Accelerating dynamic exchange and self-healing using mechanical forces in crosslinked polymers

2020 ◽  
Vol 7 (6) ◽  
pp. 1581-1587 ◽  
Author(s):  
Nethmi De Alwis Watuthanthrige ◽  
Ballal Ahammed ◽  
Madison T. Dolan ◽  
Qinghua Fang ◽  
Jian Wu ◽  
...  
Keyword(s):  
Room Temperature ◽  
Mechanical Forces ◽  
Self Healing ◽  
Ambient Conditions ◽  
Crosslinked Polymers ◽  
Dynamic Exchange

Surprisingly, a few seconds–minutes of compression at room temperature can increase the rate of dynamic bond exchange as measured by better self-healing, even for thermoresponsive dynamic bonds which do not exchange under ambient conditions.

A user's guide to the thiol-thioester exchange in organic media: scope, limitations, and applications in material science

2018 ◽  
Vol 9 (36) ◽  
pp. 4523-4534 ◽  
Author(s):  
Brady T. Worrell ◽  
Sudheendran Mavila ◽  
Chen Wang ◽  
Taylor M. Kontour ◽  
Chern-Hooi Lim ◽  
...  
Keyword(s):  
Material Science ◽  
Room Temperature ◽  
Organic Media ◽  
Crosslinked Polymers ◽  
Thioester Exchange ◽  
Dynamic Exchange

The dynamic exchange of thiols and thioesters in organic media was explored, leading to room temperature plasticity in crosslinked polymers.

Catalyst-Free Room-Temperature Self-Healing Polymer Networks Based on Dynamic Covalent Quinone Methide-Secondary Amine Chemistry

2021 ◽  
Author(s):  
Yuanxing Zhang ◽  
Ying Wu ◽  
Jiayi Li ◽  
Ke Zhang
Keyword(s):  
Secondary Amine ◽  
Michael Addition ◽  
Room Temperature ◽  
Polymer Networks ◽  
Quinone Methide ◽  
Self Healing ◽  
Ambient Conditions ◽  
Catalyst Free ◽  
External Stimuli

An aza-Michael addition between 2,6-di-t-butyl-7-phenyl-p-quinone methide and secondary amine was demonstrated to hold the dynamic covalent reaction property under ambient conditions requiring no external stimuli. Based on this dynamic covalent...

Catalyst-free dynamic exchange of aromatic Schiff base bonds and its application to self-healing and remolding of crosslinked polymers

2015 ◽  
Vol 3 (39) ◽  
pp. 19662-19668 ◽  
Author(s):  
Zhou Qiao Lei ◽  
Pu Xie ◽  
Min Zhi Rong ◽  
Ming Qiu Zhang
Keyword(s):  
Schiff Base ◽  
Self Healing ◽  
Crosslinked Polymers ◽  
Catalyst Free ◽  
Dynamic Exchange ◽  
Free Dynamic

Crosslinked polyacrylate is self-healed and reprocessed through rearrangement of networks based on catalyst-free dynamic exchange of aromatic Schiff base bonds.

Autonomous self-healing polyisoprene elastomers with high modulus and good toughness based on the synergy of dynamic ionic crosslinks and highly disordered crystals

2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Self Healing ◽  
High Modulus ◽  
Disordered Crystals ◽  
Ionic Crosslinks

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.

scholarly journals Rapid synchronized fabrication of vascularized thermosets and composites

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Mayank Garg ◽  
Jia En Aw ◽  
Xiang Zhang ◽  
Polette J. Centellas ◽  
Leon M. Dean ◽  
...  
Keyword(s):  
Large Scale ◽  
Capillary Flow ◽  
External Heat ◽  
Frontal Polymerization ◽  
Self Healing ◽  
Vascular Networks ◽  
Ambient Conditions ◽  
External Energy ◽  
Imaging Phantoms ◽  
Vascular Structures

AbstractBioinspired vascular networks transport heat and mass in hydrogels, microfluidic devices, self-healing and self-cooling structures, filters, and flow batteries. Lengthy, multistep fabrication processes involving solvents, external heat, and vacuum hinder large-scale application of vascular networks in structural materials. Here, we report the rapid (seconds to minutes), scalable, and synchronized fabrication of vascular thermosets and fiber-reinforced composites under ambient conditions. The exothermic frontal polymerization (FP) of a liquid or gelled resin facilitates coordinated depolymerization of an embedded sacrificial template to create host structures with high-fidelity interconnected microchannels. The chemical energy released during matrix polymerization eliminates the need for a sustained external heat source and greatly reduces external energy consumption for processing. Programming the rate of depolymerization of the sacrificial thermoplastic to match the kinetics of FP has the potential to significantly expedite the fabrication of vascular structures with extended lifetimes, microreactors, and imaging phantoms for understanding capillary flow in biological systems.

Visible-light-initiated Catalyst-free Oxidative Cleavage of Triaryl-Substituted Alkenes C=C Bonds under Ambient Conditions

2021 ◽  
Author(s):  
Wenjing Li ◽  
Shun Li ◽  
Lihua Luo ◽  
Yichen Ge ◽  
Jiaqi Xu ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Ambient Air ◽  
Oxidative Cleavage ◽  
Ambient Conditions ◽  
Blue Led ◽  
Catalyst Free

The catalyst-free oxidative cleavage of (Z)-triaryl-substituted alkenes bearing pyridyl motif with ambient air under irradiation of blue LED at room temperature has been developed. The reaction was facile and scalable,...

scholarly journals Foldable and washable textile-based OLEDs with a multi-functional near-room-temperature encapsulation layer for smart e-textiles

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
So Yeong Jeong ◽  
Hye Rin Shim ◽  
Yunha Na ◽  
Ki Suk Kang ◽  
Yongmin Jeon ◽  
...  
Keyword(s):  
Room Temperature ◽  
Wearable Electronics ◽  
Ambient Conditions ◽  
Light Emitting ◽  
Stable Operating ◽  
Mechanical Durability ◽  
Potential Applications ◽  
Wearable Electronic ◽  
Data Signal ◽  
Wearable Electronic Devices

AbstractWearable electronic devices are being developed because of their wide potential applications and user convenience. Among them, wearable organic light emitting diodes (OLEDs) play an important role in visualizing the data signal processed in wearable electronics to humans. In this study, textile-based OLEDs were fabricated and their practical utility was demonstrated. The textile-based OLEDs exhibited a stable operating lifetime under ambient conditions, enough mechanical durability to endure the deformation by the movement of humans, and washability for maintaining its optoelectronic properties even in water condition such as rain, sweat, or washing. In this study, the main technology used to realize this textile-based OLED was multi-functional near-room-temperature encapsulation. The outstanding impermeability of TiO2 film deposited at near-room-temperature was demonstrated. The internal residual stress in the encapsulation layer was controlled, and the device was capped by highly cross-linked hydrophobic polymer film, providing a highly impermeable, mechanically flexible, and waterproof encapsulation.

scholarly journals Optical switching of topological phase in a perovskite polariton lattice

2021 ◽  
Vol 7 (21) ◽  
pp. eabf8049
Author(s):  
Rui Su ◽  
Sanjib Ghosh ◽  
Timothy C. H. Liew ◽  
Qihua Xiong
Keyword(s):  
Optical Switching ◽  
Room Temperature ◽  
Optical Pumping ◽  
Optical Nonlinearity ◽  
Edge States ◽  
Ambient Conditions ◽  
Strong Light ◽  
Exciton Polaritons ◽  
Matter Interaction ◽  
Light Matter Interaction

Strong light-matter interaction enriches topological photonics by dressing light with matter, which provides the possibility to realize active nonlinear topological devices with immunity to defects. Topological exciton polaritons—half-light, half-matter quasiparticles with giant optical nonlinearity—represent a unique platform for active topological photonics. Previous demonstrations of exciton polariton topological insulators demand cryogenic temperatures, and their topological properties are usually fixed. Here, we experimentally demonstrate a room temperature exciton polariton topological insulator in a perovskite zigzag lattice. Polarization serves as a degree of freedom to switch between distinct topological phases, and the topologically nontrivial polariton edge states persist in the presence of onsite energy perturbations, showing strong immunity to disorder. We further demonstrate exciton polariton condensation into the topological edge states under optical pumping. These results provide an ideal platform for realizing active topological polaritonic devices working at ambient conditions, which can find important applications in topological lasers, optical modulation, and switching.

scholarly journals Research on Thermal Stability and Properties of Ca3ZrSi2O9 as Potential T/EBC Materials

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 583
Author(s):  
Yangyang Pan ◽  
Bo Liang ◽  
Yaran Niu ◽  
Dijuan Han ◽  
Dongdong Liu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Stability ◽  
Fracture Toughness ◽  
Room Temperature ◽  
Coefficient Of Thermal Expansion ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Mechanical And Thermal Properties ◽  
Self Healing ◽  
Barrier Coating

In this study, a new coating material for thermal barrier coating (TBC) or environment barrier coating (EBC) application, Ca3ZrSi2O9 (CZSO), was synthesized and prepared by atmospheric plasma spray (APS) technology. The evolution of the phases and microstructures of the coatings with different thermal-aged were characterized by XRD, XRF, EDS and SEM, respectively. The thermal stability was measured by TG-DTA and DSC. The mechanical and thermal properties, including Vickers hardness (HV), fracture toughness (KIC), thermal conductivity () and coefficient of thermal expansion (CTE) were focused on. It was found that the as-sprayed CZSO coating contained amorphous phase. Crystalline transformation happened at 900–960 ∘C and no mass changes took place from room temperature (RT) to 1300 ∘C. The phenomena of microcrack self-healing and composition uniformity were observed during thermal aging. The of coating was very low at about 0.57–0.80 Wm−1K−1 in 200–1200 ∘C. The combined properties indicated that the CZSO coating might be a potential T/EBC material.

Stretchable dual cross-linked silicon elastomer with superhydrophobic surface and fast triple self-healing ability at room temperature

Soft Matter ◽  
2021 ◽  
Author(s):  
Yuxing Shan ◽  
shuai liang ◽  
Xiangkai Mao ◽  
Jie Lu ◽  
Lili Liu ◽  
...  
Keyword(s):  
Superhydrophobic Surface ◽  
Room Temperature ◽  
Superhydrophobic Surfaces ◽  
Self Healing ◽  
Wearable Electronics ◽  
Actual Application ◽  
Potential Applications

Abstract. Stretchable elastomers with superhydrophobic surfaces have potential applications in wearable electronics. However, various types of damage inevitably occur on these elastomers in actual application, resulting in deterioration of the...

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