Highly porous graphitic carbon and Ni2P2O7 for a high performance aqueous hybrid supercapacitor

2015 ◽  
Vol 3 (43) ◽  
pp. 21553-21561 ◽  
Author(s):  
Baskar Senthilkumar ◽  
Ziyauddin Khan ◽  
Seungyoung Park ◽  
Kyoungho Kim ◽  
Hyunhyub Ko ◽  
...  

A high energy hybrid capacitor fabricated from highly porous graphitic carbon and novel electrode material Ni2P2O7 delivers a maximum energy density of 65 W h kg−1 at a power density of 800 W kg−1, good rate capability and cycling stability in an aqueous Na-ion based electrolyte.

RSC Advances ◽  
2017 ◽  
Vol 7 (55) ◽  
pp. 34488-34496 ◽  
Author(s):  
Chong Chen ◽  
Dengfeng Yu ◽  
Gongyuan Zhao ◽  
Lei Sun ◽  
Yinyong Sun ◽  
...  

Developing supercapacitors with high energy density without sacrificing the power density and cycle life has attracted enormous attention.


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Fuwei Liu ◽  
Luoyuan Xie ◽  
Li Wang ◽  
Wei Chen ◽  
Wei Wei ◽  
...  

AbstractMany hybrid electrodes for supercapacitors (SCs) are a reckless combination without proper structural design that keeps them from fulfilling their potential. Herein, we design a reduced graphene oxide/poly(3,4-ethylenedioxythiophene)/polyaniline (RGO/PEDOT/PANI) hybrid with hierarchical and porous structure for high-performance SCs, where components fully harness their advantages, forming an interconnected and conductive framework with substantial reactive sites.Thus, this hybrid achieves a high capacitance of 535 F g−1 along with good rate capability and cyclability. The planar SC based on this hybrid deliver an energy density of 26.89 Wh kg−1 at a power density of 800 W kg−1. The linear SC developed via modifying a cotton yarn with the hybrid exhibits good flexibility and structural stability, which operates normally after arbitrary deformations. This work provides a beneficial reference for developing SCs.


2019 ◽  
Vol 6 (10) ◽  
pp. 2788-2800 ◽  
Author(s):  
Hanmei Jiang ◽  
Yifu Zhang ◽  
Chen Wang ◽  
Qiushi Wang ◽  
Changgong Meng ◽  
...  

Mn3O4/manganese silicate/C nanostructured composites were synthesized using rice husks and the hybrid supercapacitor realizes a maximum energy density of 13.3 W h kg−1 at 103.9 W kg−1 and super stability.


2018 ◽  
Vol 6 (9) ◽  
pp. 4003-4012 ◽  
Author(s):  
Chong Qu ◽  
Lei Zhang ◽  
Wei Meng ◽  
Zibin Liang ◽  
Bingjun Zhu ◽  
...  

α-NiS/rGO nanohybrids synthesized from water-refluxed Ni-MOF-74/rGO were applied as a high-performance hybrid supercapacitor positive electrode for the first time.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Qiulong Wei ◽  
Qidong Li ◽  
Yalong Jiang ◽  
Yunlong Zhao ◽  
Shuangshuang Tan ◽  
...  

AbstractHigh-performance and low-cost sodium-ion capacitors (SICs) show tremendous potential applications in public transport and grid energy storage. However, conventional SICs are limited by the low specific capacity, poor rate capability, and low initial coulombic efficiency (ICE) of anode materials. Herein, we report layered iron vanadate (Fe5V15O39 (OH)9·9H2O) ultrathin nanosheets with a thickness of ~ 2.2 nm (FeVO UNSs) as a novel anode for rapid and reversible sodium-ion storage. According to in situ synchrotron X-ray diffractions and electrochemical analysis, the storage mechanism of FeVO UNSs anode is Na+ intercalation pseudocapacitance under a safe potential window. The FeVO UNSs anode delivers high ICE (93.86%), high reversible capacity (292 mAh g−1), excellent cycling stability, and remarkable rate capability. Furthermore, a pseudocapacitor–battery hybrid SIC (PBH-SIC) consisting of pseudocapacitor-type FeVO UNSs anode and battery-type Na3(VO)2(PO4)2F cathode is assembled with the elimination of presodiation treatments. The PBH-SIC involves faradaic reaction on both cathode and anode materials, delivering a high energy density of 126 Wh kg−1 at 91 W kg−1, a high power density of 7.6 kW kg−1 with an energy density of 43 Wh kg−1, and 9000 stable cycles. The tunable vanadate materials with high-performance Na+ intercalation pseudocapacitance provide a direction for developing next-generation high-energy capacitors.


Author(s):  
Huixiang Yin ◽  
Dongdong Li ◽  
Zhenzhen Chi ◽  
Qian Zhang ◽  
Xiaoqiang Liu ◽  
...  

Rechargeable Li–O2 batteries have attracted worldwide attention due to super-high energy density. However, there are still many critical challenges for Li–O2 batteries, such as huge overpotential caused by sluggish oxygen...


2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Kyeong-Nam Kang ◽  
Ananthakumar Ramadoss ◽  
Jin-Wook Min ◽  
Jong-Chul Yoon ◽  
Deokjung Lee ◽  
...  

Abstract We report a wire-shaped three-dimensional (3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites, easy access of electrolyte ions, and facile charge transport for flexible wearable applications. The interconnected and compact electrode delivers a high volumetric capacitance (gravimetric capacitance) of 73 F cm−3 (2446 F g−1), excellent rate capability, and cycle stability. The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire (NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire (Mn3O4/3D-Ni) hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1. The red light-emitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions. The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times, for smart wearable and implantable devices.


2020 ◽  
Vol 8 (42) ◽  
pp. 22163-22174
Author(s):  
Ze Yuan ◽  
Haiyan Wang ◽  
Junling Shen ◽  
Pengcheng Ye ◽  
Jiqiang Ning ◽  
...  

Hierarchical Cu2S@NiCo-LDH double-shelled nanotube arrays (Cu2S@NiCo-LDH DSNAs) are prepared by a multi-step approach, and the fabricated Cu2S@NiCo-LDH DSNAs//NPC hybrid supercapacitor exhibits a high energy density and remarkable rate capability.


RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 37562-37573 ◽  
Author(s):  
Yufeng An ◽  
Zhongai Hu ◽  
Bingshu Guo ◽  
Ning An ◽  
Yadi Zhang ◽  
...  

Through the matching of the honeycomb-shaped NiCo2O4/CC (HSNC) and reduced graphene oxide/carbon cloth (rGO/CC) to obtain the binder-free asymmetric electrochemical capacitor with high energy density good rate capability and excellent cycle life.


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