Copper catalyzed synthesis of unsymmetrical diaryl sulfones from an arenediazonium salt and sodium p-toluenesulfinate

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 62926-62930 ◽  
Author(s):  
Sitaram Haribhau Gund ◽  
Radheshyam Suresh Shelkar ◽  
Jayashree Milind Nagarkar
Keyword(s):  
Homogeneous System ◽  
System P ◽  
Arenediazonium Salt ◽  
Arenediazonium Salts

Aryl sulfones have been synthesized by the reaction of sodium p-toluenesulfinate and arenediazonium salts using a CuI catalyzed homogeneous system.

scholarly journals Linear scaling relationships and volcano plots in homogeneous catalysis – revisiting the Suzuki reaction

2015 ◽  
Vol 6 (12) ◽  
pp. 6754-6761 ◽  
Author(s):  
Michael Busch ◽  
Matthew D. Wodrich ◽  
Clémence Corminboeuf
Keyword(s):  
Homogeneous Catalysis ◽  
Heterogeneous Catalysts ◽  
Suzuki Reaction ◽  
Homogeneous System ◽  
Linear Scaling ◽  
Scaling Relationships ◽  
Volcano Plots ◽  
System P ◽  
First Time

Volcano plots, commonly used to identify attractive heterogeneous catalysts are applied, for the first time, to a prototypical homogeneous system.

Comparison of TEM and STM observations of small silver clusters on different carbon supports

1990 ◽  
Vol 48 (4) ◽  
pp. 264-265
Author(s):  
Bernd Tesche ◽  
Tobias Schilling
Keyword(s):  
Vibration Isolation ◽  
Pyrolytic Graphite ◽  
Carbon Film ◽  
Silver Clusters ◽  
Carbon Supports ◽  
Stacking Order ◽  
System P ◽  
High Resolution Tem ◽  
High Degree ◽  
Degree Of Order

The objective of our work is to determine:a) whether both of the imaging methods (TEM, STM) yield comparable data andb) which method is better suited for a reliable structure analysis of microclusters smaller than 1.5 nm, where a deviation of the bulk structure is expected.The silver was evaporated in a bell-jar system (p 10−5 pa) and deposited onto a 6 nm thick amorphous carbon film and a freshly cleaved highly oriented pyrolytic graphite (HOPG).The average deposited Ag thickness is 0.1 nm, controlled by a quartz crystal microbalance at a deposition rate of 0.02 nm/sec. The high resolution TEM investigations (100 kV) were executed by a hollow-cone illumination (HCI). For the STM investigations a commercial STM was used. With special vibration isolation we achieved a resolution of 0.06 nm (inserted diffraction image in Fig. 1c). The carbon film shows the remarkable reduction in noise by using HCI (Fig. 1a). The HOPG substrate (Fig. 1b), cleaved in sheets thinner than 30 nm for the TEM investigations, shows the typical arrangement of a nearly perfect stacking order and varying degrees of rotational disorder (i.e. artificial single crystals). The STM image (Fig. 1c) demonstrates the high degree of order in HOPG with atomic resolution.

Conclusion: What is Speculative Empiricism?

2018 ◽  
Author(s):  
Didier Debaise
Keyword(s):  
Social Groups ◽  
Speculative Philosophy ◽  
System P ◽  
History Of ◽  
Selection Of

Process and Reality ends with a warning: ‘[t]he chief danger to philosophy is narrowness in the selection of evidence’ (PR, 337). Although this danger of narrowness might emerge from the ‘idiosyncrasies and timidities of particular authors, of particular social groups, of particular schools of thought, of particular epochs in the history of civilization’ (PR, 337), we should not be mistaken: it occurs within philosophy, in its activity, its method. And the fact that this issue arises at the end of Process and Reality reveals the ambition that has accompanied its composition: Whitehead has resisted this danger through the form and ambition of his speculative construction. The temptation of a narrowness in selection attempts to expel speculative philosophy at the same time as it haunts each part of its system.

Pedestrian Oriented Vehicular Collision Avoidance Support System: P-VCASS

2010 ◽  
Vol E93-A (4) ◽  
pp. 679-688 ◽  
Author(s):  
Tomotaka WADA ◽  
Yuki NAKANISHI ◽  
Ryohta YAMAGUCHI ◽  
Kazushi FUJIMOTO ◽  
Hiromi OKADA
Keyword(s):  
Collision Avoidance ◽  
Support System ◽  
System P

Temporal variability of disinfection by-products concentration in urban public water system

2013 ◽  
Vol 14 (4) ◽  
pp. 393-398
Keyword(s):  
Drinking Water ◽  
Water Samples ◽  
Temporal Variability ◽  
Water System ◽  
The Other ◽  
Major Constituent ◽  
System P ◽  
Public Water System ◽  
Drinking Water Samples ◽  
By Products

The occurrence of trihalomethanes (THMs) was studied in the drinking water samples from urban water supply network of Karachi city that served more than 18 million people. Drinking water samples were collected from 58 locations in summer (May-August) and winter (November-February) seasons. The major constituent of THMs detected was chloroform in winter (92.34%) and summer (93.07%), while the other THMs determined at lower concentrations. Summer and winter concentrations of total THMs at places exceed the levels regulated by UEPA (80 μg l-1) and WHO (100 μg l-1). GIS linked temporal variability in two seasons showed significantly higher median concentration (2.5%-23.06%) of THMs compared to winter.

PERANGKAT KERAS ( HARDWARE ) PADA KOMPUTER

2020 ◽  
Author(s):  
Siti Kumala Dewi
Keyword(s):  
Processing System ◽  
Central Processing Unit ◽  
Input Device ◽  
Processing Unit ◽  
Central Processing ◽  
Output Device ◽  
System P ◽  
System 2

Perangkat keras komputer adalah bagian dari sistem komputer sebagai perangkat yang dapat diraba, dilihat secara fisik, dan bertindak untuk menjalankan instruksi dari perangkat lunak (software). Perangkat keras komputer juga disebut dengan hardware. Hardware berperan secara menyeluruh terhadap kinerja suatu sistem komputer. Berdasarkan fungsinya, perangkat keras terbagi menjadi :1.Sistem Perangkat Keras Masukan (Input Device System )2.Sistem Pemrosesan ( Central Processing System/ Central Processing Unit(CPU)3.Sistem Perangkat Keras Keluaran ( Output Device System )4.Sistem Perangkat Keras Tambahan (Peripheral/Accessories Device System)

Eco-friendly and fast bromination of industrially-important aromatic compounds in water using recyclable AlBr3-Br2 system

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Aromatic Compounds ◽  
Molecular Bromine ◽  
Economical Method ◽  
System P

A fast, efficient, simple, eco-friendly, regioselective, controllable and economical method for the bromination of aromatic compounds using AlBr3-Br2 system was invetigated. The direct bromination of anilines and phenols with molecular bromine in solution frequently results in polybromination, and when brominated in the existence of oxidants, they also get oxidized rather than experiencing substitutions and in some cases, require fortification of the amino (-NH2) group.

PIll Dispenser Alert System

2017 ◽  
Author(s):  
marco arambula
Keyword(s):  
Alert System ◽  
System P

A pill dispensing system that has an annoying alarm to make sure the user has to get up to take their pills

Identity concerns drive belief: The impact of partisan identity on the belief and dissemination of true and false news

2018 ◽  
Author(s):  
Andrea Pereira ◽  
Jay Joseph Van Bavel ◽  
Elizabeth Ann Harris
Keyword(s):  
Social Media ◽  
Political System ◽  
Political Identity ◽  
Social Goals ◽  
Fake News ◽  
Political Beliefs ◽  
System P ◽  
False News ◽  
Democrats And Republicans ◽  
The Impact

Political misinformation, often called “fake news”, represents a threat to our democracies because it impedes citizens from being appropriately informed. Evidence suggests that fake news spreads more rapidly than real news—especially when it contains political content. The present article tests three competing theoretical accounts that have been proposed to explain the rise and spread of political (fake) news: (1) the ideology hypothesis— people prefer news that bolsters their values and worldviews; (2) the confirmation bias hypothesis—people prefer news that fits their pre-existing stereotypical knowledge; and (3) the political identity hypothesis—people prefer news that allows their political in-group to fulfill certain social goals. We conducted three experiments in which American participants read news that concerned behaviors perpetrated by their political in-group or out-group and measured the extent to which they believed the news (Exp. 1, Exp. 2, Exp. 3), and were willing to share the news on social media (Exp. 2 and 3). Results revealed that Democrats and Republicans were both more likely to believe news about the value-upholding behavior of their in-group or the value-undermining behavior of their out-group, supporting a political identity hypothesis. However, although belief was positively correlated with willingness to share on social media in all conditions, we also found that Republicans were more likely to believe and want to share apolitical fake new. We discuss the implications for theoretical explanations of political beliefs and application of these concepts in in polarized political system.

Tracking development with Baby CROINC: The interplay of parent experience, usage, and technology approach (Preprint)

2018 ◽  
Author(s):  
Ayelet Ben-Sasson ◽  
Eli Ben-Sasson ◽  
Kayla Jacobs ◽  
Rotem Malinovitch
Keyword(s):  
Developmental Screening ◽  
Technology Competence ◽  
Proactive Approach ◽  
Crowd Wisdom ◽  
System P ◽  
Parent Experience ◽  
Wide Range ◽  
Actual Use ◽  
Perceived Usability ◽  
Crowd Intelligence

BACKGROUND To lower barriers to developmental screening, we designed Baby CROINC (CROwd INtelligence Curation), a digital platform to help parents track and assess their children’s development through crowd wisdom. OBJECTIVE To understand users’ experiences using Baby CROINC in relation to users’ technological competence and attitudes, while considering the influence of their children’s presented developmental evaluations and parents’ actual use of the system. METHODS Mothers of 260 children (M age= 17.6 months, SD=13.7) used Baby CROINC for two weeks. They entered developmental milestones on their children’s developmental diary timeline and received statistical developmental percentile reports. Mothers then completed Usability and Technology Profile Questionnaires. RESULTS Mothers’ experiences of the Baby CROINC system usability were associated with their attitudes toward solving technological problems, mediated by frequency of engagement in Internet activities. Mothers with a proactive approach toward solving technology problems, engage in a wide range of Internet activities, and/or view the Internet as integral to their lives had a better experience with Baby CROINC than mothers who did not. The system’s perceived usability was not associated with the crowd-based child developmental percentiles or quantity of mothers’ usage of the system. CONCLUSIONS Parent’s user experiences correlate with their technology competence and problem solving attitude but is not correlated with their child’s developmental status. Developmental screening platforms need to solve the tension between requiring active engagement and encouraging proactive parenting.

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