Using the dynamic behavior of macrocyclic monomers with a bis(hindered amino)disulfide linker for the preparation of end-functionalized polymers

2020 ◽  
Vol 11 (21) ◽  
pp. 3557-3563 ◽  
Author(s):  
Hirogi Yokochi ◽  
Rikito Takashima ◽  
Daisuke Aoki ◽  
Hideyuki Otsuka

End-functionalized polymers were synthesized by simply heating a mixture of a macrocyclic compound with one bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS) moiety and bifunctional acyclic BiTEMPS compounds as sources of repeat units and terminal groups, respectively.

2020 ◽  
Vol 21 (6) ◽  
pp. 619
Author(s):  
Kostandin Gjika ◽  
Antoine Costeux ◽  
Gerry LaRue ◽  
John Wilson

Today's modern internal combustion engines are increasingly focused on downsizing, high fuel efficiency and low emissions, which requires appropriate design and technology of turbocharger bearing systems. Automotive turbochargers operate faster and with strong engine excitation; vibration management is becoming a challenge and manufacturers are increasingly focusing on the design of low vibration and high-performance balancing technology. This paper discusses the synchronous vibration management of the ball bearing cartridge turbocharger on high-speed balancer and it is a continuation of papers [1–3]. In a first step, the synchronous rotordynamics behavior is identified. A prediction code is developed to calculate the static and dynamic performance of “ball bearing cartridge-squeeze film damper”. The dynamic behavior of balls is modeled by a spring with stiffness calculated from Tedric Harris formulas and the damping is considered null. The squeeze film damper model is derived from the Osborne Reynolds equation for incompressible and synchronous fluid loading; the stiffness and damping coefficients are calculated assuming that the bearing is infinitely short, and the oil film pressure is modeled as a cavitated π film model. The stiffness and damping coefficients are integrated on a rotordynamics code and the bearing loads are calculated by converging with the bearing eccentricity ratio. In a second step, a finite element structural dynamics model is built for the system “turbocharger housing-high speed balancer fixture” and validated by experimental frequency response functions. In the last step, the rotating dynamic bearing loads on the squeeze film damper are coupled with transfer functions and the vibration on the housings is predicted. The vibration response under single and multi-plane unbalances correlates very well with test data from turbocharger unbalance masters. The prediction model allows a thorough understanding of ball bearing turbocharger vibration on a high speed balancer, thus optimizing the dynamic behavior of the “turbocharger-high speed balancer” structural system for better rotordynamics performance identification and selection of the appropriate balancing process at the development stage of the turbocharger.


2006 ◽  
Vol 12 (4) ◽  
pp. 33-37
Author(s):  
V.E. Shatikhin ◽  
◽  
L.P. Semenov ◽  
V.S. Khoroshylov ◽  
V.M. Popel' ◽  
...  
Keyword(s):  

Author(s):  
Yuichi Niibori ◽  
Yasunori Kasuga ◽  
Hiroshi Kokubun ◽  
Kazuki Iijima ◽  
Hitoshi Mimura

2003 ◽  
Vol 775 ◽  
Author(s):  
Sung-Hwa Oh ◽  
Ju-Myung Song ◽  
Joon-Seop Kim ◽  
Hyang-Rim Oh ◽  
Jeong-A Yu

AbstractSolution behaviors of poly(styrene-co-sodium methacrylate) were studied by fluorescence spectroscopic methods using pyrene as a probe. The mol% of methacrylate was in the range 3.6–9.4. Water and N,N-dimethylforamide(DMF) mixture was used as a solvent (DMF/water = 0.2 mol %). The critical micelle (or aggregation) concentrations of ionomers and the partition coefficients of pyrene were obtained the temperature range 10–80°C. At room temperature, the values of CMCs (or CACs) were in the range 4.7 ×10-6 5.3 ×10-6 g/mL and we could not find any notable effect of the content of ionic repeat units within the experimental errors. Unlike CMCs, as the ion content increased, partitioning of pyrene between the hydrophobic aggregates and an aqueous media decreased from 1.5 ×105 to 9.4 ×104. As the temperature increased from 10 to 80 °C, the values of CMCs increased less than one order of magnitude. While, the partition coefficients of pyrene decreased one order of magnitude and the effect of the ion content became negligible.


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