scholarly journals Interconnection of organic–inorganic hybrid nano-building blocks towards thermally robust mesoporous structures

Nanoscale ◽  
2021 ◽  
Author(s):  
Naoki Tarutani ◽  
Riona Sato ◽  
Wataru Yamazaki ◽  
Kiyofumi Katagiri ◽  
Kei Inumaru ◽  
...  
Keyword(s):  
Mesoporous Materials ◽  
Building Blocks ◽  
Organic Anions ◽  
Metal Hydroxide ◽  
Inorganic Hybrid ◽  
Mesoporous Structures

The robustness of layered metal hydroxide nanocrystal-based mesoporous materials was improved by interconnecting the nanocrystals through polymerization of intercalated organic anions.

scholarly journals Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

2022 ◽  
Author(s):  
Jamie M. Cameron ◽  
Geoffroy Guillemot ◽  
Theodor Galambos ◽  
Sharad S. Amin ◽  
Elizabeth Hampson ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Supramolecular Materials ◽  
Inorganic Hybrid ◽  
Hierarchical Nanomaterials

Organic–inorganic hybrid polyoxometalates are versatile building blocks for the self-assembly of functional supramolecular materials.

Organic−Inorganic Hybrid Aligned by the Ligand−Ligand Hydrogen Bonds by Using Pyridyl-Substituted Oxalamides as the Building Blocks

2008 ◽  
Vol 8 (3) ◽  
pp. 869-876 ◽  
Author(s):  
Qingdao Zeng ◽  
Min Li ◽  
Dongxia Wu ◽  
Shengbin Lei ◽  
Caiming Liu ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Building Blocks ◽  
Inorganic Hybrid

scholarly journals Radially oriented mesoporous TiO2 microspheres with single-crystal–like anatase walls for high-efficiency optoelectronic devices

2015 ◽  
Vol 1 (4) ◽  
pp. e1500166 ◽  
Author(s):  
Yong Liu ◽  
Renchao Che ◽  
Gang Chen ◽  
Jianwei Fan ◽  
Zhenkun Sun ◽  
...  
Keyword(s):  
Single Crystal ◽  
Mesoporous Materials ◽  
High Performance ◽  
High Efficiency ◽  
Dye Sensitized Solar Cells ◽  
Building Blocks ◽  
Accessible Surface Area ◽  
Photoelectric Conversion Efficiency ◽  
Photoelectric Conversion ◽  
Assembly Method

Highly crystalline mesoporous materials with oriented configurations are in demand for high-performance energy conversion devices. We report a simple evaporation-driven oriented assembly method to synthesize three-dimensional open mesoporous TiO2 microspheres with a diameter of ~800 nm, well-controlled radially oriented hexagonal mesochannels, and crystalline anatase walls. The mesoporous TiO2 spheres have a large accessible surface area (112 m2/g), a large pore volume (0.164 cm3/g), and highly single-crystal–like anatase walls with dominant (101) exposed facets, making them ideal for conducting mesoscopic photoanode films. Dye-sensitized solar cells (DSSCs) based on the mesoporous TiO2 microspheres and commercial dye N719 have a photoelectric conversion efficiency of up to 12.1%. This evaporation-driven approach can create opportunities for tailoring the orientation of inorganic building blocks in the assembly of various mesoporous materials.

Synthesis, Structure Characterization and Photocatalytic Property of a New 3-D Polyoxovanadate-Based Organic-Inorganic Hybrid Compound

2014 ◽  
Vol 997 ◽  
pp. 260-263 ◽  
Author(s):  
Ya Bing Liu ◽  
Peng Yu
Keyword(s):  
Transition Metal ◽  
Elemental Analysis ◽  
Rhodamine B ◽  
Photocatalytic Property ◽  
Building Blocks ◽  
Structure Characterization ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
X Ray

A new polyoxovanadates-based organic-inorganic hybrid compound, [Cu(en)2]2[VV6VIV4O25] (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 consists of [Cu(en)2]2+transition metal coordination fragment and the [VV6VIV4O25]4-building blocks, which are linked together via covalently-bonding interactions to form a new 3-D networks. The degradation of rhodamine B (RhB) under UV-vis irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for RhB degradation.

Synthesis and Characterization of [Mo3S4(NDABu)(HNDABu)2]3-and [Mo3S4(HNDAPr)3]2-Anions as Building Blocks for Organic-Inorganic Hybrid Solids

2012 ◽  
Vol 2013 (7) ◽  
pp. 1149-1156 ◽  
Author(s):  
Sylvain Duval ◽  
Frédéric Dumur ◽  
Laure Guénée ◽  
Jérôme Marrot ◽  
Corine Simonnet-Jégat ◽  
...  
Keyword(s):  
Building Blocks ◽  
Synthesis And Characterization ◽  
Inorganic Hybrid ◽  
Hybrid Solids

scholarly journals Reuse Feasibility of Electrocoagulated Metal Hydroxide Sludge of Textile Industry in the Manufacturing of Building Blocks

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Tanveer Mehedi Adyel ◽  
Syed Hafizur Rahman ◽  
Mohammad Moniruz Zaman ◽  
Hossain Md. Sayem ◽  
Mala Khan ◽  
...  
Keyword(s):  
Firing Temperature ◽  
Textile Industry ◽  
Water Adsorption ◽  
Construction Material ◽  
Building Blocks ◽  
Metal Hydroxide ◽  
Key Factors ◽  
Foreign Exchange Earning ◽  
Textile Industries

During the last decade, the growing load of sludge from textile industries, the top foreign exchange earning sector of Bangladesh, is a common nuisance to environmental system and community health. The present study was aimed to minimize the environmental impact from the disposal of Electrocoagulated Metal Hydroxide Sludge (EMHS) by using it as a partial substitute of clay in the manufacturing of construction material like building blocks (BBs). Different batches of normal and pressurized building blocks (NBBs and PBBs, resp.) were prepared using up to 50% EMHS with clay and then fired at a particular temperature. EMHS proportion in the mixture and firing temperature were two key factors determining the quality of BB. BB did not show any deformation or uneven surfaces at any of the examined firing temperature. At higher firing temperature and EMHS proportion, more weight loss and shrinkage of BB were noticed. Higher compressive strength and lower water adsorption were found at lower EMHS content and higher firing temperature. It was explored that NBB and PBB with 20 and 30% EMHS in clay, respectively, and fired at 1050 °C would be usable for nonloading applications; namely, ornamental bricks, decoration purposes, and fence of garden.

scholarly journals Hybrid organic–inorganic catalytic mesoporous materials with proton sponges as building blocks

2011 ◽  
Vol 13 (24) ◽  
pp. 11702 ◽  
Author(s):  
Enrica Gianotti ◽  
Urbano Diaz ◽  
Salvatore Coluccia ◽  
Avelino Corma
Keyword(s):  
Mesoporous Materials ◽  
Building Blocks ◽  
Proton Sponges
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