Finding a new pathway for acid-induced nitrite reduction reaction: formation of nitric oxide with hydrogen peroxide

2019 ◽  
Vol 48 (37) ◽  
pp. 13916-13920 ◽  
Author(s):  
Mohammed Ajmal Puthiyaveetil Yoosaf ◽  
Somnath Ghosh ◽  
Yatheesh Narayan ◽  
Munendra Yadav ◽  
Subash Chandra Sahoo ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Peroxide ◽  
Nitrous Acid ◽  
Reduction Reaction ◽  
Nitrite Reduction ◽  
Reaction Formation

Here, we report a new pathway for nitrite reduction chemistry, formation of cobalt-nitrosyl ({CoII-NO}8) with H2O2 in the reaction of a CoII-nitrito complex with a one-fold acid (H+) via the formation of a CoII-nitrous acid intermediate ({CoII-ONOH}).

scholarly journals IV. The conditions of chemical change between nitric acid and certain metals

1891 ◽  
Vol 48 (292-295) ◽  
pp. 458-459 ◽  
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Peroxide ◽  
Nitric Acid ◽  
Potassium Permanganate ◽  
Nitrous Acid ◽  
Chemical Change ◽  
Potassium Chlorate ◽  
Cent Concentration ◽  
Preliminary Communication ◽  
A Current

This paper is in continuation of a preliminary communication on the same subject; the main points contained in it are as follows: I. The metals copper, mercury, and bismuth do not dissolve in nitric acid of about 30 per cent, concentration (the acid commonly employed for the preparation of nitric oxide gas) and heated to a temperature of 30ºC., provided that nitrous acid is neither present initially nor formed subsequently. To prevent this, it is nocessary in the cases of copper and bismuth to add a small quantity of some oxidising substance, such as hydrogen peroxide or potassium chlorate, or, as less efficacious, potassium permanganate, or to pass a current of air or, lastly, such a substance as urea, which destroys the nitrous acid by its interaction.

Effects of Exogenous Abscisic Acid,Nitric Oxide and Hydrogen Peroxide on Stomatal Movement in Petals and Leaves ofZephyranthes candida

2013 ◽  
Vol 31 (3) ◽  
pp. 278
Author(s):  
Wen-Qi XIE ◽  
Jin-Ping ZHANG ◽  
Jian-Yi TAN ◽  
Xiao-Li XUAN ◽  
Yong-Fei WANG ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Peroxide ◽  
Abscisic Acid ◽  
Stomatal Movement

scholarly journals Hydrogen peroxide and nitric oxide as signalling molecules in plants

2002 ◽  
Vol 53 (372) ◽  
pp. 1237-1247 ◽  
Author(s):  
Steven J. Neill ◽  
Radhika Desikan ◽  
Andrew Clarke ◽  
Roger D. Hurst ◽  
John T. Hancock
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Peroxide ◽  
Signalling Molecules

scholarly journals Cloning, Expression, and Purification of a Nitric Oxide Synthase-Like Protein fromBacillus cereus

2010 ◽  
Vol 2010 ◽  
pp. 1-4 ◽  
Author(s):  
Heather J. Montgomery ◽  
Andrea L. Dupont ◽  
Hilary E. Leivo ◽  
J. Guy Guillemette
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Peroxide ◽  
Nitric Oxide Synthase ◽  
Expression And Purification ◽  
Spectral Shifts ◽  
Reconstituted System ◽  
Low Levels ◽  
And Function ◽  
Oxide Synthase ◽  
Reductase Domain

The nitric oxide synthase-like protein fromBacillus cereus(bcNOS) has been cloned, expressed, and characterized. This small hemeprotein (356 amino acids in length) has a mass of 43 kDa and forms a dimer. The recombinant protein showed similar spectral shifts to the mammalian NOS proteins and could bind the substrates L-arginine andNG-hydroxy-L-arginine as well as the ligand imidazole. Low levels of activity were recorded for the hydrogen peroxide-dependent oxidation ofNG-hydroxy-L-arginine and L-arginine by bcNOS, while a reconstituted system with the rat neuronal NOS reductase domain showed no activity. The recombinant bcNOS protein adds to the complement of bacterial NOS-like proteins that are used for the investigation of the mechanism and function of NO in microorganisms.

Sign in / Sign up

Export Citation Format

Share Document