Self-assembled CdS quantum dots in carbon nanotubes: induced polysulfide trapping and redox kinetics enhancement for improved lithium–sulfur battery performance

2019 ◽  
Vol 7 (2) ◽  
pp. 806-815 ◽  
Author(s):  
Dong Cai ◽  
Lili Wang ◽  
La Li ◽  
Yupu Zhang ◽  
Junzhi Li ◽  
...  

Self-assembled CdS-QDs in carbon nanotubes are highly efficient cathode materials for lithium–sulfur batteries with improved rate performance and cycle life. The configuration suppresses polysulfide shuttling and enhances redox kinetics.

2020 ◽  
Vol 31 (49) ◽  
pp. 495406
Author(s):  
Tianyu Shi ◽  
Chenyuan Zhao ◽  
Chuan Yin ◽  
Haihong Yin ◽  
Changqing Song ◽  
...  

Author(s):  
Zhihao Wang ◽  
zhihao zeng ◽  
Wei Nong ◽  
Zhen Yang ◽  
Chenze Qi ◽  
...  

Lithium sulfur battery is one of the most promising applicants for the next generation of energy storage devices whose commercial applications are impeded by the key issue of shuttle effect....


RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5516-5522 ◽  
Author(s):  
Shuangke Liu ◽  
Kai Xie ◽  
Yujie Li ◽  
Zhongxue Chen ◽  
Xiaobin Hong ◽  
...  

A graphene oxide sheet wrapped hierarchical porous carbon–sulfur (HPC–S@GO) composite was designed by a two-step method to improve the lithium sulfur battery performance.


2009 ◽  
Vol 1208 ◽  
Author(s):  
Kunio Shimura ◽  
DaeGwi Kim ◽  
Masaaki Nakayama

AbstractWe have investigated efficient energy transfer (ET) between CdS quantum dots (QDs) measuring photoluminescence dynamics in layer-by-layer (LBL) self-assembled films. The assembly of negatively charged colloidal QDs and positively charged polyelectrolytes results in QD/polymer multilayers. Furthermore, to reveal how the ET rate depends on the distance between CdS QDs, we fabricated bilayer structures consisting of differently sized CdS QDs. It is experimentally verified that ET between the donor and acceptor QDs is conclusively dominated by the dipole-dipole interaction.


The Analyst ◽  
2021 ◽  
Author(s):  
Hui-Jun Zhang ◽  
Jin Zhu ◽  
Ning Bao ◽  
Shou-Nian Ding

The mechanism of enhanced ECL of MPA@CdS QDs by EDC activation was investigated, and a sandwich-type ECL immunosensor has been designed for Zika virus detection.


Author(s):  
Haojie Li ◽  
Yihua Song ◽  
Kai Xi ◽  
Wei Wang ◽  
Sheng Liu ◽  
...  

A sufficient areal capacity is necessary for achieving high-energy lithium sulfur battery, which requires high enough sulfur loading in cathode materials. Therefore, kinetically fast catalytic conversion of polysulfide intermediates is...


Author(s):  
Maru Dessie Walle ◽  
You-Nian Liu

AbstractThe lithium–sulfur (Li–S) batteries are promising because of the high energy density, low cost, and natural abundance of sulfur material. Li–S batteries have suffered from severe capacity fading and poor cyclability, resulting in low sulfur utilization. Herein, S-DHCS/CNTs are synthesized by integration of a double-hollow carbon sphere (DHCS) with carbon nanotubes (CNTs), and the addition of sulfur in DHCS by melt impregnations. The proposed S-DHCS/CNTs can effectively confine sulfur and physically suppress the diffusion of polysulfides within the double-hollow structures. CNTs act as a conductive agent. S-DHCS/CNTs maintain the volume variations and accommodate high sulfur content 73 wt%. The designed S-DHCS/CNTs electrode with high sulfur loading (3.3 mg cm−2) and high areal capacity (5.6 mAh mg cm−2) shows a high initial specific capacity of 1709 mAh g−1 and maintains a reversible capacity of 730 mAh g−1 after 48 cycles at 0.2 C with high coulombic efficiency (100%). This work offers a fascinating strategy to design carbon-based material for high-performance lithium–sulfur batteries.


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