Next-generation flexible solid oxide fuel cells with high thermomechanical stability

2018 ◽  
Vol 6 (37) ◽  
pp. 18018-18024
Author(s):  
Ok Sung Jeon ◽  
Ho Jung Hwang ◽  
Oh Chan Kwon ◽  
Jin Goo Lee ◽  
Yong Gun Shul

Solid oxide cells (SOCs) convert chemical energy into electrical energy at high temperature with very high energy efficiency and fuel flexibility.

2011 ◽  
Vol 2011 (CICMT) ◽  
pp. 000009-000016
Author(s):  
Thomas Maeder ◽  
Bo Jiang ◽  
Yan Yan ◽  
Peter Ryser ◽  
Paul Muralt

Micro solid-oxide fuel cells (μ -SOFCs) based on microfabrication processes are a promising alternative to batteries for supplying portable electronics, as very high energy densities may be achieved. However, a complete μ -SOFC module is a quite intricate structure, comprising 1) a gas-processing unit (GPU) to process a convenient energy source such as lighter gas into a more usable form, 2) the energy-generating cells proper, and 3) a post-combustor. The mechanical integration of these elements and their fluidic and electrical interconnection into a single module is a very challenging task for micro-scale integration. Therefore, a modular low-temperature co-fired ceramic (LTCC) package is proposed, allowing individual testing and subsequent full integration of the different cell elements. The package functions as a hotplate, a mechanical support for the hot zone and as an electrical / fluidic interconnect, applying a slender-bridge design to minimise thermal conduction losses and stresses, thus allowing convenient low-temperature electrical connections and fluidic ports. For applications requiring a better thermal expansion match to silicon and borosilicate glass, a silicon / borosilicate glass-sealed variant was also developed. Preliminary thermal characterisation of these packages is shown, and concepts for integrating the GPU and post-combustor into the LTCC structure are presented.


2018 ◽  
Vol 30 ◽  
pp. 103-114 ◽  
Author(s):  
Jessica Grove-Smith ◽  
Vera Aydin ◽  
Wolfgang Feist ◽  
Jürgen Schnieders ◽  
Stefan Thomas

Author(s):  
Min Soo Kim ◽  
Young Sang Kim ◽  
Young Duk Lee ◽  
Minsung Kim ◽  
dongkyu Kim

Abstract This study analyzed the internal phenomena of solid oxide fuel cells driven by liquefied natural gas. Reforming reactions of liquefied natural gas constituent in the solid oxide fuel cells were examined. First, the performance of solid oxide fuel cells using liquefied natural gas was compared to those using methane as fuel. Liquefied natural gas-driven solid oxide fuel cells outperformed methane-driven solid oxide fuel cells under all current conditions, with a maximum performance difference of approximately 12.8%. Then, the effect of inlet composition ratio on the internal phenomena in the solid oxide fuel cells was examined. The lower the steam-to-carbon ratio, the higher the steam reforming reaction in the cell. By changing the ratio, 7.1% of more hydrogen could be reformed. Finally, the effect of reformer operation on the internal phenomena in the solid oxide fuel cells was examined. Under 0.35 A/cm2, lower pre-reforming rate of reformer enhance the performance of solid oxide fuel cells. At high current density region, however, a higher pre-reforming rate of reforming is more favorable because the reforming reaction is rare in solid oxide fuel cells. This research can provide guidelines for achieving high power output of solid oxide fuel cells with high fuel flexibility.


2020 ◽  
Vol 166 ◽  
pp. 04007
Author(s):  
Cevat Yaman ◽  
Yusuf Kucukaga

Generating electrical energy from landfill gas (LFG) is a challenge due to its low conversion efficiency. In this study, performance of a NiO/yttria-stabilized zirconia (NiO-YSZ) anode-supported cell operating with LFG feed stream was evaluated. This study investigated the potential of solid oxide fuel cells (SOFC) to produce electricity from LFG generated in pilot scale anaerobic municipal solid waste bioreactors. During the initial experiments, power generation was achieved in the SOFC with direct feeding of the LFG. Different feed flow rates (10 25 mL/min) and varying temperature conditions (700 800 °C) were also investigated to define the optimal conditions. Experiments were carried out at different feed rates and the successful results obtained from 10 mL/min and 20 mL/min feed speeds. It was also observed that the maximal power values were between 0.10 0.11 Watt/cm2 for all experiments. This study showed that SOFCs can provide significantly higher energy efficiencies than steam engines for LFG conversion into electrical energy.


2011 ◽  
Vol 13 (9) ◽  
pp. 959-962 ◽  
Author(s):  
Toshio Suzuki ◽  
Shinichi Sugihara ◽  
Toshiaki Yamaguchi ◽  
Hirofumi Sumi ◽  
Koichi Hamamoto ◽  
...  

2012 ◽  
Vol 727-728 ◽  
pp. 769-774
Author(s):  
A. Ávila ◽  
J. Poveda ◽  
D. Gómez ◽  
D. Hotza ◽  
J. Escobar

Solid oxide fuel cells (SOFCs) have emerged as an efficient way to transform chemical energy into electrical energy. However, a major disadvantage of this technology is related to the high temperatures required for SOFC operation. In this way, new materials are necessary to maintain the electrical properties of the cell at intermediate temperatures. Based on these ideas, it is necessary to study both the structural variation of the cells components at different temperatures and their electrochemical behavior. In this work, a crystallographic characterization is presented, which was performed in a commercial SOFC cell using X-ray diffraction (XRD). An equivalent linear electrical model to predict SOFC losses is developed as well. Keywords: Solid oxide fuel cells (SOFCs); AC impedance; Electrochemical impedance spectroscopy (EIS); Equivalent circuit models.


2013 ◽  
Author(s):  
William M. Harris ◽  
Jeffrey J. Lombardo ◽  
George J. Nelson ◽  
Wilson K. S. Chiu ◽  
Barry Lai ◽  
...  

Fuel flexibility is widely considered one of the most significant advantages of solid oxide fuel cells (SOFC). However, the presence of small amounts of sulfur or other impurities in the gas stream can have a serious impact on cell performance [1–10]. Under certain conditions, hydrogen sulfide (H2S), even at the ppm level, can lead to the formation of bulk nickel-sulfides within the conventional Ni–yttria-stabilized zirconia (Ni-YSZ) anode of SOFC’s [9]. Understanding the distribution of these sulfides is critical to describing their effects on the electrochemical activity of the cell.


2015 ◽  
Vol 1116 ◽  
pp. 190-201
Author(s):  
Md. Hasan Zahir

The generation of environmental-friendly energy is now one of the major demand of the world for healthy future. Fuel cell is one of the prime candidate in this regard which convert chemical energy of a fuel gas very efficiently and directly into electrical energy. This chapter describes the concept, impact of anode and electrolyte morphology, thickness, diameter, and fabrication of a micro-tubular solid oxide fuel cell (SOFC). The chapter describes the anode, cathode, and electrolyte of the cell components in more detail and their importance of each is regarding their size and thickness. Advantages of micro-tubular SOFCs with respect to the other fuel cell technologies are compared. The chapter describes the potential for directly running off hydrocarbon fuels and the design and operation of micro-tubular SOFCs on bio-fuel specifications and materials’ requirements. The chapter also discuss fabrication technology of micro-tubular single cell by using commercially available raw materials.


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