scholarly journals Comparative study of the strongest solid Lewis acids known: ACF and HS-AlF3

2018 ◽  
Vol 47 (46) ◽  
pp. 16461-16473 ◽  
Author(s):  
Beatriz Calvo ◽  
Clara Patricia Marshall ◽  
Thoralf Krahl ◽  
Jutta Kröhnert ◽  
Annette Trunschke ◽  
...  

Aluminium chlorofluoride (ACF) and high-surface aluminium fluoride (HS-AlF3) can be considered as solid superacids based on several surface characterization techniques presented here.

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1376
Author(s):  
Alex Quok An Teo ◽  
Lina Yan ◽  
Akshay Chaudhari ◽  
Gavin Kane O’Neill

Additive manufacturing of stainless steel is becoming increasingly accessible, allowing for the customisation of structure and surface characteristics; there is little guidance for the post-processing of these metals. We carried out this study to ascertain the effects of various combinations of post-processing methods on the surface of an additively manufactured stainless steel 316L lattice. We also characterized the nature of residual surface particles found after these processes via energy-dispersive X-ray spectroscopy. Finally, we measured the surface roughness of the post-processing lattices via digital microscopy. The native lattices had a predictably high surface roughness from partially molten particles. Sandblasting effectively removed this but damaged the surface, introducing a peel-off layer, as well as leaving surface residue from the glass beads used. The addition of either abrasive polishing or electropolishing removed the peel-off layer but introduced other surface deficiencies making it more susceptible to corrosion. Finally, when electropolishing was performed after the above processes, there was a significant reduction in residual surface particles. The constitution of the particulate debris as well as the lattice surface roughness following each post-processing method varied, with potential implications for clinical use. The work provides a good base for future development of post-processing methods for additively manufactured stainless steel.


2008 ◽  
Vol 14 (20) ◽  
pp. 6205-6212 ◽  
Author(s):  
Damien Dambournet ◽  
Gehan Eltanamy ◽  
Alexandre Vimont ◽  
Jean-Claude Lavalley ◽  
Jean-Michel Goupil ◽  
...  

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