S Hegde ◽  
K Ramesh

Abstract Photovoltaics (PV) have become increasingly popular and reached as the third-largest renewable energy source. Thin-film solar cells made from earth-abundant, inexpensive and environmentally friendly materials are needed to replace the current PV technologies whose large-scale applications are limited by material and/or resource constraints. Near optimum direct optical bandgap of 1.3 eV, high absorption coefficient (>104 cm−1), less toxic, and abundant raw resources along with considerable scalability have made tin sulfide (SnS) as a strategic choice for next-generation PVs. In this review, limitations of leading commercial PV technologies and the status of a few alternate low-cost PV materials are outlined. Recent literature on crucial physical properties of SnS thin-films and the present status of SnS thin-film-based solar cells are discussed. Deficiency and adequacy of some of the key properties of SnS including carrier mobility (μ), minority carrier lifetime (τ), and absorption coefficient (α) are discussed in comparison of existing commercial solar cell materials. Future research trends on SnS based solar cells to enhance their conversion efficiencies towards the theoretical maximum of 24% from present ~5% and its prospectus as next-generation solar cell is also discussed.


2018 ◽  
Vol 67 ◽  
pp. 01022 ◽  
Author(s):  
Michael Hariadi ◽  
Istighfari Dzikri ◽  
Retno Wigajatri Purnamaningsih ◽  
Nji Raden Poespawati

Indonesia is an archipelagic nation that has many small islands where the average load is low and currently supplied by diesel power generators. The drawbacks from these generators are cost constraints from its operation. Solar cells are the solution of this problem with the support of daily average radiation in Indonesia of 4.8 kWh/m2/day. There has been a lot of technology for the construction of solar cells such as silicon based, copper indium gallium selenide (CIGS), which was already successfully commercialized. However, these technologies have been obsolete and started to reach its maximum potential. Perovskite solar cells have a very high future potential, due to the increase on the efficiency of this technology in a relatively short amount of time. The current challenge for the fabrication of perovskite solar cell is the material cost and fabrication cost. This paper discussed the low-cost fabrication of perovskite solar cell using only spin coating deposition method and relatively also low-cost materials for the structure of the perovskite solar cell itself. As a result, we achieve perovskite solar cell with VOC of 0.6 V, ISC of 13 mA, FF of 0.28, and 1.2% efficiency.


MRS Bulletin ◽  
1993 ◽  
Vol 18 (10) ◽  
pp. 45-47 ◽  
Author(s):  
T. Suntola

Cadmium telluride is currently the most promising material for high efficiency, low-cost thin-film solar cells. Cadmium telluride is a compound semiconductor with an ideal 1.45 eV bandgap for direct light-to-electricity conversion. The light absorption coefficient of CdTe is high enough to make a one-micrometer-thick layer of material absorb over 99% of the visible light. Processing homogenous polycrystalline thin films seems to be less critical for CdTe than for many other compound semiconductors. The best small-area CdTe thin-film cells manufactured show more than 15% conversion efficiency. Large-area modules with aperture efficiencies in excess of 10% have also been demonstrated. The long-term stability of CdTe solar cell structures is not known in detail or in the necessary time span. Indication of good stability has been demonstrated. One of the concerns about CdTe solar cells is the presence of cadmium which is an environmentally hazardous material.


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