A robust and luminescent covalent organic framework as a highly sensitive and selective sensor for the detection of Cu2+ions

2016 ◽  
Vol 52 (39) ◽  
pp. 6613-6616 ◽  
Author(s):  
Zhongping Li ◽  
Yuwei Zhang ◽  
Hong Xia ◽  
Ying Mu ◽  
Xiaoming Liu

A highly crystalline and porous azine-linked covalent organic framework possesses excellent stability and luminescence properties with high quantum yield. It can serve as a promising luminescent probe for selectively sensing copper ions.




2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>





Author(s):  
Jinmeng Xiang ◽  
Xiaoqi Zhao ◽  
Hao Suo ◽  
Minkun Jin ◽  
Xue Zhou ◽  
...  

Controlling the light environment of plant growth using phosphor-converted light-emitting diodes (pc-LEDs) is an important means to regulate the growth rhythm and enhance the yield, in which bluish violet light...





2014 ◽  
Vol 2 (41) ◽  
pp. 8678-8682 ◽  
Author(s):  
Guojun Gao ◽  
Jingxue Wei ◽  
Yang Shen ◽  
Mingying Peng ◽  
Lothar Wondraczek

We employ a statistical approach to estimate the number of photoluminescence quenching species as a function of doping concentration.





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