Flower-like ZnO@MnCo2O4 nanosheet structures on nickel foam as novel electrode material for high-performance supercapacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 102961-102967 ◽  
Author(s):  
Chandu V. V. M. Gopi ◽  
Mallineni Venkata-Haritha ◽  
Soo-Kyoung Kim ◽  
Kandasamy Prabakar ◽  
Hee-Je Kim
Keyword(s):  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance

The flower-like ZnO@MnCo2O4 nanosheet electrode exhibited high specific capacitance than dandelion-like MnCo2O4.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

Copolymer derived micro/meso-porous carbon nanofibers with vacancy-type defects for high-performance supercapacitors

2020 ◽  
Vol 8 (5) ◽  
pp. 2463-2471 ◽  
Author(s):  
Jiye Li ◽  
Weimiao Zhang ◽  
Xu Zhang ◽  
Liyao Huo ◽  
Jiayi Liang ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
Carbon Nanofibers ◽  
Electrode Material ◽  
Porous Carbon ◽  
High Performance ◽  
High Specific Capacitance ◽  
Cycling Stability ◽  
Supercapacitor Electrode ◽  
Excellent Cycling Stability

Micro/meso-porous carbon nanofibers have been successfully prepared and directly adopted as a supercapacitor electrode material with high specific capacitance, area normalized capacitance and excellent cycling stability.

Design and synthesis of hierarchical NiCo2S4@NiMoO4core/shell nanospheres for high-performance supercapacitors

2015 ◽  
Vol 39 (11) ◽  
pp. 8430-8438 ◽  
Author(s):  
Mingming Yao ◽  
Zhonghua Hu ◽  
Yafei Liu ◽  
Peipei Liu
Keyword(s):  
Specific Capacitance ◽  
Hydrothermal Method ◽  
Current Density ◽  
Electrode Material ◽  
High Performance ◽  
Three Dimensional ◽  
High Specific Capacitance ◽  
Core Shell ◽  
Design And Synthesis ◽  
A Current

A novel electrode material of three-dimensional hierarchical NiCo2S4@NiMoO4core/shell nanospheres was synthesized by a facile two-step hydrothermal method. These hierarchical NiCo2S4@NiMoO4core/shell nanospheres exhibit a high specific capacitance of 1714 F g−1at a current density of 1 A g−1, which indicated the excellent electrochemistry performance.

One-step Synthesis of O-self-doped Honeycomb-like Hierachically Porous Carbons for Supercapacitors

2021 ◽  
pp. 1-19
Author(s):  
Shiying Lin ◽  
Lanlan Mo ◽  
Feijun Wang
Keyword(s):  
Electrode Material ◽  
Porous Carbon ◽  
High Performance ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
Electrode System ◽  
Porous Carbon Material ◽  
Hierarchical Porous ◽  
One Step ◽  
Porous Carbon Electrode

Abstract A facile and environmentally friendly approach to produce self-doped hierachically porous carbon as electrode material for high-performance supercapacitor was demonstrated. 3D honeycomb-like hierarchically porous carbon was successfully obtained by one-step carbonization and activation of sodium carboxymethyl cellulose (CMC) via K2CO3. With the optimized temperature of carbonization and activation, the porous carbon material achieved well-shaped hierarchically pores (micro-, meso and macropores) like a honeycomb, ultrahigh specific surface area (1666 m2·g-1), as well as highly O-self-doping (3.6 at.%), endowing an excellent electrochemical properties for the electrode in three-electrode system. The porous carbon electrode material delivered a high specific capacitance of 300.8 F·g-1 at 1 A·g-1, an eminent rate capability of 228.4 F·g-1 at the current density up to 20 A·g-1 and outstanding cycle stability of 94.3% retention after 10000 cycles. Therefore, the CMC derived hierarchical porous carbon activated by K2CO3 would have promising foreground in application of supercapacitors.

Manganese silicate drapes as a novel electrode material for supercapacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105771-105779 ◽  
Author(s):  
Hong-Yan Wang ◽  
Yue-Ya Wang ◽  
Xue Bai ◽  
Huan Yang ◽  
Jian-Ping Han ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
Electrode Material ◽  
High Specific Capacitance ◽  
Rate Performance ◽  
Hydrothermal Time ◽  
Manganese Silicate

Manganese silicate drapes (hydrothermal time of 3 h) exhibit high specific capacitance and excellent rate performance.

scholarly journals Atomic Modulation of 3D Conductive Frameworks Boost Performance of MnO2 for Coaxial Fiber-Shaped Supercapacitors

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Xiaona Wang ◽  
Zhenyu Zhou ◽  
Zhijian Sun ◽  
Jinho Hah ◽  
Yagang Yao ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Superior Performance ◽  
High Mass ◽  
Mass Loading ◽  
Energy Storage Devices ◽  
Free Standing ◽  
Cell Potential

Abstract Coaxial fiber-shaped supercapacitors are a promising class of energy storage devices requiring high performance for flexible and miniature electronic devices. Yet, they are still struggling from inferior energy density, which comes from the limited choices in materials and structure used. Here, Zn-doped CuO nanowires were designed as 3D framework for aligned distributing high mass loading of MnO2 nanosheets. Zn could be introduced into the CuO crystal lattice to tune the covalency character and thus improve charge transport. The Zn–CuO@MnO2 as positive electrode obtained superior performance without sacrificing its areal and gravimetric capacitances with the increasing of mass loading of MnO2 due to 3D Zn–CuO framework enabling efficient electron transport. A novel category of free-standing asymmetric coaxial fiber-shaped supercapacitor based on Zn0.11CuO@MnO2 core electrode possesses superior specific capacitance and enhanced cell potential window. This asymmetric coaxial structure provides superior performance including higher capacity and better stability under deformation because of sufficient contact between the electrodes and electrolyte. Based on these advantages, the as-prepared asymmetric coaxial fiber-shaped supercapacitor exhibits a high specific capacitance of 296.6 mF cm−2 and energy density of 133.47 μWh cm−2. In addition, its capacitance retention reaches 76.57% after bending 10,000 times, which demonstrates as-prepared device’s excellent flexibility and long-term cycling stability.

Biowaste-derived 3D honeycomb-like porous carbon with binary-heteroatom doping for high-performance flexible solid-state supercapacitors

2018 ◽  
Vol 6 (1) ◽  
pp. 160-166 ◽  
Author(s):  
Yuxi Liu ◽  
Zechuan Xiao ◽  
Yongchang Liu ◽  
Li-Zhen Fan
Keyword(s):  
Solid State ◽  
Electrode Material ◽  
Porous Carbon ◽  
High Performance ◽  
High Specific Capacitance ◽  
High Energy ◽  
Cyclic Stability ◽  
Large Specific Surface Area ◽  
Heteroatom Doping ◽  
Co Doped

N and S-co-doped activated corncob sponge of honeycomb-like porous carbon with the interconnected micro-meso-macropores and the large specific surface area was evaluated as an electrode material for flexible solid-state supercapacitors, exhibiting high specific capacitance, high energy–power density, and great cyclic stability.

Ultrathin Nanosheets-Assembled Nickel-Based Metal-Organic Framework Microflowers for Supercapacitor Application

2022 ◽  
Author(s):  
Chong-Huan Wang ◽  
Da-Wei Zhang ◽  
Shude Liu ◽  
Yusuke Yamauchi ◽  
Fei-Bao Zhang ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
Metal Organic Framework ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
Supercapacitor Application ◽  
Ultrathin Nanosheets ◽  
Metal Organic ◽  
Organic Framework

Herein, we propose a solvent-assisted approach for preparing Ni-MOF microflowers with high specific capacitance and excellent rate capability as an electrode material for supercapacitors. Such high electrochemical performance is attributed...

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