Upscale synthesis of a binary pillared layered MOF for hydrocarbon gas storage and separation

2020 ◽  
Vol 22 (3) ◽  
pp. 718-724 ◽  
Author(s):  
Mickaele Bonneau ◽  
Christophe Lavenn ◽  
Patrick Ginet ◽  
Ken-ichi Otake ◽  
Susumu Kitagawa

Scaling up the synthesis of metal organic frameworks (MOFs) is necessary in order to demonstrate their potential in industrial applications.

Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1291 ◽  
Author(s):  
Isobel Tibbetts ◽  
George Kostakis

Metal-organic frameworks (MOFs) have found uses in adsorption, catalysis, gas storage and other industrial applications. Metal Biomolecule Frameworks (bioMOFs) represent an overlap between inorganic, material and medicinal sciences, utilising the porous frameworks for biologically relevant purposes. This review details advances in bioMOFs, looking at the synthesis, properties and applications of both bioinspired materials and MOFs used for bioapplications, such as drug delivery, imaging and catalysis, with a focus on examples from the last five years.


Author(s):  
Ayushi Singh ◽  
Ashish Kumar Singh ◽  
Jian-Qiang Liu ◽  
Abhinav Kumar

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...


Author(s):  
Jian Xiong ◽  
Ailin Li ◽  
Ye Liu ◽  
Liming Wang ◽  
Xiaohong Qin ◽  
...  

Integrating metal-organic frameworks (MOFs) into flexible polymeric matrices can improve their practical processibility and enlarge industrial applications greatly. However, current methods suffer from the serious aggregation of MOFs, low MOF...


2018 ◽  
Vol 140 (32) ◽  
pp. 10191-10197 ◽  
Author(s):  
Hana Bunzen ◽  
Felicitas Kolbe ◽  
Andreas Kalytta-Mewes ◽  
German Sastre ◽  
Eike Brunner ◽  
...  

Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 325 ◽  
Author(s):  
Joshua Sosa ◽  
Timothy Bennett ◽  
Katherine Nelms ◽  
Brandon Liu ◽  
Roberto Tovar ◽  
...  

The inherent porous nature and facile tunability of metal–organic frameworks (MOFs) make them ideal candidates for use in multiple fields. MOF hybrid materials are derived from existing MOFs hybridized with other materials or small molecules using a variety of techniques. This led to superior performance of the new materials by combining the advantages of MOF components and others. In this review, we discuss several hybridization methods for the preparation of various MOF hybrids with representative examples from the literature. These methods include covalent modifications, noncovalent modifications, and using MOFs as templates or precursors. We also review the applications of the MOF hybrids in the fields of catalysis, drug delivery, gas storage and separation, energy storage, sensing, and others.


2019 ◽  
Vol 45 (14-15) ◽  
pp. 1082-1121 ◽  
Author(s):  
Arni Sturluson ◽  
Melanie T. Huynh ◽  
Alec R. Kaija ◽  
Caleb Laird ◽  
Sunghyun Yoon ◽  
...  

EnergyChem ◽  
2019 ◽  
Vol 1 (1) ◽  
pp. 100006 ◽  
Author(s):  
Hao Li ◽  
Libo Li ◽  
Rui-Biao Lin ◽  
Wei Zhou ◽  
Zhangjing Zhang ◽  
...  

2020 ◽  
Vol 7 (1) ◽  
pp. 223-228 ◽  
Author(s):  
Long Xiang ◽  
Donghui Liu ◽  
Hua Jin ◽  
Long-Wei Xu ◽  
Chongqing Wang ◽  
...  

The framework flexibility of metal–organic frameworks (MOFs) is beneficial for gas storage and adsorption but is disadvantageous to the separation process based on the size-extrusion mechanism.


Soft Matter ◽  
2018 ◽  
Vol 14 (47) ◽  
pp. 9589-9598 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Feier Li ◽  
Jing Xiao ◽  
Shaojuan Luo ◽  
...  

A simple, rapid and versatile method was developed to increase the pore sizes and pore volumes of microporous MOFs (HKUST-1, ZIF-8, ZIF-67, and ZIF-90) by employing organic amine as the template. The resultant hierarchically porous HKUST-1 exhibited significantly enhanced adsorption capacities and faster diffusion rates for CH4 and CO2 gas storage.


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