Unraveling the dissolution mechanism of platinum and silver electrodes during composite electrodeposition in a deep eutectic solvent

2020 ◽  
Vol 8 (8) ◽  
pp. 4354-4361
Author(s):  
Shujuan Wang ◽  
Xiaolu Xiong ◽  
Xingli Zou ◽  
Kai Ding ◽  
Zhongya Pang ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Deep Eutectic Solvent ◽  
Catalytic Performance ◽  
Dissolution Mechanism ◽  
Reference Electrodes ◽  
Silver Electrodes ◽  
Composite Electrodeposition

A three-dimensional Ni–AC–Ag–Pt composite with enhanced catalytic performance for HER has been deposited through the dissolution of Pt counter and Ag reference electrodes in a deep eutectic solvent, and the dissolution mechanism has been proposed.

Fabrication and Excellent Catalytic Performance of Three-dimensional Ordered Mesoporous Molybdenum Oxides

2014 ◽  
Vol 29 (2) ◽  
pp. 124-130 ◽  
Author(s):  
Yu-Cheng DU ◽  
Guang-Wei ZHENG ◽  
Qi MENG ◽  
Li-Ping WANG ◽  
Hai-Guang FAN ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Catalytic Performance ◽  
Molybdenum Oxides ◽  
Ordered Mesoporous ◽  
Excellent Catalytic Performance

Three-dimensionally ordered macroporous spinel-type MCr2O4 (M = Co, Ni, Zn, Mn) catalysts with highly enhanced catalytic performance for soot combustion

2015 ◽  
Vol 5 (9) ◽  
pp. 4594-4601 ◽  
Author(s):  
Jinguo Wang ◽  
Gaoyang Yang ◽  
Li Cheng ◽  
Eun Woo Shin ◽  
Yong Men
Keyword(s):  
Catalytic Activity ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Soot Combustion ◽  
Spinel Type ◽  
Ordered Macroporous

MCr2O4 catalysts with three-dimensional ordered macroporous structures displayed superior catalytic activity for soot combustion to their bulk counterparts.

Facile synthesis of three-dimensional ordered macroporous Sr1−xKxTiO3 perovskites with enhanced catalytic activity for soot combustion

2018 ◽  
Vol 8 (21) ◽  
pp. 5462-5472 ◽  
Author(s):  
Peng Zhao ◽  
Nengjie Feng ◽  
Fan Fang ◽  
Geng Liu ◽  
Li Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Soot Combustion ◽  
Facile Synthesis ◽  
Ordered Macroporous

The appropriate incorporation of potassium into 3DOM SrTiO3 perovskites effectively improved the catalytic performance for soot combustion.

Facile synthesis and catalytic performance of Co3O4nanosheets in situ formed on reduced graphene oxide modified Ni foam

2017 ◽  
Vol 46 (40) ◽  
pp. 13845-13853 ◽  
Author(s):  
Congying Song ◽  
Xianzhi Yin ◽  
Biaopeng Li ◽  
Ke Ye ◽  
Kai Zhu ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Hydrothermal Method ◽  
Reduced Graphene Oxide ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Ni Foam ◽  
Facile Synthesis ◽  
Reduced Graphene ◽  
Catalyst Electrode

A three-dimensional (3D) catalyst electrode of Co3O4nanosheetsin situformed on reduced graphene oxide modified Ni foam (Co3O4/rGO@Ni foam) for H2O2electroreduction is prepared by a two-step hydrothermal method.

Fabrication of three-dimensional MoS2-graphene hybrid monoliths and their catalytic performance for hydrodesulfurization

Carbon ◽  
2014 ◽  
Vol 76 ◽  
pp. 471 ◽  
Author(s):  
Xu-zhen Wang ◽  
Ning Liu ◽  
Han Hu ◽  
Xin-ping Wang ◽  
Jie-shan Qiu
Keyword(s):  
Three Dimensional ◽  
Catalytic Performance

A three-dimensional porphyrin-based porous organic polymer with excellent biomimetic catalytic performance

2017 ◽  
Vol 8 (30) ◽  
pp. 4327-4331 ◽  
Author(s):  
Wei Zhu ◽  
Zheng-Dong Ding ◽  
Xuan Wang ◽  
Tao Li ◽  
Rui Shen ◽  
...  
Keyword(s):  
High Stability ◽  
Three Dimensional ◽  
Catalytic Efficiency ◽  
Catalytic Performance ◽  
Organic Polymer ◽  
Diamond Structure ◽  
Porous Organic Polymer ◽  
Biomimetic Catalyst

A porphyrin-based porous organic polymer PPOP-1(Fe) with a three-dimensional diamond structure was synthesized, which exhibits high stability and excellent catalytic efficiency as a biomimetic catalyst.

Three dimensional nitrogen-doped graphene hydrogels with in situ deposited cobalt phosphate nanoclusters for efficient oxygen evolution in a neutral electrolyte

2016 ◽  
Vol 1 (1) ◽  
pp. 41-44 ◽  
Author(s):  
Anthony Vasileff ◽  
Sheng Chen ◽  
Shi Zhang Qiao
Keyword(s):  
Oxygen Evolution ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Nitrogen Doped ◽  
Nitrogen Doped Graphene ◽  
Doped Graphene ◽  
Neutral Electrolyte ◽  
Cobalt Phosphate ◽  
Excellent Catalytic Performance

Nitrogen doped graphene hydrogel electrocatalysts with in situ deposited cobalt phosphate demonstrated excellent catalytic performance toward oxygen evolution in a neutral electrolyte.

A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

2018 ◽  
Vol 54 (91) ◽  
pp. 12808-12811 ◽  
Author(s):  
Weiwei Cheng ◽  
Yun-shan Xue ◽  
Xi-Ming Luo ◽  
Yan Xu
Keyword(s):  
Three Dimensional ◽  
Catalytic Performance ◽  
Inorganic Framework ◽  
Metal Polymer

A rare inorganic framework constructed from CO2 and polyoxoanions exhibits interesting performance in the cycloaddition of CO2 with epoxides.

scholarly journals The Anodic Behaviour of Bulk Copper in Ethaline and 1-Butyl-3-Methylimidazolium Chloride

2019 ◽  
Vol 9 (20) ◽  
pp. 4401 ◽  
Author(s):  
Karim ◽  
Aziz ◽  
Brza ◽  
Abdullah ◽  
Kadir
Keyword(s):  
Electrochemical Impedance ◽  
Choline Chloride ◽  
Metallic Copper ◽  
Electrochemical Techniques ◽  
Deep Eutectic Solvent ◽  
Molar Ratio ◽  
Interfacial Region ◽  
Dissolution Mechanism ◽  
Spectroscopic Techniques ◽  
Electrochemical Dissolution

The anodic dissolution of bulk metallic copper was conducted in ionic liquids (ILs)—a deep eutectic solvent (DES) ((CH3)3NC2H4OH) comprised of a 1:2 molar ratio mixture of choline chloride Cl (ChCl), and ethylene glycol (EG)—and imidazolium-based ILs, such as C4mimCl, using electrochemical techniques, such as cyclic voltammetry, anodic linear sweep voltammetry, and chronopotentiometry.To investigate the electrochemical dissolution mechanism, electrochemical impedance spectroscopy (EIS) was used. In addition to spectroscopic techniques, for instance, UV-visible spectroscopy, microscopic techniques, such as atomic force microscopy (AFM), were used. The significant industrial importance of metallic copper has motivated several research groups to deal with such an invaluable metal. It was confirmed that the speciation of dissolved copper from the bulk phase at the interface region is [CuCl3]− and [CuCl4]2− in such chloride-rich media, and the EG determine the structure of the interfacial region in the electrochemical dissolution process. A super-saturated solution was produced at the electrode/solution interface and CuCl2 was deposited on the metal surface.

One-Step Synthesis of Nano-Size Iron Oxide /Three-Dimensional Wormlike Hierarchical Mesoporous SiO2 Catalysts and its Catalytic Performance on Phenol Hydroxylation

2013 ◽  
Vol 662 ◽  
pp. 202-206
Author(s):  
Jia Feng Wu ◽  
Yu Mei Zhao ◽  
Peng Liang
Keyword(s):  
Iron Oxide ◽  
High Surface ◽  
High Surface Area ◽  
Three Dimensional ◽  
Catalytic Performance ◽  
Phenol Hydroxylation ◽  
Weight Percentage ◽  
One Step ◽  
Hierarchical Pore ◽  
Nano Size

A series of nano-sized iron oxide supported on 3D wormlike hierarchical mesoporous SiO2 catalysts were synthesized by one-step hydrothermal synthesis. The samples were characterized by XRD, N2 sorption, FT-IR, UV–Vis, TEM and ICP-AES. The catalysts were probed for the oxidation of phenol employing hydrogen peroxide. The results indicate that the materials exhibit high surface area and 3D wormlike hierarchical pore, iron ions exist as isolated framework species when the weight percentage content of iron is below 0.24 and nano-size iron oxide is dispersed in the surface (iron content above 0.24 wt%). Catalytic performance indicates that nano-size iron oxide supported on SiO2 is useful to enhance both the catalytic activity and the selectivity of target products compared with isolated iron species.

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