Governing metal–organic frameworks towards high stability

Stability of MOFs is a crucial issue for their practical applications, which might be improved by varying their chemical composition and/or structurally tuning them. Several strategies for enhancing the stability of MOFs were provided.

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Nanocomposite Synthesis Strategies Based on the Transformation of Well-Tailored Metal–Organic Frameworks

Chemical Communications ◽

10.1039/d1cc01989a ◽

2021 ◽

Author(s):

Jae Hwa Lee ◽

Min Hyuk Kim ◽

Hoi Ri Moon

Keyword(s):

Chemical Composition ◽

Metal Organic Frameworks ◽

Practical Applications ◽

Metal Organic ◽

Significant Attention

Increasing the complexity of nanomaterials in terms of their structure and chemical composition has attracted significant attention, because it can yield unique scientific outcomes and considerable improvements for practical applications....

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A Sr 2+ -metal–organic framework with high chemical stability: synthesis, crystal structure and photoluminescence property

Philosophical Transactions of The Royal Society A Mathematical Physical and Engineering Sciences ◽

10.1098/rsta.2016.0026 ◽

2017 ◽

Vol 375 (2084) ◽

pp. 20160026 ◽

Cited By ~ 4

Author(s):

Yan-Yuan Jia ◽

Xiao-Ting Liu ◽

Wen-He Wang ◽

Li-Zhu Zhang ◽

Ying-Hui Zhang ◽

...

Keyword(s):

Chemical Stability ◽

Metal Organic Framework ◽

Metal Organic Frameworks ◽

Photoluminescence Property ◽

Environment Friendly ◽

Crystalline Materials ◽

Practical Applications ◽

Square Channel ◽

Metal Organic ◽

The Stability

Metal–organic frameworks (MOFs) are typically built by assembly of metal centres and organic linkers, and have emerged as promising crystalline materials in a variety of fields. However, the stability of MOFs is a key limitation for their practical applications. Herein, we report a novel Sr 2+ -MOF [Sr 4 (Tdada) 2 (H 2 O) 3 (DMF) 2 ] (denoted as NKU- 105 , NKU = Nankai University; H 4 Tdada = 5,5'-((thiophene-2,5-dicar bonyl)bis(azanediyl))diisophthalic acid; DMF = N,N -dimethylformamide) featuring an open square channel of about 6 Å along the c -axis. Notably, NKU- 105 exhibits much outstanding chemical stability against common organic solvents, boiling water, acids and bases, relative to most MOF materials. Furthermore, NKU- 105 is an environment-friendly luminescent material with a bright cyan emission. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

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Porphyrin MOF-Derived Porous Carbons: Preparation and Applications

C – Journal of Carbon Research ◽

10.3390/c7020047 ◽

2021 ◽

Vol 7 (2) ◽

pp. 47

Author(s):

Flávio Figueira ◽

Filipe A. Almeida Paz

Keyword(s):

Chemical Composition ◽

Carbon Material ◽

Metal Organic Frameworks ◽

Electrochemical Reactions ◽

Porous Carbon Material ◽

Important Class ◽

Porous Carbons ◽

Preparation Methods ◽

Crystalline Materials ◽

Metal Organic

Metal–organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.

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Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

Dalton Transactions ◽

10.1039/d0dt04338a ◽

2021 ◽

Author(s):

Xinyao Liu ◽

Yunling Liu

Keyword(s):

Building Block ◽

High Stability ◽

Recent Progress ◽

Metal Organic Frameworks ◽

Excellent Performance ◽

Design And Synthesis ◽

Molecular Building Block ◽

Secondary Building Units ◽

Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

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Binder-Free mechanochemical metal-organic framework nanocrystal coatings

Nanoscale ◽

10.1039/d1nr08377e ◽

2022 ◽

Author(s):

Rijia Lin ◽

Yuqi Yao ◽

Muhammad Yazid Bin Zulkifli ◽

Xuemei Li ◽

Shuai Gao ◽

...

Keyword(s):

Metal Organic Framework ◽

Metal Organic Frameworks ◽

Practical Applications ◽

Metal Organic ◽

Binder Free ◽

Organic Framework

The practical applications of metal-organic frameworks (MOFs) usually require their assembly into mechanically robust structures, usually achieved via coating onto various types of substrates. This paper describes a simple, scalable,...

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The Rise of Metal-Organic Frameworks for Electrolyte Applications

Journal of Materials Chemistry A ◽

10.1039/d1ta05201b ◽

2021 ◽

Author(s):

Xia Hu ◽

Qi Liu ◽

Kui Lin ◽

Cuipang Han ◽

Baohua Li

Keyword(s):

Chemical Composition ◽

Pore Structure ◽

Metal Organic Frameworks ◽

Surface Functionality ◽

Metal Organic

Metal−organic frameworks (MOFs) have been attracting a great attention for application in electrolytes. Benefiting from the controllable chemical composition, tunable pore structure and surface functionality, MOFs offer great opportunities for...

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Ti4(embonate)6 Cage-Ligand Strategy on the Construction of Metal–Organic Frameworks with High Stability and Gas Sorption Properties

Inorganic Chemistry ◽

10.1021/acs.inorgchem.9b03075 ◽

2020 ◽

Vol 59 (2) ◽

pp. 964-967 ◽

Cited By ~ 2

Author(s):

Yan-Ping He ◽

Guang-Hui Chen ◽

Lv-Bing Yuan ◽

Lei Zhang ◽

Jian Zhang

Keyword(s):

High Stability ◽

Metal Organic Frameworks ◽

Sorption Properties ◽

Gas Sorption ◽

Metal Organic

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Poly(ionic liquid)-Modified Metal Organic Framework for Carbon Dioxide Adsorption

Polymers ◽

10.3390/polym12020370 ◽

2020 ◽

Vol 12 (2) ◽

pp. 370 ◽

Cited By ~ 2

Author(s):

Guangyuan Yang ◽

Jialin Yu ◽

Sanwen Peng ◽

Kuang Sheng ◽

Haining Zhang

Keyword(s):

Carbon Dioxide ◽

Ionic Liquid ◽

Composite Materials ◽

Metal Organic Frameworks ◽

Carbon Dioxide Partial Pressure ◽

Carbon Dioxide Adsorption ◽

Solid Sorbent ◽

Practical Applications ◽

Metal Organic ◽

Poly Ionic Liquid

The design and synthesis of solid sorbents for effective carbon dioxide adsorption are essential for practical applications regarding carbon emissions. Herein, we report the synthesis of composite materials consisting of amine-functionalized imidazolium-type poly(ionic liquid) (PIL) and metal organic frameworks (MOFs) through complexation of amino groups and metal ions. The carbon dioxide adsorption behavior of the synthesized composite materials was evaluated using the temperature-programmed desorption (TPD) technique. Benefiting from the large surface area of metal organic frameworks and high carbon dioxide diffusivity in ionic liquid moieties, the carbon dioxide adsorption capacity of the synthesized composite material reached 19.5 cm3·g−1, which is much higher than that of pristine metal organic frameworks (3.1 cm3·g−1) under carbon dioxide partial pressure of 0.2 bar at 25 °C. The results demonstrate that the combination of functionalized poly(ionic liquid) with metal organic frameworks can be a promising solid sorbent for carbon dioxide adsorption.

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