Facile in situ synthesis of core–shell MOF@Ag nanoparticle composites on screen-printed electrodes for ultrasensitive SERS detection of polycyclic aromatic hydrocarbons

2019 ◽  
Vol 7 (23) ◽  
pp. 14108-14117 ◽  
Author(s):  
Dan Li ◽  
Xiukai Cao ◽  
Qinmei Zhang ◽  
Xingang Ren ◽  
Lei Jiang ◽  
...  

An HKUST-1@Ag-based SERS chip is fabricated by an in situ electrodeposition method and used for on-site detection of PAHs in environmental samples.

2015 ◽  
Vol 17 (33) ◽  
pp. 21158-21163 ◽  
Author(s):  
Meng Jiang ◽  
Zhijiang Qian ◽  
Xufeng Zhou ◽  
Xing Xin ◽  
Jinghua Wu ◽  
...  

A facile and convenient strategy to detect polycyclic aromatic hydrocarbons is presented, using graphene–Ag nanoparticle hybrids as a surface-enhanced Raman scattering substrate.


2017 ◽  
Vol 9 (11) ◽  
pp. 1816-1824 ◽  
Author(s):  
Lanlan Xiao ◽  
Min Zhang ◽  
Zhen Liu ◽  
Weiwei Bian ◽  
Xiaoli Zhang ◽  
...  

The migration of solid samples from the interior to the surface of materials has raised serious concerns due to the increasing environmental health hazards in recent years.


2022 ◽  
Vol 284 ◽  
pp. 117006
Author(s):  
Jun Ho Myung ◽  
Jihyun Yoon ◽  
Yong Min Kim ◽  
Jeong-Yun Sun ◽  
Woong-Ryeol Yu

2019 ◽  
Author(s):  
Thomas Delouche ◽  
Antoine Vacher ◽  
Elsa Caytan ◽  
Thierry Roisnel ◽  
Boris Le Guennic ◽  
...  

In this communication, we report the straightforward<br>synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) where two phosphoniums are connected through various PAHs backbones. The impact of pi-extension on both the optical and redox properties is investigated using a joint experimental/theoretical approach.<br>Finally, (spectro)-electrochemical studies prove that these<br>compounds possess three redox states and EPR studies confirms the in situ formation of an organic radical.


Molecules ◽  
2020 ◽  
Vol 25 (16) ◽  
pp. 3727
Author(s):  
Łukasz Dąbrowski

For complex matrices such as environmental samples, there is usually a problem with not fully resolved peaks during GC/MS analysis. The PARADISe computer program (based on the PARFAC2 model) allows the identification of peaks using the deconvoluted mass spectra and the NIST MS library. The number of repetitions required by this software (at least five) is a real limitation for the determination of semi-volatile compounds, like polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organic pesticides in environmental samples. In this work, the method to overcome this condition was proposed and evaluated. The sets of the five files required by PARADISe were prepared by mathematically modifying the original GC/MS chromatograms obtained for the standard mixture (C = 2 µg/mL of 40 compounds) and real sample extracts (soil samples with different total organic carbon content and one cardboard extract) spiked with standards. Total average match factor for all the substances identified in a standard mixture was 874 (near 900—“excellent match”), and for all the substances in the real samples, it was 786 (near 800—“good match”). The results from PARADISe were comparable to those obtained with other programs: AMDIS (NIST) and MassHunter (Agilent), tested also in this work. PARADISe software can be effectively used for chromatogram deconvolution and substance identification.


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