scholarly journals Copper doped BaMnO3 perovskite catalysts for NO oxidation and NO2-assisted diesel soot removal

RSC Advances ◽  
2017 ◽  
Vol 7 (56) ◽  
pp. 35228-35238 ◽  
Author(s):  
Verónica Torregrosa-Rivero ◽  
Vicente Albaladejo-Fuentes ◽  
María-Salvadora Sánchez-Adsuar ◽  
María-José Illán-Gómez
Keyword(s):  
Perovskite Structure ◽  
Active Catalyst ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Redox Properties ◽  
No Oxidation ◽  
Perovskite Catalysts

BaMn0.7Cu0.3O3 is the most active catalyst for NO2 generation and soot oxidation. This behavior is a result of the enhancement of the redox properties of the catalyst due to the replacement of Mn(iii)/Mn(iv) by Cu(ii) in the perovskite structure.

scholarly journals Synthesis and Performance of Transition Metal Based Perovskite Catalysts for Diesel Soot Oxidation

2017 ◽  
Vol 12 (3) ◽  
pp. 469 ◽  
Author(s):  
Anupama Mishra ◽  
Ram Prasad
Keyword(s):  
Transition Metal ◽  
Perovskite Structure ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Total Oxidation ◽  
Intrinsic Factors ◽  
Diesel Soot Oxidation ◽  
Abo3 Perovskite ◽  
Perovskite Catalysts ◽  
And Performance

In present investigation, the effect of the intrinsic factors including the structure, nature of B-site ions in the four systems LaCoO3, LaNiO3, LaFeO3 and LaZnOy perovskite-type oxide catalysts, and the external factors of catalyst-soot contacting model, and the operating parameters such as air flow rate and temperature on the catalytic performances for the combustion of diesel soot were reported. The catalysts were characterized by XRD, FTIR, SEM, and N2-sorption. Activity of the catalyst for soot oxidation was evaluated on the basis of light off temperature characteristics Ti, T50 and T100. LaCoO3, LaFeO3 and LaNiO3 samples possessed the perovskite structure, and gave high activities for the total oxidation of soot below 445 oC. Whereas, LaZnOy catalyst was not indicating the ABO3 perovskite structure and existed as a mixture of metal oxides. The activity order in decreasing sequence of the catalyst was as follows: LaCoO3>LaFeO3>LaNiO3>LaZnOy. SEM pictures of the perovskite samples showed that the particles sizes were close to 100 nm. Copyright © 2017 BCREC GROUP. All rights reservedReceived: 2nd March 2017; Revised: 16th June 2017; Accepted: 12nd July 2017; Available online: 27th October 2017; Published regularly: December 2017How to Cite: Mishra, A., Prasad, R. (2017). Synthesis and Performance of Transition Metal Based Perovskite Catalysts for Diesel Soot Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3): 469-477 (doi:10.9767/bcrec.12.3.968.469-477) 

A novel catalyst for diesel soot oxidation

2005 ◽  
Vol 61 (3-4) ◽  
pp. 334-345 ◽  
Author(s):  
D. Uner ◽  
M.K. Demirkol ◽  
B. Dernaika
Keyword(s):  
Soot Oxidation ◽  
Diesel Soot ◽  
Diesel Soot Oxidation ◽  
Novel Catalyst

scholarly journals Nanostructure changes in diesel soot during NO2–O2 oxidation under diesel particulate filter-like conditions toward filter regeneration

2018 ◽  
Vol 20 (8-9) ◽  
pp. 953-966 ◽  
Author(s):  
Madhu Singh ◽  
Mek Srilomsak ◽  
Yujun Wang ◽  
Katsunori Hanamura ◽  
Randy Vander Wal
Keyword(s):  
Diesel Particulate Filter ◽  
Surface Oxidation ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Particulate Filter ◽  
Exhaust Gas ◽  
Fringe Analysis ◽  
Diesel Particulate ◽  
Oxidation Rates ◽  
Passive Regeneration

Development of the regeneration process on diesel particulate filters requires a better understanding of soot oxidation phenomena, especially its relation to soot nanostructure. Nitrogen dioxide (NO2) is known to play an essential role in passive regeneration by oxidizing soot at low temperatures, especially in the presence of oxygen (O2) in the exhaust. However, change in soot nanostructure due to oxidation by NO2–O2 mixtures has not received much attention. This work focuses on nanostructure evolution during passive regeneration of the diesel particulate filter by oxidation of soot at normal exhaust gas temperatures (300°C–400°C). High-resolution transmission electron microscopy of partially oxidized model carbons (R250, M1300, arc-generated soot) and diesel soot under NO2–O2 mixtures is used to investigate physical changes in nanostructure correlating with the material’s behavior during oxidation. Microscopy reveals the changing nanostructure of model carbons during oxidation while fringe analysis of the images points to the differences in the structural metrics of fringe length and tortuosity of the resultant structures. The variation in oxidation rates highlights the inter-dependence of the material’s reactivity with its structure. NO2 preferentially oxidizes edge-site carbon, promotes surface oxidation by altering the particle’s burning mode with increased overall reactivity of NO2+O2 resulting in inhibition of internal burning, typically observed by O2 at exhaust gas temperatures.

Low-temperature NO oxidation using lattice oxygen in Fe-site substituted SrFeO3−δ

2020 ◽  
Vol 22 (42) ◽  
pp. 24181-24190
Author(s):  
Kazuki Tamai ◽  
Saburo Hosokawa ◽  
Kazuo Kato ◽  
Hiroyuki Asakura ◽  
Kentaro Teramura ◽  
...  
Keyword(s):  
Fine Structure ◽  
Low Temperature ◽  
Lattice Oxygen ◽  
No Oxidation ◽  
Oxygen Release ◽  
X Ray ◽  
Absorption Fine ◽  
Perovskite Catalysts ◽  
X Ray Absorption

The dynamics of lattice oxygen release from perovskite catalysts during NO oxidation was investigated by dispersive X-ray absorption fine structure.

Synthesis and Catalytic Activity Studies of V/K/Ca and V/Ks/Ce Based Catalysts for Diesel Soot Oxidation

2007 ◽  
Vol 336-338 ◽  
pp. 1995-1998
Author(s):  
Yong Heng Zhang ◽  
Jian Zhong Xue
Keyword(s):  
Catalytic Activity ◽  
Catalytic Oxidation ◽  
Amorphous Phase ◽  
Porous Alumina ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Oxidation Activity ◽  
Diesel Soot Oxidation ◽  
Oxidation Onset Temperature ◽  
Catalyst Systems

The catalysts based on V/K/Ca and V/Ks/Ce systems for diesel soot catalytic oxidation were synthesized onto the porous alumina substrates. Both catalyst systems showed a good catalytic oxidation activity. The V/K/Ca system exhibited the lowest oxidation onset temperature (OOT) of about 359oC with a composition of V/K/Ca =1:1:0.1 where the V and Ca and/or K elements could form a kind of amorphous phase that determined the catalytic activity. The V/Ks/Ce system displayed the lowest OOT of about 350oC with a composition of V/Ks/Ce = 1:2:0.1 where the K2SO4 and K5V2O3(SO4)4 phases could contribute most to the catalytic activity.

scholarly journals Investigation of Copper-supported Ceria Nanofibers for Catalytic Oxidation of Diesel Soot

2021 ◽  
Author(s):  
Dan Bahadur Pal ◽  
Anupama Mishra
Keyword(s):  
Photoelectron Spectroscopy ◽  
Fixed Bed ◽  
Tubular Reactor ◽  
Soot Oxidation ◽  
Diesel Soot ◽  
Air Flow Rate ◽  
Reaction Conditions ◽  
Tight Contact ◽  
Diesel Soot Oxidation ◽  
Working Parameters

Abstract In the present research, CeO2 and CuO/CeO2 nanofibers were synthesized by electrospinning at 12 kV DC by maintaining a tip to collector distance of 10 cm. The morphology of the as-synthesized nanofibers was determined by scanning electron microscopy, and their elemental composition was verified by X-ray photoelectron spectroscopy. The activity of the prepared samples for diesel soot oxidation was determined in a bench-scale fixed bed tubular reactor, and effluent gases were analyzed by online gas chromatography. The variations of working parameters (air flow rate, catalyst-soot ratio, catalyst-soot contact type) were evaluated in a range to optimized reaction conditions for diesel soot oxidation. The catalyst with 40% CuO/CeO2 had the highest surface area, the smallest crystallite size, and the best activity for diesel soot oxidation (tight contact) at Tf = 318oC.

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