Metal-complex chromophores for solar hydrogen generation

2017 ◽  
Vol 46 (3) ◽  
pp. 603-631 ◽  
Author(s):  
Yong-Jun Yuan ◽  
Zhen-Tao Yu ◽  
Da-Qin Chen ◽  
Zhi-Gang Zou

Photoactive metal-complexes with applications in solar energy harvesting have been receiving profound research interest. We present in this exciting area the recent development of metal-complex chromophores as sensitizers and supramolecular photocatalysts to facilitate the conversion of solar energy into chemical hydrogen fuel.

Author(s):  
J. Nowotny ◽  
T. N. Veziroglu

The present work considers the impact of hydrogen fuel on the environment within the cycles of its generation and combustion. Hydrogen has been portrayed by the media as a fuel that is environmentally clean because its combustion results in the formation of harmless water. However, hydrogen first must be generated. The effect of hydrogen generation on the environment depends on the production process and the related byproducts. Hydrogen available on the market at present is mainly generated by using steam reforming of natural gas, which is a fossil fuel. Its byproduct is CO2, which is a greenhouse gas and its emission results in global warming and climate change. Therefore, hydrogen generated from fossil fuels is contributing to global warming to the similar extent as direct combustion of the fossil fuels. On the other hand hydrogen obtained from renewable energy, such solar energy, is environmentally clean during the cycles of its generation and combustion. Consequently, the introduction of hydrogen economy must be accompanied by the development of hydrogen that is environmentally friendly. The present work considers several aspects related to the generation and utilisation of hydrogen obtained by steam reforming and solar energy conversion (solar-hydrogen).


2014 ◽  
Vol 5 (7) ◽  
pp. 2363 ◽  
Author(s):  
Egle Puodziukynaite ◽  
Li Wang ◽  
Kirk S. Schanze ◽  
John M. Papanikolas ◽  
John R. Reynolds

Author(s):  
Tin Wai Mui ◽  
Jianxin Yang ◽  
Yajun Lin ◽  
Yong Zhou ◽  
Yanqi Zheng ◽  
...  

2021 ◽  
Author(s):  
Bowen Ding ◽  
Bun Chan ◽  
Nicholas Proschogo ◽  
Marcello Solomon ◽  
Cameron Kepert ◽  
...  

Innovative and robust photosensitisation materials play a cardinal role in advancing the combined effort towards efficient solar energy harvesting. Here, we demonstrate the photocathode functionality of a Metal-Organic Framework (MOF)...


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