Highly dispersed ultrafine palladium nanoparticles encapsulated in a triazinyl functionalized porous organic polymer as a highly efficient catalyst for transfer hydrogenation of aldehydes

2018 ◽  
Vol 6 (37) ◽  
pp. 18242-18251 ◽  
Author(s):  
Jin Yang ◽  
Man Yuan ◽  
Dan Xu ◽  
Hong Zhao ◽  
Yangyang Zhu ◽  
...  

A stable Pd@TP-POP catalyst with highly dispersed ultrafine Pd NPs confined in its organic pores was fabricated for catalytic reduction of 4-nitrophenol and transfer hydrogenation of aromatic aldehydes under very mild conditions.

ChemCatChem ◽  
2018 ◽  
Vol 10 (6) ◽  
pp. 1431-1437 ◽  
Author(s):  
Caiyan Cui ◽  
Yujiao Tang ◽  
Muhammad Asad Ziaee ◽  
Dongxu Tian ◽  
Ruihu Wang

2020 ◽  
Vol 98 (8) ◽  
pp. 445-452
Author(s):  
Hamid Aliyan ◽  
Razieh Fazaeli

A novel, heterogeneous, and bifunctional metal organic framework containing palladium and manganese, Pd/APN-Mn(BTC), has been prepared and completely characterized using FTIR, XRD, SEM-EDS, N2 adsorption–desorption, TG-DTG, NH3-TPD, and ICP analytical techniques. The APN-Mn(BTC) framework has been shown to be a useful platform for the stabilization and support of palladium nanoparticles (Pd NPs). Very effective catalytic activity has been exhibited by the highly dispersed Pd particles, Pd-NPs/APN-Mn(BTC), in the Suzuki–Miyaura cross-coupling reaction with reasonable to excellent reaction yields under mild conditions in H2O–ethanol solvent.


2020 ◽  
Vol 8 (34) ◽  
pp. 17360-17391
Author(s):  
Rao Tao ◽  
Xiangran Ma ◽  
Xinlei Wei ◽  
Yinghua Jin ◽  
Li Qiu ◽  
...  

The state-of-the-art strategies for the directed growth and immobilization of palladium nanoparticles using porous organic polymers as supports are reviewed, with their catalytic applications discussed.


RSC Advances ◽  
2020 ◽  
Vol 10 (16) ◽  
pp. 9414-9419 ◽  
Author(s):  
Xianzhao Shao ◽  
Xinyi Miao ◽  
Xiaohu Yu ◽  
Wei Wang ◽  
Xiaohui Ji

Precise design of catalytic supports is an encouraging technique for simultaneously improving the activity and stability of the catalyst.


Nanoscale ◽  
2018 ◽  
Vol 10 (45) ◽  
pp. 21466-21474 ◽  
Author(s):  
Hong Zhao ◽  
Guiqin Yu ◽  
Man Yuan ◽  
Jin Yang ◽  
Dan Xu ◽  
...  

Highly dispersed ultrafine Pt nanoparticles were confined in a triazinyl-containing porous organic polymer for the catalytic hydrolysis of ammonia borane and the selective hydrogenation of halogenated nitrobenzenes with excellent catalytic activity.


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