Tb-MOF: a naked-eye and regenerable fluorescent probe for selective and quantitative detection of Fe3+and Al3+ions

RSC Advances ◽  
2016 ◽  
Vol 6 (97) ◽  
pp. 94622-94628 ◽  
Author(s):  
Mengfei Zhang ◽  
Jing Han ◽  
Haipeng Wu ◽  
Qing Wei ◽  
Gang Xie ◽  
...  

A unique Tb-MOF fluorescent probe has features that are visible to the naked-eye and can be regenerated; it presents high selectivity and sensitivity to the quantitative detection of Fe3+and Al3+ions.

RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 60546-60549 ◽  
Author(s):  
Lubna Rasheed ◽  
Muhammad Yousuf ◽  
Il Seung Youn ◽  
Genggongwo Shi ◽  
Kwang S. Kim

A novel anthraquinone-imidazole based colorimetric and fluorogenic probe 1 discriminates the oxidation states of Pd0 and Pd2+ by naked eye with high selectivity in aqueous media due to the difference in coordination in the pocket of probe molecule.


2020 ◽  
Vol 44 (7-8) ◽  
pp. 475-481
Author(s):  
Dan Wu ◽  
Yi Liu ◽  
Fei Zheng ◽  
Shi-Qi Rong ◽  
Tao Yang ◽  
...  

Taking advantages of both the well-known α,β-unsaturated structure and the special nucleophilicity of organic amines toward its acceptor moieties, intramolecular charge transfer as a signaling mechanism is used to design and synthesize a new ratiometric chromophoric fluorescent probe (BI-CA-ID) with large emission shifts toward organic amines. This probe is employed for the detection of organic amines with high selectivity and sensitivity and a “naked-eye” color change (from red to colorless). Ultraviolet–visible and fluorescence spectrometric measurements are used to determine detection limits as low as 0.024 and 0.43 μM. Furthermore, nucleophilic addition of the amine on the α,β-unsaturated of BI-CA-ID indicated that the sensing mechanism occurs via interruption of the π-conjugation.


2019 ◽  
Vol 11 (26) ◽  
pp. 3280-3285 ◽  
Author(s):  
Zhen Huang ◽  
Cuiyan Wu ◽  
Yaqian Li ◽  
Zile Zhou ◽  
Ruihua Xie ◽  
...  

A turn-on fluorescent probe for cysteine with high selectivity was designed and synthetized. The probe can be used for “naked-eye” detection of Cys with an obvious color change from yellow to colorless. The probe could be applied for Cys detection in real human serum.


2019 ◽  
Vol IV (I) ◽  
pp. 1-10
Author(s):  
Urooj Naseem ◽  
Ayesha Ayub ◽  
Fatima Iqbal ◽  
Farhan Sohail

Different methods are adopted for the quantitative detection of chemicals in the blood. One of which is discussed here, i.e., the fluorescent probes that are preferred in biological systems owing to their sensitivity, high selectivity, elevated spatiotemporal resolution, and noninvasiveness. In recent years, for the identification of various chemicals, a large number of probes have been designed. For the detection as well as identification of fluorescent probes, sulfides, different chemicals such as iron, glucose, glutathione etc., in the blood are discussed. The maximum detection limits of newly synthesized fluorescent probes for different chemical analysis are studied and comparatively analyzed. Different parameters like pH, incubation time, mixing time, the detection limit of the fluorescent probes is also explored.


2021 ◽  
Author(s):  
Shanzhu Zhang ◽  
Yunlan Gu ◽  
Zongqian Shi ◽  
Nan Lu ◽  
Hai-Yan Xu

A new Schiff base fluorescent probe NBP derived from the one-step condensation strategy of 2-butyl-6-hydroxy-1,3-dioxo-2,3-dihydro-1H-benzo[de]isoquinoline-5-carbaldehyde and N-(2-(hydrazinecarbonyl)phenyl)benzamide was synthesized and characterized. NBP exhibited high selectivity toward Al3+ along with naked-eye...


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zhenlong Guo ◽  
YiFei Su ◽  
Kexin Li ◽  
MengYi Tang ◽  
Qiang Li ◽  
...  

AbstractThe development of detecting residual level of abamectin B1 in apples is of great importance to public health. Herein, we synthesized a octopus-like azobenzene fluorescent probe 1,3,5-tris (5′-[(E)-(p-phenoxyazo) diazenyl)] benzene-1,3-dicarboxylic acid) benzene (TPB) for preliminary detection of abamectin B1 in apples. The TPB molecule has been characterized by ultraviolet–visible absorption spectrometry, 1H-nuclear magnetic resonance, fourier-transform infrared (FT-IR), electrospray ionization mass spectroscopy (ESI-MS) and fluorescent spectra. A proper determination condition was optimized, with limit of detection and limit of quantification of 1.3 µg L−1 and 4.4 μg L−1, respectively. The mechanism of this probe to identify abamectin B1 was illustrated in terms of undergoing aromatic nucleophilic substitution, by comparing fluorescence changes, FT-IR and ESI-MS. Furthermore, a facile quantitative detection of the residual abamectin B1 in apples was achieved. Good reproducibility was present based on relative standard deviation of 2.2%. Six carboxyl recognition sites, three azo groups and unique fluorescence signal towards abamectin B1 of this fluorescent probe demonstrated reasonable sensitivity, specificity and selectivity. The results indicate that the octopus-like azobenzene fluorescent probe can be expected to be reliable for evaluating abamectin B1 in agricultural foods.


RSC Advances ◽  
2020 ◽  
Vol 10 (36) ◽  
pp. 21399-21405
Author(s):  
Chunwei Yu ◽  
Shuhua Cui ◽  
Yuxiang Ji ◽  
Shaobai Wen ◽  
Li Jian ◽  
...  

In this study, a naphthalene Schiff-base P which serves as a dual-analyte probe for the quantitative detection of Al3+ and Mg2+ has been designed.


2021 ◽  
Author(s):  
Nian Rao ◽  
Yi Le ◽  
Dan Li ◽  
Yan Zhang ◽  
Qin Wang ◽  
...  

Lab on a Chip ◽  
2017 ◽  
Vol 17 (19) ◽  
pp. 3240-3245 ◽  
Author(s):  
Zichen Zhao ◽  
Yuanye Bao ◽  
Lok Ting Chu ◽  
John Kin Lim Ho ◽  
Ching-Chang Chieng ◽  
...  

We demonstrate a microfluidic bead trap capable of forming a dipstick-type bar visible to the naked eye for simple and quantitative detection of oligonucleotides.


Author(s):  
Zhanxian Li ◽  
Haixia Li ◽  
Caixia Shi ◽  
Mingming Yu ◽  
Liuhe Wei ◽  
...  

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