High capacity and exceptional cycling stability of ternary metal sulfide nanorods as Li ion battery anodes

2015 ◽  
Vol 51 (69) ◽  
pp. 13350-13353 ◽  
Author(s):  
Dhrubajyoti Bhattacharjya ◽  
Apurba Sinhamahapatra ◽  
Jae-Jung Ko ◽  
Jong-Sung Yu
Keyword(s):  
Specific Capacity ◽  
High Capacity ◽  
Metal Sulfide ◽  
Cycling Stability ◽  
Passivation Layer ◽  
Li Ion Battery ◽  
Composite Binder ◽  
High Specific Capacity ◽  
Ternary Metal ◽  
Li Ion

Ternary spinel NiCo2S4 nanorods demonstrate high specific capacity and outstanding cycling stability as Li ion battery anodes due to restriction of a polymeric gel passivation layer by the CMC–PAA composite binder.

scholarly journals Wire-in-Wire TiO2/C Nanofibers Free-Standing Anodes for Li-Ion and K-Ion Batteries with Long Cycling Stability and High Capacity

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Die Su ◽  
Yi Pei ◽  
Li Liu ◽  
Zhixiao Liu ◽  
Junfang Liu ◽  
...  
Keyword(s):  
Critical Role ◽  
Electronic Conductivity ◽  
Specific Capacity ◽  
High Capacity ◽  
Cycling Stability ◽  
Free Standing ◽  
High Specific Capacity ◽  
Tetracarboxylic Dianhydride ◽  
Carbon Network

AbstractWearable and portable mobile phones play a critical role in the market, and one of the key technologies is the flexible electrode with high specific capacity and excellent mechanical flexibility. Herein, a wire-in-wire TiO2/C nanofibers (TiO2 ww/CN) film is synthesized via electrospinning with selenium as a structural inducer. The interconnected carbon network and unique wire-in-wire nanostructure cannot only improve electronic conductivity and induce effective charge transports, but also bring a superior mechanic flexibility. Ultimately, TiO2 ww/CN film shows outstanding electrochemical performance as free-standing electrodes in Li/K ion batteries. It shows a discharge capacity as high as 303 mAh g−1 at 5 A g−1 after 6000 cycles in Li half-cells, and the unique structure is well-reserved after long-term cycling. Moreover, even TiO2 has a large diffusion barrier of K+, TiO2 ww/CN film demonstrates excellent performance (259 mAh g−1 at 0.05 A g−1 after 1000 cycles) in K half-cells owing to extraordinary pseudocapacitive contribution. The Li/K full cells consisted of TiO2 ww/CN film anode and LiFePO4/Perylene-3,4,9,10-tetracarboxylic dianhydride cathode possess outstanding cycling stability and demonstrate practical application from lighting at least 19 LEDs. It is, therefore, expected that this material will find broad applications in portable and wearable Li/K-ion batteries.

High capacity, power density and cycling stability of silicon Li-ion battery anodes with a few layer black phosphorus additive

2019 ◽  
Vol 3 (1) ◽  
pp. 245-250 ◽  
Author(s):  
Kingshuk Roy ◽  
Malik Wahid ◽  
Dhanya Puthusseri ◽  
Apurva Patrike ◽  
Subas Muduli ◽  
...  
Keyword(s):  
Power Density ◽  
Anode Material ◽  
High Capacity ◽  
Black Phosphorus ◽  
Cycling Stability ◽  
Li Ion Battery ◽  
Volume Changes ◽  
High Theoretical Capacity ◽  
Li Ion ◽  
Battery Anode

The exceptionally high theoretical capacity of silicon as a Li-ion battery anode material is hard to realize and stabilize in practice due to huge volume changes during lithiation/de-lithiation. With the use of black phosphorus additive we could achieve tremendous stability due to strain management.

Realization of High Capacity and Cycling Stability in Pb‐Free A 2 CuBr 4 (A=CH 3 NH 3 /Cs, 2 D/3 D) Perovskite‐Based Li‐Ion Battery Anodes

ChemSusChem ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 3742-3746 ◽  
Author(s):  
Padmini Pandey ◽  
Neha Sharma ◽  
Reena A. Panchal ◽  
S. W. Gosavi ◽  
Satishchandra Ogale
Keyword(s):  
High Capacity ◽  
Cycling Stability ◽  
Li Ion Battery ◽  
Li Ion

FeMnO3: a high-performance Li-ion battery anode material

2016 ◽  
Vol 52 (76) ◽  
pp. 11414-11417 ◽  
Author(s):  
Kangzhe Cao ◽  
Huiqiao Liu ◽  
Xiaohong Xu ◽  
Yijing Wang ◽  
Lifang Jiao
Keyword(s):  
Anode Material ◽  
High Performance ◽  
High Capacity ◽  
Cycling Stability ◽  
Li Ion Battery ◽  
Li Ion ◽  
Battery Anode

FeMnO3particles were synthesized and evaluated as a Li-ion battery anode, exhibiting a high capacity and long-term cycling stability.

Zinc ion stabilized MnO2 nanospheres for high capacity and long lifespan aqueous zinc-ion batteries

2019 ◽  
Vol 7 (22) ◽  
pp. 13727-13735 ◽  
Author(s):  
Jinjin Wang ◽  
Jian-Gan Wang ◽  
Huanyan Liu ◽  
Chunguang Wei ◽  
Feiyu Kang
Keyword(s):  
Specific Capacity ◽  
High Capacity ◽  
Zinc Ion ◽  
Cycling Stability ◽  
High Specific Capacity ◽  
Stabilized Mno ◽  
Superior Cycling Stability

Zinc ion stabilized MnO2 nanospheres with a flower-like morphology and mesoporous texture are prepared, and they show high specific capacity and superior cycling stability for Zn-ion batteries.

scholarly journals Chemical vapor deposition-assisted fabrication of a graphene-wrapped MnO/carbon nanofibers membrane as a high-rate and long-life anode for lithium ion batteries

RSC Advances ◽  
2017 ◽  
Vol 7 (80) ◽  
pp. 50973-50980 ◽  
Author(s):  
Juan Wang ◽  
Chao Li ◽  
Zhenyu Yang ◽  
Deliang Chen
Keyword(s):  
Vapor Deposition ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Chemical Vapor ◽  
High Energy ◽  
High Rate ◽  
Li Ion Battery ◽  
High Specific Capacity ◽  
Li Ion ◽  
Cycling Life

Novel MnO/CNFs@G membrane by electrospinning and APCVD; this anode with high specific capacity and longest cycling life is of great interest to high energy thin film or flexible Li-ion battery.

Density modulated multilayer silicon thin films as li-ion battery anodes

2012 ◽  
Vol 1440 ◽  
Author(s):  
M. Taha Demirkan ◽  
Xin Li ◽  
Bingqing Wei ◽  
Tansel Karabacak
Keyword(s):  
Thin Films ◽  
Coulombic Efficiency ◽  
Specific Capacity ◽  
High Capacity ◽  
Reversible Capacity ◽  
Low Density ◽  
Li Ion Battery ◽  
Silicon Thin Film ◽  
Battery Cell ◽  
Li Ion

AbstractIn this work, we demonstrate a new density modulated multilayered silicon thin film anode approach that can provide a robust high capacity electrode for Li-ion batteries. These films have the ability to tolerate large volume changes due to their controlled microstructure. Silicon films with alternating layers of high/low material density were deposited using a DC sputtering system. Density of the individual layers was controlled by simply changing the working gas pressure during sputtering. Samples of Si films having thicknesses of 460 nm with different number of high/low density layers have been deposited on Cu current collectors. The electrochemical performance of the multilayered anode material was evaluated using a galvanostatic battery testing system at C/10 rate. After reaching a stabilized phase the battery cell showed a high coulombic efficiency of 96% to 99% and reversible specific capacity of 666 mAh g-1 (after 100 cycles). Low-density layers are believed to be acting as compliant sheets during volume expansion making the films more durable compared to conventional Si film anodes. The results indicate that density modulated multilayer Si thin films can be used to improve the mechanical properties of Li-ion battery anodes leading to high reversible capacity values even after high number of cycles.

scholarly journals New Fe2O3-Clay@C Nanocomposite Anodes for Li-Ion Batteries Obtained by Facile Hydrothermal Processes

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 808 ◽  
Author(s):  
Daniel Alonso-Domínguez ◽  
María Pico ◽  
Inmaculada Álvarez-Serrano ◽  
María López
Keyword(s):  
Iron Oxide ◽  
Electrochemical Performance ◽  
Low Cost ◽  
Specific Capacity ◽  
High Capacity ◽  
Particle Morphology ◽  
High Specific Capacity ◽  
Li Ion ◽  
Composition Structure ◽  
Structure And Microstructure

New iron-oxide-based anodes are prepared by an environmentally-friendly and low-cost route. The analysis of the composition, structure, and microstructure of the samples reveals the presence of a major hematite phase, which is accompanied by a certain concentration of an oxyhydroxide phase, which can act as a “lithium-reservoir”. By using sodium alginate as a binder, the synthesized anodes display superior electrochemical response, i.e., high specific capacity values and high stability, not only versus Li but also versus a high voltage cathode in a full cell. From these bare materials, clay-supported anodes are further obtained using sepiolite and bentonite natural silicates. The electrochemical performance of such composites is improved, especially for the sepiolite-containing one treated at 400 °C. The thermal treatment at this temperature provides the optimal conditions for a synergic nano-architecture to develop between the clay and the hematite nanoparticles. High capacity values of ~2500 mA h g−1 after 30 cycles at 1 A g−1 and retentions close to 92% are obtained. Moreover, after 450 cycles at 2 A g−1 current rate, this composite electrode displays values as high as ~700 mA h g−1. These results are interpreted taking into account the interactions between the iron oxide nanoparticles and the sepiolite surface through hydrogen bonds. The electrochemical performance is not only dependent on the oxidation state and particle morphology, but the composition is revealed as a key feature.

A photochromic zinc-based coordination polymer for a Li-ion battery anode with high capacity and stable cycling stability

2018 ◽  
Vol 47 (37) ◽  
pp. 13222-13228 ◽  
Author(s):  
Shu-Biao Xia ◽  
Fu-Shao Li ◽  
Xiang Shen ◽  
Xue Li ◽  
Fei-Xiang Cheng ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Anode Material ◽  
High Capacity ◽  
Cycling Stability ◽  
Li Ion Batteries ◽  
Li Ion Battery ◽  
Redox Active ◽  
Li Ion ◽  
Battery Anode

A zinc-based coordination polymer with photochromic 4,4′-bipyridinium derivatives as redox active building units is demonstrated as an anode material for Li-ion batteries.

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