PVP-derived carbon nanofibers harvesting enhanced anode performance for lithium ion batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (5) ◽  
pp. 4193-4199 ◽  
Author(s):  
Litian Dong ◽  
Guowen Wang ◽  
Xifei Li ◽  
Dongbin Xiong ◽  
Bo Yan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Carbon Nanofibers ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance

Co-embedded carbon nanofibers were synthesized using electrospinning with polyvinylpyrrolidone instead of high cost polyacrylonitrile. The nanocomposites deliver enhanced cycling performance and rate capability in lithium ion batteries.

scholarly journals A Cellulose-Derived Nanofibrous MnO2-TiO2-Carbon Composite as Anodic Material for Lithium-Ion Batteries

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3411
Author(s):  
Shun Li ◽  
Ming Yang ◽  
Guijin He ◽  
Dongmei Qi ◽  
Jianguo Huang
Keyword(s):  
Lithium Ion Batteries ◽  
Carbon Nanofibers ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Carbon Composite ◽  
Electrochemical Performances ◽  
Mno2 Nanosheets ◽  
Specific Discharge ◽  
Extraction Processes

A bio-inspired nanofibrous MnO2-TiO2-carbon composite was prepared by utilizing natural cellulosic substances (e.g., ordinary quantitative ashless filter paper) as both the carbon source and structural matrix. Mesoporous MnO2 nanosheets were densely immobilized on an ultrathin titania film precoated with cellulose-derived carbon nanofibers, which gave a hierarchical MnO2-TiO2-carbon nanoarchitecture and exhibited excellent electrochemical performances when used as an anodic material for lithium-ion batteries. The MnO2-TiO2-carbon composite with a MnO2 content of 47.28 wt % exhibited a specific discharge capacity of 677 mAh g−1 after 130 repeated charge/discharge cycles at a current rate of 100 mA g−1. The contribution percentage of MnO2 in the composite material is equivalent to 95.1% of the theoretical capacity of MnO2 (1230 mAh g−1). The ultrathin TiO2 precoating layer with a thickness ca. 2 nm acts as a crucial interlayer that facilitates the growth of well-organized MnO2 nanosheets onto the surface of the titania-carbon nanofibers. Due to the interweaved network structures of the carbon nanofibers and the increased content of the immobilized MnO2, the exfoliation and aggregation, as well as the large volume change of the MnO2 nanosheets, are significantly inhibited; thus, the MnO2-TiO2-carbon electrodes displayed outstanding cycling performance and a reversible rate capability during the Li+ insertion/extraction processes.

Building sponge-like robust architectures of CNT–graphene–Si composites with enhanced rate and cycling performance for lithium-ion batteries

2015 ◽  
Vol 3 (7) ◽  
pp. 3962-3967 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Fathy M. Hassan ◽  
Matthew Li ◽  
Kun Feng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycling Stability ◽  
Great Promise ◽  
Practical Applications ◽  
Excellent Cycling Stability

High-performance robust CNT–graphene–Si composites are designed as anode materials with enhanced rate capability and excellent cycling stability for lithium-ion batteries. Such an improvement is mainly attributed to the robust sponge-like architecture, which holds great promise in future practical applications.

Synthesis and Electrochemical Performance of SnO2/Graphene Hybrid Anode for Lithium Ion Batteries

2013 ◽  
Vol 1540 ◽  
Author(s):  
Chia-Yi Lin ◽  
Chien-Te Hsieh ◽  
Ruey-Shin Juang
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Homogeneous Distribution

ABSTRACTAn efficient microwave-assisted polyol (MP) approach is report to prepare SnO2/graphene hybrid as an anode material for lithium ion batteries. The key factor to this MP method is to start with uniform graphene oxide (GO) suspension, in which a large amount of surface oxygenate groups ensures homogeneous distribution of the SnO2 nanoparticles onto the GO sheets under the microwave irradiation. The period for the microwave heating only takes 10 min. The obtained SnO2/graphene hybrid anode possesses a reversible capacity of 967 mAh g-1 at 0.1 C and a high Coulombic efficiency of 80.5% at the first cycle. The cycling performance and the rate capability of the hybrid anode are enhanced in comparison with that of the bare graphene anode. This improvement of electrochemical performance can be attributed to the formation of a 3-dimensional framework. Accordingly, this study provides an economical MP route for the fabrication of SnO2/graphene hybrid as an anode material for high-performance Li-ion batteries.

Co3Sn2/SnO2 nanocomposite loaded on Cu foam as high-performance three-dimensional anode for lithium-ion batteries

2019 ◽  
Vol 43 (3) ◽  
pp. 1238-1246 ◽  
Author(s):  
Duo Zhang ◽  
Chaoqi Bi ◽  
Qingliu Wu ◽  
Guangya Hou ◽  
Guoqu Zheng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Tin Dioxide ◽  
Three Dimensional ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cu Foam ◽  
Low Rate

It is a challenge to commercialize tin dioxide-based anodes for lithium-ion batteries due to their low rate capability and poor cycling performance of the electrodes.

Firework-shaped TiO2 microspheres embedded with few-layer MoS2 as an anode material for excellent performance lithium-ion batteries

2015 ◽  
Vol 3 (12) ◽  
pp. 6392-6401 ◽  
Author(s):  
Bangjun Guo ◽  
Ke Yu ◽  
Hao Fu ◽  
Qiqi Hua ◽  
Ruijuan Qi ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Composite Electrode ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Excellent Performance ◽  
Tio2 Microspheres ◽  
Novel Strategy

Firework-shaped TiO2 microspheres embedded with few-layer MoS2 are prepared by a novel strategy, and the composite electrode exhibits excellent cycling performance, high capacity and rate capability compared to pure MoS2 and TiO2 electrodes.

Hierarchical NiCoO2 nanosheets supported on amorphous carbon nanotubes for high-capacity lithium-ion batteries with a long cycle life

2014 ◽  
Vol 2 (32) ◽  
pp. 13069-13074 ◽  
Author(s):  
Xin Xu ◽  
Bitao Dong ◽  
Shujiang Ding ◽  
Chunhui Xiao ◽  
Demei Yu
Keyword(s):  
Carbon Nanotubes ◽  
Lithium Ion Batteries ◽  
Amorphous Carbon ◽  
Anode Materials ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Cycle Life ◽  
Long Cycle Life

NiCoO2 nanosheets@amorphous CNT composites show enhanced cycling performance and rate capability as anode materials for lithium-ion batteries.

High-Performance Anode Materials with Superior Structure of Fe3O4/FeS/rGO Composite for Lithium Ion Batteries

NANO ◽  
2020 ◽  
Vol 15 (10) ◽  
pp. 2050128 ◽  
Author(s):  
Ruirui Gao ◽  
Suqin Wang ◽  
Zhaoxiu Xu ◽  
Hongbo Li ◽  
Shuiliang Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Composite Electrode ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Charging And Discharging Processes ◽  
New Perspective

In this work, we developed a simple one-step hydrothermal method to successfully prepare Fe3O4/FeS-reduced graphene oxide (Fe3O4/FeS/rGO) composite directly, which is a novel Lithium-ion batteries (LIBs) anode material. The characterization of Fe3O4/FeS/rGO composite demonstrates that octahedral Fe3O4/FeS particles are uniformly deposited on the rGO, leading to a strong synergy between them. The excellent structural design can make Fe3O4/FeS/rGO composite to have higher reversible capacity (744.7[Formula: see text]mAh/g at 0.1[Formula: see text]C after 50 cycles), excellent cycling performance and superior rate capability. This outstanding electrochemical behavior can be attributed to the conductivity network of rGO, which improves the composite electrode conductivity, facilitates the diffusion and transfer of ions and prevents the aggregation and pulverization of Fe3O4/FeS particles during the charging and discharging processes. Moreover, the Fe3O4/FeS/rGO electrode surface is covered with a thin solid-electrolyte interface (SEI) film and the octahedral structure of Fe3O4/FeS particles is still clearly visible, which indicates that composite electrode has excellent interface stability. We believe that the design of this composite structure will provide a new perspective for the further study of other transition metal oxides for LIBs.

SnSb–ZnO composite materials as high performance anodes for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (128) ◽  
pp. 105643-105650 ◽  
Author(s):  
Yongliang Li ◽  
Wei Zhang ◽  
Huihua Cai ◽  
Jingwei Wang ◽  
Xiangzhong Ren ◽  
...  
Keyword(s):  
Composite Materials ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Alloy Anode

The addition of ZnO significantly improved the cycling performance and rate capability of SnSb alloy anode material.

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