Surface chemistry of tube-in-tube nanostructured cuprous sulfide@void@carbon in catalytical polysulfide conversion

2019 ◽  
Vol 7 (20) ◽  
pp. 12815-12824
Author(s):  
Bokai Cao ◽  
Jiangtao Huang ◽  
Fangyuan Zhao ◽  
Yan Mo ◽  
Yong Chen ◽  
...  

Tube-in-tube nanostructured Cu2S@void@C with a superficial CuO layer is able to enhance the electrochemical kinetics of sulfur cathodes.

2007 ◽  
Vol 111 (37) ◽  
pp. 13957-13966 ◽  
Author(s):  
Emma I. Rogers ◽  
Debbie S. Silvester ◽  
Sarah E. Ward Jones ◽  
Leigh Aldous ◽  
Christopher Hardacre ◽  
...  

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Ruirui Wang ◽  
Renbing Wu ◽  
Chaofan Ding ◽  
Ziliang Chen ◽  
Hongbin Xu ◽  
...  

AbstractThe practical application of lithium–sulfur batteries is severely hampered by the poor conductivity, polysulfide shuttle effect and sluggish reaction kinetics of sulfur cathodes. Herein, a hierarchically porous three-dimension (3D) carbon architecture assembled by cross-linked carbon leaves with implanted atomic Co–N4 has been delicately developed as an advanced sulfur host through a SiO2-mediated zeolitic imidazolate framework-L (ZIF-L) strategy. The unique 3D architectures not only provide a highly conductive network for fast electron transfer and buffer the volume change upon lithiation–delithiation process but also endow rich interface with full exposure of Co–N4 active sites to boost the lithium polysulfides adsorption and conversion. Owing to the accelerated kinetics and suppressed shuttle effect, the as-prepared sulfur cathode exhibits a superior electrochemical performance with a high reversible specific capacity of 695 mAh g−1 at 5 C and a low capacity fading rate of 0.053% per cycle over 500 cycles at 1 C. This work may provide a promising solution for the design of an advanced sulfur-based cathode toward high-performance Li–S batteries.


2022 ◽  
Vol 429 ◽  
pp. 132395
Author(s):  
Seongjoon So ◽  
Jaewook Ko ◽  
Yong Nam Ahn ◽  
Il Tae Kim ◽  
Jaehyun Hur

1993 ◽  
Vol 27 (3) ◽  
pp. 331-339 ◽  
Author(s):  
S.D. Varfolomeyev ◽  
A.I. Yaropolov ◽  
A.A. Karyakin

1986 ◽  
Vol 15 (10) ◽  
pp. 1687-1690 ◽  
Author(s):  
Tetsuya Osaka ◽  
Katsuhiko Naoi ◽  
Satoshi Ogano ◽  
Sadako Nakamura

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