Janus bis(NHCs) tuned by heteroatom-bridge oxidation states
Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal(i) complexes provides a first glimpse on their potential use.
2012 ◽
Vol 2012
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pp. 1-9
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Keyword(s):
1985 ◽
pp. 1439
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Keyword(s):
Keyword(s):