scholarly journals Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance

RSC Advances ◽  
2019 ◽  
Vol 9 (48) ◽  
pp. 28089-28094 ◽  
Author(s):  
Qinru Li ◽  
Xiaoxia Zhou ◽  
Wanpeng Zhao ◽  
Chunlei Peng ◽  
Huixia Wu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ion Exchange ◽  
Ethylene Glycol ◽  
Co Oxidation ◽  
Water Resistance ◽  
Reduction Method ◽  
Zeolite Beta ◽  
High Catalytic Activity ◽  
Mesoporous Zeolite ◽  
Highly Dispersed

A series of Pt/Fe co-loaded mBeta catalysts with highly dispersed Pt species have been successfully prepared by an ion exchange and subsequent ethylene glycol reduction method, and show excellent catalytic activity and durability in CO oxidation.

Facile synthesis of Pt–Pd nanodendrites and their superior electrocatalytic activity

2014 ◽  
Vol 2 (12) ◽  
pp. 4384-4390 ◽  
Author(s):  
Jing-Jing Lv ◽  
Jie-Ning Zheng ◽  
Shan-Shan Li ◽  
Li-Li Chen ◽  
Ai-Jun Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ethylene Glycol ◽  
Electrocatalytic Activity ◽  
Reduction Method ◽  
Chemical Reduction ◽  
Alkaline Media ◽  
High Catalytic Activity ◽  
Chemical Reduction Method ◽  
Facile Synthesis ◽  
Electrooxidation Of Methanol

Porous Pt–Pd nanodendrites were fabricated by a co-chemical reduction method using both PVP and urea as the co-stabilizing and co-structure-directing agents. The Pt–Pd nanodendrites displayed high catalytic activity and stability toward the electrooxidation of methanol and ethylene glycol in alkaline media.

scholarly journals CO Oxidation Efficiency and Hysteresis Behavior over Mesoporous Pd/SiO2 Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 131 ◽  
Author(s):  
Rola Mohammad Al Soubaihi ◽  
Khaled Mohammad Saoud ◽  
Myo Tay Zar Myint ◽  
Mats A. Göthelid ◽  
Joydeep Dutta
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Active Sites ◽  
Bond Activation ◽  
Dissociative Adsorption ◽  
High Catalytic Activity ◽  
Good Catalytic Activity ◽  
Pretreatment Conditions ◽  
Oxidation Efficiency

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (Tig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than Tig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at Tig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.

scholarly journals Immobilization of an Iridium(I)-NHC-Phosphine Catalyst for Hydrogenation Reactions under Batch and Flow Conditions

Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 656
Author(s):  
Henrietta Kovács ◽  
Krisztina Orosz ◽  
Gábor Papp ◽  
Ferenc Joó ◽  
Henrietta Horváth
Keyword(s):  
Catalytic Activity ◽  
Ion Exchange ◽  
Heterogeneous Catalyst ◽  
Aqueous Phase ◽  
Levulinic Acid ◽  
Flow Reactor ◽  
High Catalytic Activity ◽  
Flow Conditions ◽  
Hydrogenation Reactions ◽  
Excellent Selectivity

Na2[Ir(cod)(emim)(mtppts)] (1) with high catalytic activity in various organic- and aqueous-phase hydrogenation reactions was immobilized on several types of commercially available ion-exchange supports. The resulting heterogeneous catalyst was investigated in batch reactions and in an H-Cube flow reactor in the hydrogenation of phenylacetylene, diphenylacetylene, 1-hexyne, and benzylideneacetone. Under proper conditions, the catalyst was highly selective in the hydrogenation of alkynes to alkenes, and demonstrated excellent selectivity in C=C over C=O hydrogenation; furthermore, it displayed remarkable stability. Activity of 1 in hydrogenation of levulinic acid to γ-valerolactone was also assessed.

CO Oxidation on Inverse CeOx/Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O2

2011 ◽  
Vol 133 (10) ◽  
pp. 3444-3451 ◽  
Author(s):  
Fan Yang ◽  
Jesús Graciani ◽  
Jaime Evans ◽  
Ping Liu ◽  
Jan Hrbek ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
High Catalytic Activity

Synthesis and characterization of new isostructural series LnFe0.5Sb1.5O6 (Ln = La-Sm) exhibiting high catalytic activity in CO oxidation

2019 ◽  
Vol 777 ◽  
pp. 655-662 ◽  
Author(s):  
A.V. Egorysheva ◽  
O.G. Ellert ◽  
E. Yu Liberman ◽  
D.I. Kirdyankin ◽  
S.V. Golodukhina ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Synthesis And Characterization ◽  
High Catalytic Activity

High catalytic activity for CO oxidation on single Fe atom stabilized in graphene vacancies

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93985-93996 ◽  
Author(s):  
Yanan Tang ◽  
Jincheng Zhou ◽  
Zigang Shen ◽  
Weiguang Chen ◽  
Chenggang Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
First Principles ◽  
High Catalytic Activity ◽  
First Principles Method

The geometric, electronic and catalytic characters of Fe atom embedded graphene (including monovacancy and divacancy) are investigated using the first-principles method, which gives a reference on designing graphene-based catalysts for CO oxidation.

Mussel-inspired construction of thermo-responsive double-hydrophilic diblock copolymers-decorated reduced graphene oxide as effective catalyst supports for highly dispersed superfine Pd nanoparticles

Nanoscale ◽  
2018 ◽  
Vol 10 (26) ◽  
pp. 12487-12496 ◽  
Author(s):  
Haichao Duan ◽  
Yu Yang ◽  
Jianhua Lü ◽  
Changli Lü
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Diblock Copolymer ◽  
Diblock Copolymers ◽  
Pd Nanoparticles ◽  
Catalyst Supports ◽  
High Catalytic Activity ◽  
Reduced Graphene ◽  
Highly Dispersed

We report a facile, mussel-inspired construction of a thermo-responsive diblock copolymer-anchored rGO support for superfine PdNPs with high catalytic activity.

scholarly journals Cellulose nanocrystals (CNCs) as hard templates for preparing mesoporous zeolite Y assemblies with high catalytic activity

2020 ◽  
Vol 22 (15) ◽  
pp. 5115-5122 ◽  
Author(s):  
Samer Abdulridha ◽  
Jiuxing Jiang ◽  
Shaojun Xu ◽  
Zhaoxia Zhou ◽  
He Liang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cellulose Nanocrystals ◽  
Zeolite Y ◽  
Synthesis Method ◽  
High Catalytic Activity ◽  
Mesoporous Zeolite ◽  
Y Zeolite ◽  
Directed Synthesis

Faujasite (FAU) Y zeolite assemblies with high mesoporosity (Sext = 347 m2 g−1 and Vmeso = 0.52 cm3 g−1) were synthesised using sustainable and economic cellulose nanocrystals (CNCs) via a template-directed synthesis method.

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