Syntheses, structures and properties of three organic–inorganic hybrid polyoxotungstates constructed from {Ni6PW9} building blocks: from isolated clusters to 2-D layers

Abstract Various (metallo)porphyrins and related compounds have been intensively investigated by different research groups due to their extremely important role in living organisms along with their versatile applications in technology. The design of novel porphyrinoids by core-modification, or substitution of pyrrole nitrogens, with the elements of other groups of the Periodic Table has been considered as a highly promising methodology for tuning structures and properties of porphyrinoids and thus opening new possible applications for them. Much effort has been given to the modifications of the porphyrin core with elements of the main groups, namely O, S, Se (chalcogens), and the heavier congener of nitrogen, phosphorus. In general, the porphyrin core modification by replacing nitrogens with heteroatoms is a promising and effective strategy for obtaining new compounds with unusual structures and properties (optical, electrochemical, coordinating, etc.) as well as reactivity. These novel molecules can also be employed as promising building or construction blocks in various applications in the nanotechnology area.

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Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

Chemical Society Reviews ◽

10.1039/d1cs00832c ◽

2022 ◽

Author(s):

Jamie M. Cameron ◽

Geoffroy Guillemot ◽

Theodor Galambos ◽

Sharad S. Amin ◽

Elizabeth Hampson ◽

...

Keyword(s):

Self Assembly ◽

Building Blocks ◽

Supramolecular Assemblies ◽

The Self ◽

Supramolecular Materials ◽

Inorganic Hybrid ◽

Hierarchical Nanomaterials

Organic–inorganic hybrid polyoxometalates are versatile building blocks for the self-assembly of functional supramolecular materials.

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Organic−Inorganic Hybrid Aligned by the Ligand−Ligand Hydrogen Bonds by Using Pyridyl-Substituted Oxalamides as the Building Blocks

Crystal Growth & Design ◽

10.1021/cg070506u ◽

2008 ◽

Vol 8 (3) ◽

pp. 869-876 ◽

Cited By ~ 23

Author(s):

Qingdao Zeng ◽

Min Li ◽

Dongxia Wu ◽

Shengbin Lei ◽

Caiming Liu ◽

...

Keyword(s):

Hydrogen Bonds ◽

Building Blocks ◽

Inorganic Hybrid

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Guidance of growth mode and structural character in organic–inorganic hybrid materials – a comparative study

Dalton Transactions ◽

10.1039/c3dt52391h ◽

2014 ◽

Vol 43 (9) ◽

pp. 3492-3500 ◽

Cited By ~ 16

Author(s):

K. B. Klepper ◽

O. Nilsen ◽

S. Francis ◽

H. Fjellvåg

Keyword(s):

Thin Films ◽

Atomic Layer Deposition ◽

Comparative Study ◽

Hybrid Materials ◽

Atomic Layer ◽

Organic Ligands ◽

Film Properties ◽

Inorganic Hybrid ◽

Layer Deposition ◽

Hybrid Thin Films

We investigated the influence of the functionality of organic ligands on film properties in organic–inorganic hybrid thin films deposited by atomic layer deposition.

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Synthesis, Structure Characterization and Photocatalytic Property of a New 3-D Polyoxovanadate-Based Organic-Inorganic Hybrid Compound

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.997.260 ◽

2014 ◽

Vol 997 ◽

pp. 260-263 ◽

Cited By ~ 1

Author(s):

Ya Bing Liu ◽

Peng Yu

Keyword(s):

Transition Metal ◽

Elemental Analysis ◽

Rhodamine B ◽

Photocatalytic Property ◽

Building Blocks ◽

Structure Characterization ◽

X Ray Diffraction ◽

Hybrid Compound ◽

Inorganic Hybrid ◽

X Ray

A new polyoxovanadates-based organic-inorganic hybrid compound, [Cu(en)2]2[VV6VIV4O25] (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 consists of [Cu(en)2]2+transition metal coordination fragment and the [VV6VIV4O25]4-building blocks, which are linked together via covalently-bonding interactions to form a new 3-D networks. The degradation of rhodamine B (RhB) under UV-vis irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for RhB degradation.

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