Fabrication of highly dispersed/active ultrafine Pd nanoparticle supported catalysts: a facile solvent-free in situ dispersion/reduction method

2017 ◽  
Vol 19 (11) ◽  
pp. 2646-2652 ◽  
Author(s):  
Yu Shen ◽  
Xiangkun Bo ◽  
Zhengfang Tian ◽  
Yongzheng Wang ◽  
Xiangke Guo ◽  
...  

The development of sustainable routes for the synthesis of noble metal supported catalysts is of high importance because of their wide applications on a large scale in the catalysis field.

RSC Advances ◽  
2016 ◽  
Vol 6 (113) ◽  
pp. 112193-112200 ◽  
Author(s):  
Shengyang Tao ◽  
Huan Wang ◽  
Huilong Wang

We present an in situ reduction strategy to prepare mesoporous silica supported by highly-dispersed noble metals.


2008 ◽  
pp. 4186 ◽  
Author(s):  
Susannah L. Scott ◽  
Brian C. Peoples ◽  
Cathleen Yung ◽  
René S. Rojas ◽  
Vikram Khanna ◽  
...  

Nanoscale ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 3663-3667 ◽  
Author(s):  
Chunpeng Xiang ◽  
Yanhua Xiao ◽  
Hang Bai ◽  
Xia Yin ◽  
Meng Peng ◽  
...  

Controllable and recyclable fabrication of a highly dispersed/active Pd/Al2O3-CARM catalyst at 50 °C by introducing M2+ (M = Mn, Zn or Cu) ions to promote the reduction of Pd2+ in ethylene glycol–water solution.


Author(s):  
J. Liu ◽  
M. Pan ◽  
G. E. Spinnler

Small metal particles have peculiar chemical and physical properties as compared to bulk materials. They are especially important in catalysis since metal particles are common constituents of supported catalysts. The structural characterization of small particles is of primary importance for the understanding of structure-catalytic activity relationships. The shape and size of metal particles larger than approximately 5 nm in diameter can be determined by several imaging techniques. It is difficult, however, to deduce the shape of smaller metal particles. Coherent electron nanodiffraction (CEND) patterns from nano particles contain information about the particle size, shape, structure and defects etc. As part of an on-going program of STEM characterization of supported catalysts we report some preliminary results of CEND study of Ag nano particles, deposited in situ in a UHV STEM instrument, and compare the experimental results with full dynamical simulations in order to extract information about the shape of Ag nano particles.


Author(s):  
Yaru Li ◽  
Yu-Quan Zhu ◽  
Weili Xin ◽  
Song Hong ◽  
Xiaoying Zhao ◽  
...  

Rationally designing low-content and high-efficiency noble metal nanodots offers opportunities to enhance electrocatalytic performances for water splitting. However, the preparation of highly dispersed nanodots electrocatalysts remains a challenge. Herein, we...


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