C3-symmetry Mo3S4 aminophosphino clusters combining three sources of stereogenicity: stereocontrol directed by hydrogen bond interactions and ligand configuration
The reaction between Mo3S4Cl4(PPh)3(H2O)2 and (R)-PPro or (S)-PPro is diastereoselective towards the (P)-Mo3S4 configuration with the preservation of the aminophosphine chirality and the formation of a stereogenic nitrogen center.
2012 ◽
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