Synthesis and catalytic activities of a Zn(ii) based metallomacrocycle and a metal–organic framework towards one-pot deacetalization-Knoevenagel tandem reactions under different strategies: a comparative study

2020 ◽  
Vol 49 (24) ◽  
pp. 8075-8085 ◽  
Author(s):  
Anirban Karmakar ◽  
Mohamed M. A. Soliman ◽  
Guilherme M. D. M. Rúbio ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro

4,4′-{(Pyridine-2,6-dicarbonyl)bis(azanediyl)}dibenzoic acid is used to synthesize macrocycle and MOF which act as catalysts for tandem deacetalization-Knoevenagel condensation reactions under heating, microwave or ultrasonic irradiation.

2016 ◽  
Vol 45 (35) ◽  
pp. 13917-13924 ◽  
Author(s):  
Zongcheng Miao ◽  
Yi Luan ◽  
Chao Qi ◽  
Daniele Ramella

A novel one-pot aerobic oxidation/Knoevenagel condensation reaction system is developed employing a Cu(ii)/basic bifunctional metal–organic framework (MOF) as the catalyst.


RSC Advances ◽  
2020 ◽  
Vol 10 (58) ◽  
pp. 35206-35213
Author(s):  
Abdelaziz M. Aboraia ◽  
Viktor V. Shapovalov ◽  
Alexnader A. Guda ◽  
Vera V. Butova ◽  
Alexander Soldatov

LiCoPO4 (LCP) is a promising high voltage cathode material but suffers from low conductivity and poor electrochemical properties.


RSC Advances ◽  
2015 ◽  
Vol 5 (2) ◽  
pp. 893-900 ◽  
Author(s):  
Xiu-Chun Yi ◽  
Fu-Gui Xi ◽  
Yan Qi ◽  
En-Qing Gao

A new azido-functionalized Zr(iv) MOF was synthesized and further functionalized via post-synthetic click reactions, and the amino-tagged MOF is a base catalyst for Knoevenagel condensation.


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