Thermochromism and piezochromism of an atomically precise high-nuclearity silver sulfide nanocluster

2021 ◽  
Author(s):  
Qiao-Qiao Sun ◽  
Qian Li ◽  
Hai-Yang Li ◽  
Miao-Miao Zhang ◽  
Meng-En Sun ◽  
...  

A novel high-nuclearity silver chalcogenolate nanocluster [Ag50S7(SPhF)36(dppp)6] have been obtained, which shows reversible color changes in response to temperature and pressure.

2019 ◽  
Vol 74 (12) ◽  
pp. 1115-1122
Author(s):  
Najm ul Aarifeen ◽  
Afaq Ahmad ◽  
H. Bushra Munir ◽  
Abu Bakar

AbstractA systematic first principles study has been carried on zinc oxide and their Cd-substituted ternary alloys in the zinc blende phase for the measurement of various thermodynamic parameters over a wide range of temperature (0–1200 K) and pressure (0–10 GPa). A significant change in various thermodynamic parameters of Cd-substituted ZnO has been noted. Cd-rich CdxZn1−xO has the least thermal conductivity, bulk modulus and Debye temperature, whereas maximum molar heat capacities, Grüneisen parameter and entropy. The anharmonicity of the semiconducting system changes in response to temperature and pressure variation, which in turn control thermal expansion. Internal energy, free energy and entropy are more temperature sensitive as compared to pressure.


2004 ◽  
Vol 51 (4) ◽  
pp. 202-204
Author(s):  
Tatsuya Mishiro ◽  
Hidetaka Fuchu ◽  
Yoshiro Kodama ◽  
Masaaki Sugiyama ◽  
Tadashi Matsumoto

Author(s):  
Bill Olson ◽  
David Ammerman ◽  
Harmut Hage

This paper discusses the design, specification, and installation of an integrally geared, 8-stage centrifugal compressor for CO2 pipeline service in North America. To the authors’ knowledge, this was the first, and remains the only, such application of this compression technology in a cross-country pipeline in North America. The facilities were installed in 1999 and became operational in 2000. Design considerations included compressing process CO2 from near atmospheric pressure to the super critical phase that allows for efficient transport of large volumes over long distances in a pipeline. In this phase, the CO2 behaves much like a liquid, but its physical properties (e.g. density and viscosity) vary much like a gas in response to temperature and pressure changes. In order to function properly in this application, the compressor must be flexible enough to compress the CO2 under varying inlet temperature and pressure conditions. Inlet guide vanes were used to regulate flow to the suction of alternating stages. The controls system for these vanes was required to closely monitor interstage conditions in order to make sure that no stage entered surge. Furthermore, the interstage coolers also required precise control to prevent overheating in summer or liquid formation in winter. Ambient design temperatures ranged from −50°F (−45°C) to +104°F (+40°C). A simplified system diagram is shown in Fig. 1. If the air-cooled heat exchangers remove too much heat, liquids will form and the subsequent compressor stage could be severely damaged. If the compressor unit, or any stage, enters surge (stalls), the machine can also be damaged. Consequently, bypass and recirculation schemes (see Fig. 1) were used to enhance safe operations. Ambient airflow to the coolers was controlled by louvers, which in turn were regulated by the compressor control system. These heat exchangers also employed recirculation plenums to permit recirculation of warm air during low ambient temperature conditions. The problem solved by the application of this technology was to efficiently compress large volumes of very low pressure CO2 into the super critical phase for pipeline transportation. The overall compression ratio across these units exceeded 180. In the past, CO2 compression for pipeline service has been accomplished by using numerous, multi-stage reciprocating compressors, over much narrower compression ratios (typically < 15).


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1047 ◽  
Author(s):  
Javier Conesa-Egea ◽  
Alberto Moreno-Vázquez ◽  
Vanesa Fernández-Moreira ◽  
Yolanda Ballesteros ◽  
Milagros Castellanos ◽  
...  

Herein is presented the preparation and characterization of a composite material obtained by the combination of nanosheets of a coordination polymer (CP) based on the copper(I)-I double chain with response to temperature and pressure with polylactic acid (PLA) as biodegradable organic matrix. The new films of composite materials are generated using a simple and low-cost method and can be created with long lateral dimensions and thicknesses ranging from a few microns to a few nanometers. Studies show that the new material maintains the optical response versus the temperature, while the elasticity and flexibility of the PLA totally quenches the response to pressure previously observed for the CP. This new material can act as a reversible sensor at low temperatures, thanks to the flexibility of the copper(I)-iodine chain that conforms the CP. The addition of CP to the PLA matrix reduces the elastic modulus and ultimate elongation of the organic matrix, although it does not reduce its tensile strength.


Author(s):  
Ronald S. Weinstein ◽  
N. Scott McNutt

The Type I simple cold block device was described by Bullivant and Ames in 1966 and represented the product of the first successful effort to simplify the equipment required to do sophisticated freeze-cleave techniques. Bullivant, Weinstein and Someda described the Type II device which is a modification of the Type I device and was developed as a collaborative effort at the Massachusetts General Hospital and the University of Auckland, New Zealand. The modifications reduced specimen contamination and provided controlled specimen warming for heat-etching of fracture faces. We have now tested the Mass. General Hospital version of the Type II device (called the “Type II-MGH device”) on a wide variety of biological specimens and have established temperature and pressure curves for routine heat-etching with the device.


Author(s):  
G.D. Danilatos

Over recent years a new type of electron microscope - the environmental scanning electron microscope (ESEM) - has been developed for the examination of specimen surfaces in the presence of gases. A detailed series of reports on the system has appeared elsewhere. A review summary of the current state and potential of the system is presented here.The gas composition, temperature and pressure can be varied in the specimen chamber of the ESEM. With air, the pressure can be up to one atmosphere (about 1000 mbar). Environments with fully saturated water vapor only at room temperature (20-30 mbar) can be easily maintained whilst liquid water or other solutions, together with uncoated specimens, can be imaged routinely during various applications.


Sign in / Sign up

Export Citation Format

Share Document