Synthesis of Co-based bimetallic nanocrystals with one-dimensional structure for selective control on syngas conversion

Nanoscale ◽  
2015 ◽  
Vol 7 (29) ◽  
pp. 12365-12371 ◽  
Author(s):  
Rongbin Ba ◽  
Yonghui Zhao ◽  
Lujing Yu ◽  
Jianjun Song ◽  
Shuangshuang Huang ◽  
...  

Co-based bimetallic nanocrystals with a 1D structure are more effective for syngas conversion than the corresponding Co-based nanoparticles.

RSC Advances ◽  
2016 ◽  
Vol 6 (15) ◽  
pp. 12467-12471 ◽  
Author(s):  
Qiong Luo ◽  
Liyong Chen ◽  
Binhua Duan ◽  
Zhizhi Gu ◽  
Jing Liu ◽  
...  

Hierarchical porous and hollow N-doped graphitic carbon with one-dimensional structure was successfully achieved by a sacrificial template method, and exhibited an enhanced electrocatalytic performance towards ORR due to its special structure.


NANO ◽  
2019 ◽  
Vol 14 (07) ◽  
pp. 1950084 ◽  
Author(s):  
Jilong Wang ◽  
Siheng Su ◽  
Jingjing Qiu ◽  
Shiren Wang

In this paper, a novel and facile method to achieve fluorescent nanosized-diamond based nanowire (NW) is reported. One-dimensional (1D) organic NW has received tremendous attention due to its superior chemical functionality and size-, shape-, and material-dependent properties. In addition, nanosized-diamond is comprehensively studied and investigated due to superior tunable fluorescent properties, cost-effectiveness, facile manufacturing and high biocompatibility. Through thermal treatment, sulfur-modified nanosized-diamond was fabricated by mixing oxidized nanosized-diamond and dibenzyl disulfide at 900∘C. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and zeta potential were employed to characterize sulfur-modified nanosized-diamond. After that, porous anodic aluminum oxide template-assisted cathodic electrophoretic deposition method was used to achieve sulfur-modified nanosized-diamond NW. Scanning electron microscopy and transmission electron microscopy were applied to present the one-dimensional structure of the NWs. The optical properties of sulfur nanosized-diamond NW were characterized via ultraviolet-visible spectroscopy and photoluminescence spectroscopy. Finally, the as-synthesized sulfur-modified nanosized-diamond NW-based optical sensor was fabricated to detect vitamin B[Formula: see text] with high sensitivity and selectivity.


Quantum ◽  
2019 ◽  
Vol 3 ◽  
pp. 116 ◽  
Author(s):  
Aidan Dang ◽  
Charles D. Hill ◽  
Lloyd C. L. Hollenberg

We detail techniques to optimise high-level classical simulations of Shor's quantum factoring algorithm. Chief among these is to examine the entangling properties of the circuit and to effectively map it across the one-dimensional structure of a matrix product state. Compared to previous approaches whose space requirements depend on r, the solution to the underlying order-finding problem of Shor's algorithm, our approach depends on its factors. We performed a matrix product state simulation of a 60-qubit instance of Shor's algorithm that would otherwise be infeasible to complete without an optimised entanglement mapping.


2007 ◽  
Vol 63 (11) ◽  
pp. i185-i185 ◽  
Author(s):  
Wei Liu ◽  
Jingtai Zhao

The title compound, ammonium catena-[monoboro-monodihydrogendiborate-monohydrogenphosphate] hemihydrate, was obtained under solvothermal conditions using glycol as the solvent. The crystal structure is constructed of one-dimensional infinite borophosphate chains, which are interconnected by ammonium ions and water molecules via a complex hydrogen-bond network to form a three-dimensional structure. The water molecules of crystallization are disordered over inversion centres, and their H atoms were not located.


Author(s):  
Xiang Liu ◽  
Guoping Cai ◽  
K. W. Wang

Abstract In this research, the nonreciprocal wave transmission features in one-dimensional and two-dimensional metastable modular metastructures are studied. Unlike previous work, in which the nonreciprocal transmission in metastable metastructures is realized by utilizing the supratransmission phenomenon when the excitation frequency is inside the linearized bandgap, a new approach is explored to achieve nonreciprocal wave transmission exploiting metastability and asymmetric dual-threshold snap-through. It is found that because of the asymmetry of potential energy wells of the equilibria, there will be two excitation amplitude thresholds for a metastable component when it is initially at the high-potential-energy equilibrium with excitation frequency within the passband. When the excitation amplitude increases and exceeds the first threshold, the metastable component will snap to the low-potential-energy equilibrium and maintain intrawell motion around this stable point, which will cause a significant decrease of the wave transmission. And when the excitation amplitude exceeds the second threshold, the metastable component will start to perform interwell motion, and now the wave transmission will increase suddenly. By using this “dual-threshold” phenomenon, nonreciprocal wave transmission in a one-dimensional structure is realized by connecting a metastable chain with a linear periodic part. Because of the wave attenuation effect of the linear part of the system, the excitation amplitude thresholds on different sides of the one-dimensional structure will be discrepant. Therefore, nonreciprocal wave transmission can be developed when the excitation amplitude is within certain ranges. It is interesting to note that the direction of nonreciprocal wave transmission can be changed by setting the excitation amplitude to different values. By changing the configuration of the metastable chain, the operation frequency and excitation amplitude ranges of the nonreciprocal transmission can be tuned. For a two-dimensional metastable metastructure, nonreciprocal wave transmission can be realized by adjusting the parameters of some metastable modules in the metastructure in the manner that the potential energy and energy thresholds of the adjusted modules and the unadjusted modules are different, but the passbands of the adjusted modules and the unadjusted modules will overlap in some frequency regions. Numerical studies provide clear insight of the proposed nonreciprocal wave transmission approach.


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