Histidine-assisted synthesis of CeO2 nanoparticles for improving the catalytic performance of Pt-based catalysts in methanol electrooxidation

2018 ◽  
Vol 42 (22) ◽  
pp. 18159-18165 ◽  
Author(s):  
Shengdong Dai ◽  
Jinli Zhang ◽  
Yan Fu ◽  
Wei Li
Keyword(s):  
Oxygen Vacancies ◽  
Catalytic Performance ◽  
Ceo2 Nanoparticles ◽  
Methanol Electrooxidation ◽  
Pt Catalysts

Histidine-assisted CeO2 Pt catalysts with more oxygen vacancies are synthesized to improve the catalytic performance in methanol electrooxidation.

scholarly journals Influence of the Reduction Temperature and the Nature of the Support on the Performance of Zirconia and Alumina-Supported Pt Catalysts for n-Dodecane Hydroisomerization

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 88
Author(s):  
Diana García-Pérez ◽  
Maria Consuelo Alvarez-Galvan ◽  
Jose M. Campos-Martin ◽  
Jose L. G. Fierro
Keyword(s):  
Catalytic Activity ◽  
Surface Area ◽  
Catalytic Properties ◽  
Catalytic Performance ◽  
Major Influence ◽  
Pt Catalysts ◽  
Reduction Temperature ◽  
Metal Dispersion ◽  
Tungsten Oxides ◽  
Supported Pt Catalysts

Catalysts based on zirconia- and alumina-supported tungsten oxides (15 wt % W) with a small loading of platinum (0.3 wt % Pt) were selected to study the influence of the reduction temperature and the nature of the support on the hydroisomerization of n-dodecane. The reduction temperature has a major influence on metal dispersion, which impacts the catalytic activity. In addition, alumina and zirconia supports show different catalytic properties (mainly acid site strength and surface area), which play an important role in the conversion. The NH3-TPD profiles indicate that the acidity in alumina-based catalysts is clearly higher than that in their zirconia counterparts; this acidity can be attributed to a stronger interaction of the WOx species with alumina. The PtW/Al catalyst was found to exhibit the best catalytic performance for the hydroisomerization of n-dodecane based on its higher acidity, which was ascribed to its larger surface area relative to that of its zirconia counterparts. The selectivity for different hydrocarbons (C7–10, C11 and i-C12) was very similar for all the catalysts studied, with branched C12 hydrocarbons being the main products obtained (~80%). The temperature of 350 °C was clearly the best reduction temperature for all the catalysts studied in a trickled-bed-mode reactor.

scholarly journals The Catalytic Oxidation of Formaldehyde by FeOx-MnO2-CeO2 Catalyst: Effect of Iron Modification

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 555
Author(s):  
Yaxin Dong ◽  
Chenguang Su ◽  
Kai Liu ◽  
Haomeng Wang ◽  
Zheng Zheng ◽  
...  
Keyword(s):  
Low Temperatures ◽  
Oxygen Vacancies ◽  
Catalytic Performance ◽  
Active Oxygen ◽  
Molar Ratio ◽  
N2 Adsorption ◽  
Structure Activity ◽  
Iron Modification ◽  
Surface Active ◽  
Catalyst Effect

A series of FeOx-MnO2-CeO2 catalysts were synthesized by the surfactant-templated coprecipitation method and applied for HCHO removal. The influence of Fe/Mn/Ce molar ratio on the catalytic performance was investigated, and the FeOx-MnO2-CeO2 catalyst exhibited excellent catalytic activity, with complete HCHO conversion at low temperatures (40 °C) when the molar ratio of Fe/Mn/Ce was 2/5/5. The catalysts were characterized by N2 adsorption and desorption, XRD, H2-TPR, O2-TPD and XPS techniques to illustrate their structure–activity relationships. The result revealed that the introduction of FeOx into MnO2-CeO2 formed a strong interaction between FeOx-MnO2-CeO2, which facilitated the improved dispersion of MnO2-CeO2, subsequently increasing the surface area and aiding pore development. This promotion effect of Fe enhanced the reducibility and produced abundant surface-active oxygen. In addition, a great number of Oα is beneficial to the intermediate decomposition, whereas the existence of Ce3+ favors the formation of oxygen vacancies on the surface of the catalyst, all of which contributed to HCHO oxidation at low temperatures.

scholarly journals On the Effects of Doping on the Catalytic Performance of (La,Sr)CoO3. A DFT Study of CO Oxidation

Catalysts ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 312 ◽  
Author(s):  
Antonella Glisenti ◽  
Andrea Vittadini
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Density Functional Calculations ◽  
Density Functional ◽  
Formation Energy ◽  
Oxygen Vacancies ◽  
Catalytic Performance ◽  
Energy Profiles ◽  
High Concentrations ◽  
3D Impurities

The effects of modifying the composition of LaCoO3 on the catalytic activity are predicted by density functional calculations. Partially replacing La by Sr ions has benefical effects, causing a lowering of the formation energy of O vacancies. In contrast to that, doping at the Co site is less effective, as only 3d impurities heavier than Co are able to stabilize vacancies at high concentrations. The comparison of the energy profiles for CO oxidation of undoped and of Ni-, Cu-m and Zn-doped (La,Sr)CoO3(100) surface shows that Cu is most effective. However, the effects are less spectacular than in the SrTiO3 case, due to the different energetics for the formation of oxygen vacancies in the two hosts.

Remarkable promoting effects of BiOCl on the room-temperature selective oxidation of benzyl alcohol over supported Pt catalysts

2018 ◽  
Vol 42 (11) ◽  
pp. 8979-8984 ◽  
Author(s):  
Juanjuan Liu ◽  
Feng Han ◽  
Lingze Chen ◽  
Linfang Lu ◽  
Shihui Zou ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
Room Temperature ◽  
Catalytic Performance ◽  
Pt Catalysts ◽  
Oxidation Of Benzyl Alcohol ◽  
Supported Pt Catalysts

BiOCl, in addition to traditional Bi metal, could remarkably promote the catalytic performance of Pt/MOx in the selective oxidation of benzyl alcohol.

Ce0.8Sn0.2O2−–C composite as a co-catalytic support for Pt catalysts toward methanol electrooxidation

2014 ◽  
Vol 265 ◽  
pp. 335-344 ◽  
Author(s):  
Yu Gu ◽  
Chuntao Liu ◽  
Yabei Li ◽  
Xulei Sui ◽  
Kuo Wang ◽  
...  
Keyword(s):  
Methanol Electrooxidation ◽  
Pt Catalysts ◽  
Catalytic Support

Black TiO2−x with stable surface oxygen vacancies as the support of efficient gold catalysts for water-gas shift reaction

2018 ◽  
Vol 8 (5) ◽  
pp. 1277-1287 ◽  
Author(s):  
Lei Li ◽  
Li Song ◽  
Longfeng Zhu ◽  
Zheng Yan ◽  
Xuebo Cao
Keyword(s):  
Oxygen Vacancies ◽  
Electron Flow ◽  
Catalytic Performance ◽  
Water Gas Shift ◽  
Hot Electron ◽  
Surface Oxygen ◽  
Water Gas Shift Reaction ◽  
Black Tio2 ◽  
Shift Reaction ◽  
Water Gas

H2-etching engineered oxygen vacancies on black TiO2−x to enhance the hot-electron flow and water-gas shift catalytic performance of Au catalysts.

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