Interfacial shear strength characterization of GMA-grafted UHMWPE fiber/epoxy/nano clay hybrid nanocomposite materials

RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 41793-41799 ◽  
Author(s):  
Mohammad Mohammadalipour ◽  
Mahmood Masoomi ◽  
Mojtaba Ahmadi ◽  
Somayeh Safi

Interfacial properties of glycidyl methacrylate grafted ultra-high molecular weight polyethylene fibers and nano clay/epoxy resin were characterized by a microdroplet test.

2018 ◽  
Vol 774 ◽  
pp. 54-59
Author(s):  
Janis Andersons ◽  
I. Filipova ◽  
Mikelis Kirpluks ◽  
Ugis Cabulis

Nanocellulose in the form of whiskers and nanofibers has become a promising reinforcement material for polymer composites due to its high mechanical characteristics and sustainability. For optimization of composite properties, efficient means of characterization of the stress transfer between fibrous nanofiller and the polymer matrix are needed. In the current work, the apparent interfacial shear strength (IFSS) of cellulose nanofiber/PVA is evaluated by a modified Bowyer and Bader method based on an analysis of the stress–strain curve of a composite film in uniaxial tension. The IFSS is found to exceed shear yield strength of the neat polymer, suggesting good adhesion.


2018 ◽  
Vol 8 (3) ◽  
pp. 3038-3040
Author(s):  
N. Zaman ◽  
S. Ahmed ◽  
M. Sanaullah ◽  
A. U. Rehman ◽  
A. R. Shar ◽  
...  

Synthesis and characterization of polyester nanocomposites was conducted in order to fabricate hybrid composite materials of polyester/montmorillonite (MMT). Polyester based polymeric nanocomposite materials were synthesized by incorporating MMT nanoclay to produce polyester/MMT hybrid materials. Successful efforts were made to fabricate hybrid nanocomposite materials based on matrix (polyester based) and reinforcement (organoclay) through sonication at 6 and 12 hours. Synthesized nanocomposite polymers (polyester/MMT) showed different properties when compared to the properties of MMT and polyester, which confirmed the successful fabrication of the desired material. The finest incorporation of polyester with MMT was verified by UV-Visible spectrophotometer, Fourier tranform-infrared (FTIR) and scanning electron microscopy (SEM). The disappearance of the Si-O characteristic peak was observed in the FTIR spectrum justifying the fabrication of the desired composite materials. Colored SEM images were used to confirm the fine homogenous distribution of organoclay. Black SEM images showed the matrix and reinforcement together. SEM, FTIR and UV-Visible spectroscopic techniques were used to analyze polyester based nanocomposite materials and organoclay was found randomly distributed in the polymeric matrix whereas on the surface was observed to be mostly uniform.


Author(s):  
K. S. Kanaga Karuppiah ◽  
Sriram Sundararajan ◽  
Zhi-Hui Xu ◽  
Xiaodong Li

Ultra-high molecular weight polyethylene (UHMWPE) is a popular choice for the liner material of the acetabular cup and forms one of the articulating surfaces in total joint replacements (TJRs). Evaluating the tribological characteristics of UHMWPE on immediate contact with the physiological fluid is essential to understand pathways and mechanisms of eventual failure. In this study, the friction response and interfacial shear strength of a UHMWPE - ceramic interface was quantified using atomic force microscopy (AFM) before and after exposure to bovine serum albumin (BSA) solution. A 10% protein solution concentration was used to closely mimic protein levels in human physiological fluid. Medical grade UHMWPE samples with two different surface finishing treatments, milling and melting/reforming were used in the experiments. Friction response as a function of normal load was monitored on a particular area on each sample. Fluorescence microscopy was used to assess the protein adsorption on the test area. The interfacial shear strength of the interface was calculated from the friction data using contact mechanics. Contact angle measurements were also performed on the surfaces to evaluate the surface energies before and after protein adsorption. Correlations between the friction behavior and surface energy of the surfaces are discussed.


Wear ◽  
2019 ◽  
Vol 436-437 ◽  
pp. 203042 ◽  
Author(s):  
Tanmaya Mishra ◽  
Matthijn de Rooij ◽  
Meghshyam Shisode ◽  
Javad Hazrati ◽  
Dirk J. Schipper

2013 ◽  
Vol 750-752 ◽  
pp. 840-844 ◽  
Author(s):  
Yao Ke Wen ◽  
Cheng Xu ◽  
Xue Hua Dong ◽  
Shu Wang

Ultra-high molecular weight polyethylene (UHMWPE) fiber reinforced plastic (UFRP) is an integral part of hard body armor. The intensive study on the material characterization of UFRP can help to understanding the bulletproof mechanism and behind-armor blunt trauma (BABT) well, and thus improve the performance of body armor. The research presented in this paper represents an effort to characterize the properties of UFRP under quasi-static and ballistic loading. The tensile behavior along the fiber direction and through thickness compressive behavior were obtained using an universal material testing machine. Experiments show that the tensile strength and compressive strength of UFRP are approximately 500MPa and 650MPa, respectively. The through thickness shear strength of UFRP was also obtained according to the punch-shear testing, and a set of special clamp was used to clamp the samples. The composite has been found to have a low shear strength. The UFRP was impacted by a 4.8mm diameter spherical fragment with velocity 694m/s~920m/s, to study the ballistic performance. And the height and radius of the deformed conical region on the back face of UFRP were captured using high-speed photography technique. Results show the maximum transient height of the cone is about 3 to 4 times greater than the final height of the cone, and the radius of the cone reaches to 59±7.4mm. The ballistic limit of the 11mm thick UFRP is approximately 800m/s.


1989 ◽  
Vol 153 ◽  
Author(s):  
A. Ozzello ◽  
D. S. Grummon ◽  
L. T. Drzal ◽  
J. Kalantar ◽  
I-H. Loh ◽  
...  

AbstractUltra-high molecular weight polyethylene fibers possess exceptional strength and stiffness combined with low density. Their use as reinforcements in polymer matrix composites has, however, been limited by poor fiber adhesion. In the present study, individual fibers of UHMW-PE (Allied-Signal SPECTRA-1000) were modified by direct implantation of N+, Ti+ and Ar+ ions, at energies between 30 and 100 KeV, to doses ranging between 1x1014 and lx1015 ions/cm2. Fiber tensile strength was generally unaffected by these irradiations. Single-fiber droplet pull-off tests using DGEBA Epoxy with m-PDA curing agent have shown that ion beam surface modification of the fibers can give an increase of over 300% in interfacial shear strength (ISS). The improvements were found to vary with dose but were relatively insensitive to implant species. TEM observation of transverse microtomed sections confirmed a substantial improvement in fiber-matrix adhesion for ion beam modified UHMW-PE composites.


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