scholarly journals Signal transduction and amplification through enzyme-triggered ligand release and accelerated catalysis

2015 ◽  
Vol 6 (8) ◽  
pp. 4978-4985 ◽  
Author(s):  
Sean Goggins ◽  
Barrie J. Marsh ◽  
Anneke T. Lubben ◽  
Christopher G. Frost
Keyword(s):  
Signal Transduction ◽  
Signal Amplification ◽  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Enzyme Substrate ◽  
Amplification Cascade

An enzyme-triggered catalytic signal amplification cascade is described through the design of a novel enzyme substrate that selectively activates an organometallic transfer hydrogenation catalyst once triggered.

N-Benzyl Substituted N-Heterocyclic Carbene Complexes of Iridium(I): Assessment in Transfer Hydrogenation Catalyst

2013 ◽  
Vol 52 (18) ◽  
pp. 10601-10609 ◽  
Author(s):  
Süleyman Gülcemal ◽  
Aytaç Gürhan Gökçe ◽  
Bekir Çetinkaya
Keyword(s):  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Carbene Complexes

scholarly journals Carbohydrate-functionalized N-heterocyclic carbene Ru(ii) complexes: synthesis, characterization and catalytic transfer hydrogenation activity

2019 ◽  
Vol 48 (31) ◽  
pp. 11838-11847 ◽  
Author(s):  
Joseph P. Byrne ◽  
Pauline Musembi ◽  
Martin Albrecht
Keyword(s):  
Metal Complex ◽  
Hybrid System ◽  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Catalytic Transfer Hydrogenation ◽  
Hydrogenation Activity ◽  
Catalytic Transfer

Triazolylidene NHCs decorated with a carbohydrate wingtip group were complexed to a ruthenium(ii) center. Deprotection of the carbohydrate in the metal complex affords a carbohydrate–NHC hybrid system for use as a transfer hydrogenation catalyst.

Ultra dispersed cobalt anchored on nitrogen-doping ordered porous carbon as an efficient transfer hydrogenation catalyst

2019 ◽  
Vol 491 ◽  
pp. 544-552 ◽  
Author(s):  
Longkang Zhang ◽  
Junmin Wang ◽  
Ningzhao Shang ◽  
Shutao Gao ◽  
Yongjun Gao ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Nitrogen Doping ◽  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Ordered Porous ◽  
Efficient Transfer

scholarly journals Ir-Catalyzed Reduction of Carbonyl Compounds Using Biogenetic Alcohols

Inorganics ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 114 ◽  
Author(s):  
Yuta Nishina
Keyword(s):  
Carbonyl Compounds ◽  
Fossil Fuel ◽  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Present System ◽  
Aliphatic Aldehydes ◽  
Catalytic Systems

Biomass has gained great attention as an alternative to fuel-derived chemicals. This report concerns new catalytic systems consisting of [IrCp*Cl2]2 (Cp*: Pentamethylcyclopentadienyl) for the reduction of aldehyde and biogenetic alcohols as hydrogen sources. [IrCp*Cl2]2 has been used as a transfer hydrogenation catalyst using fossil fuel-derived alcohols as hydrogen sources in the presence of a base. In contrast, our system does not require any base, and the reaction can proceed in water. Various types of biogenetic alcohols can be used as hydrogen sources, such as monosaccharides, oligosaccharides, and glycerol. Aromatic and aliphatic aldehydes, as well as ketones, were successfully reduced to the corresponding alcohols in the present system.

ChemInform Abstract: Synthesis and Evaluation of a Chiral Heterogeneous Transfer Hydrogenation Catalyst.

ChemInform ◽  
2010 ◽  
Vol 29 (45) ◽  
pp. no-no
Author(s):  
D. J. BAYSTON ◽  
C. B. TRAVERS ◽  
M. E. C. POLYWKA
Keyword(s):  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst

Ruthenium Phenylindenyl Complex as an Efficient Transfer Hydrogenation Catalyst

2012 ◽  
Vol 354 (16) ◽  
pp. 3036-3044 ◽  
Author(s):  
Simone Manzini ◽  
César A. Urbina Blanco ◽  
Steven P. Nolan
Keyword(s):  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst ◽  
Efficient Transfer

Synthesis and evaluation of a chiral heterogeneous transfer hydrogenation catalyst

1998 ◽  
Vol 9 (12) ◽  
pp. 2015-2018 ◽  
Author(s):  
Daniel J Bayston ◽  
Catherine B Travers ◽  
Mario E.C Polywka
Keyword(s):  
Transfer Hydrogenation ◽  
Hydrogenation Catalyst
Sign in / Sign up

Export Citation Format

Share Document