Hot plasmonic electron-driven catalytic reactions on patterned metal–insulator–metal nanostructures

Nanoscale ◽  
2017 ◽  
Vol 9 (32) ◽  
pp. 11667-11677 ◽  
Author(s):  
Sun Mi Kim ◽  
Changhwan Lee ◽  
Kalyan C. Goddeti ◽  
Jeong Young Park

We fabricated two-dimensional (2D) arrays of metal–insulator–metal (MIM) plasmonic nanoislands designed to efficiently shuttle hot plasmonic electrons. These MIM nanostructures exhibit higher catalytic activity under light irradiation, revealing a significant impact on the catalytic activity for CO oxidation.

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 2097
Author(s):  
Yuan-Fong Chou Chau ◽  
Chung-Ting Chou Chao ◽  
Siti Zubaidah Binti Haji Jumat ◽  
Muhammad Raziq Rahimi Kooh ◽  
Roshan Thotagamuge ◽  
...  

This work proposed a multiple mode Fano resonance-based refractive index sensor with high sensitivity that is a rarely investigated structure. The designed device consists of a metal–insulator–metal (MIM) waveguide with two rectangular stubs side-coupled with an elliptical resonator embedded with an air path in the resonator and several metal defects set in the bus waveguide. We systematically studied three types of sensor structures employing the finite element method. Results show that the surface plasmon mode’s splitting is affected by the geometry of the sensor. We found that the transmittance dips and peaks can dramatically change by adding the dual air stubs, and the light–matter interaction can effectively enhance by embedding an air path in the resonator and the metal defects in the bus waveguide. The double air stubs and an air path contribute to the cavity plasmon resonance, and the metal defects facilitate the gap plasmon resonance in the proposed plasmonic sensor, resulting in remarkable characteristics compared with those of plasmonic sensors. The high sensitivity of 2600 nm/RIU and 1200 nm/RIU can simultaneously achieve in mode 1 and mode 2 of the proposed type 3 structure, which considerably raises the sensitivity by 216.67% for mode 1 and 133.33% for mode 2 compared to its regular counterpart, i.e., type 2 structure. The designed sensing structure can detect the material’s refractive index in a wide range of gas, liquids, and biomaterials (e.g., hemoglobin concentration).


Author(s):  
Mallik M. R. Hussain ◽  
Zhengning Gao ◽  
Domenico de Ceglia ◽  
Maria A. Vincenti ◽  
Andrew Sarangan ◽  
...  

2014 ◽  
Vol 31 (2) ◽  
pp. 259 ◽  
Author(s):  
Joseph W. Haus ◽  
Domenico de Ceglia ◽  
Maria Antonietta Vincenti ◽  
Michael Scalora

2018 ◽  
Vol 54 (97) ◽  
pp. 13734-13737
Author(s):  
Sun Mi Kim ◽  
Jeong Ho Mun ◽  
Si Woo Lee ◽  
Hyesung An ◽  
Hyun You Kim ◽  
...  

The activity increased with increasing Pd content and the resultant synergistic activity is can be precisely tuned by varying the chemical composition.


2018 ◽  
Vol 3 (1) ◽  
pp. 1-10
Author(s):  
Catarina Dias ◽  
Luís M. Guerra ◽  
Paulo Aguiar ◽  
João Ventura

Present computer processing capabilities are becoming a restriction to meet modern technological needs. Therefore, approaches beyond the von Neumann computational architecture are imperative and the brain operation and structure are truly attractive models. Memristors are characterized by a nonlinear relationship between current history and voltage and were shown to present properties resembling those of biological synapses. Here, the use of metal-insulator-metal-based memristive devices in neural networks capable of simulating the learning and adaptation features present in mammal brains is discussed.


RSC Advances ◽  
2017 ◽  
Vol 7 (88) ◽  
pp. 56073-56080 ◽  
Author(s):  
Si Woo Lee ◽  
Changhwan Lee ◽  
Kalyan C. Goddeti ◽  
Sun Mi Kim ◽  
Jeong Young Park

Hot carriers generated from LSPR excitation of Au can transfer to Co3O4, thus enhancing the catalytic activity for CO oxidation.


2019 ◽  
Vol 125 (10) ◽  
pp. 105302
Author(s):  
M. M. R. Hussain ◽  
I. Agha ◽  
Z. Gao ◽  
D. de Ceglia ◽  
M. A. Vincenti ◽  
...  

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