New understanding on the reaction pathways of the polyacrylonitrile copolymer fiber pre-oxidation: online tracking by two-dimensional correlation FTIR spectroscopy

RSC Advances ◽  
2016 ◽  
Vol 6 (6) ◽  
pp. 4397-4409 ◽  
Author(s):  
Jing Zhao ◽  
Jihai Zhang ◽  
Tao Zhou ◽  
Xifei Liu ◽  
Qiang Yuan ◽  
...  

FTIR spectroscopy in combination with scaling-MW2D and 2D correlation analysis is used to study the reaction pathways of polyacrylonitrile copolymer fibers pre-oxidation.

RSC Advances ◽  
2017 ◽  
Vol 7 (74) ◽  
pp. 47017-47028 ◽  
Author(s):  
Bai Xue ◽  
Lan Xie ◽  
Junhua Zhang

The sequential order of the groups' movement and the microdynamics mechanism of PLLA cold-crystallization are successfully investigated.


2014 ◽  
Vol 1069 ◽  
pp. 176-182 ◽  
Author(s):  
Hideyuki Shinzawa ◽  
Kosuke Hashimoto ◽  
Hidetoshi Sato ◽  
Wataru Kanematsu ◽  
Isao Noda

2019 ◽  
Vol 21 (39) ◽  
pp. 21882-21889 ◽  
Author(s):  
Meng Cheng ◽  
Shengtong Sun ◽  
Peiyi Wu

A microdynamic mechanism of moisture-induced ACC crystallization involving three consecutive conversion stages is elucidated via in situ FTIR spectroscopy and two-dimensional correlation analysis.


ACS Catalysis ◽  
2015 ◽  
Vol 5 (6) ◽  
pp. 3588-3599 ◽  
Author(s):  
Qisong Xu ◽  
LiangFeng Guo ◽  
Tung Nguyen Dinh ◽  
Angie Cheong ◽  
Marc Garland

2002 ◽  
Vol 56 (12) ◽  
pp. 1562-1567 ◽  
Author(s):  
Young Mee Jung ◽  
Hyeon Suk Shin ◽  
Seung Bin Kim ◽  
Isao Noda

The direct combination of chemometrics and two-dimensional (2D) correlation spectroscopy is considered. The use of a reconstructed data matrix based on the significant scores and loading vectors obtained from the principal component analysis (PCA) of raw spectral data is proposed as a method to improve the data quality for 2D correlation analysis. The synthetic noisy spectra were analyzed to explore the novel possibility of the use of PCA-reconstructed spectra, which are highly noise suppressed. 2D correlation analysis of this reconstructed data matrix, instead of the raw data matrix, can significantly reduce the contribution of the noise component to the resulting 2D correlation spectra.


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