Counterintuitive solvation effect of ionic-liquid/DMSO solvents on acidic C–H dissociation and insight into respective solvation
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The dependence of PhCH(CN)2 pKa on the molar fraction of ionic liquids in ionic–molecular binary mixtures showed a nonlinear three-fragment plot, which was rationalized for the first time by the respective roles of each solvent component for solvation.
2017 ◽
Vol 7
(10)
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pp. 2065-2073
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2018 ◽
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