scholarly journals Opportunities and critical factors of porous metal–organic frameworks for industrial light olefins separation

2020 ◽  
Vol 4 (7) ◽  
pp. 1954-1984 ◽  
Author(s):  
Tianhao Lan ◽  
Libo Li ◽  
Yang Chen ◽  
Xiaoqing Wang ◽  
Jiangfeng Yang ◽  
...  
Keyword(s):  
Real World ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Light Olefins ◽  
Critical Factors ◽  
Recent Advances ◽  
Real World Applications ◽  
Metal Organic ◽  
Key Features ◽  
Made In

We summarize and highlight recent advances in the realm of light olefins separation using MOFs as adsorbents, covering the progress made in improving the key features of MOFs that are necessary for their real-world applications.

Computational exploration of newly synthesized zirconium metal–organic frameworks UiO-66, -67, -68 and analogues

2014 ◽  
Vol 2 (34) ◽  
pp. 7111-7125 ◽  
Author(s):  
Li-Ming Yang ◽  
Eric Ganz ◽  
Stian Svelle ◽  
Mats Tilset
Keyword(s):  
Chemical Stability ◽  
Real World ◽  
Metal Organic Frameworks ◽  
Real World Applications ◽  
Acid And Base ◽  
Computational Exploration ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Thermal And Chemical Stability

Metal–organic frameworks UiO-66, -67, -68 and analogues have exceptional thermal and chemical stability, are resistant to water, acid, and base for use in real-world applications.

scholarly journals Recent advances in the synthesis of nanoscale hierarchically porous metal–organic frameworks

2022 ◽  
Author(s):  
Chongxiong Duan ◽  
Kuan Liang ◽  
Zena Zhang ◽  
Jingjing Li ◽  
Ting Chen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Hierarchically Porous ◽  
Recent Advances ◽  
Metal Organic

Supramolecular templating of hierarchically porous metal–organic frameworks

2014 ◽  
Vol 43 (16) ◽  
pp. 5431-5443 ◽  
Author(s):  
Darren Bradshaw ◽  
Samir El-Hankari ◽  
Lucia Lupica-Spagnolo
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Hierarchically Porous ◽  
Hierarchical Porosity ◽  
Recent Advances ◽  
Soft Templating ◽  
Metal Organic

This tutorial review summarises recent advances in the soft templating of metal–organic frameworks with hierarchical porosity across the micro- and mesoporous regimes.

Critical factors influencing the structures and properties of metal–organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (5) ◽  
pp. 981-991 ◽  
Author(s):  
Kang Shen ◽  
Mingdao Zhang ◽  
Hegen Zheng
Keyword(s):  
Metal Organic Frameworks ◽  
Critical Factors ◽  
Factors Influencing ◽  
Recent Advances ◽  
Structures And Properties ◽  
Metal Organic

This article highlights the recent advances in the different factors influencing the structures of MOFs.

scholarly journals Synthesis of Metal Organic Frameworks by Ball-Milling

Crystals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 15
Author(s):  
Cheng-An Tao ◽  
Jian-Fang Wang
Keyword(s):  
Ball Milling ◽  
Large Scale ◽  
Raw Materials ◽  
Metal Organic Frameworks ◽  
Research Topic ◽  
Mass Ratio ◽  
Time Consumption ◽  
Metal Organic ◽  
Short Time ◽  
Made In

Metal-organic frameworks (MOFs) have been used in adsorption, separation, catalysis, sensing, photo/electro/magnetics, and biomedical fields because of their unique periodic pore structure and excellent properties and have become a hot research topic in recent years. Ball milling is a method of small pollution, short time-consumption, and large-scale synthesis of MOFs. In recent years, many important advances have been made. In this paper, the influencing factors of MOFs synthesized by grinding were reviewed systematically from four aspects: auxiliary additives, metal sources, organic linkers, and reaction specific conditions (such as frequency, reaction time, and mass ratio of ball and raw materials). The prospect for the future development of the synthesis of MOFs by grinding was proposed.

Recent advances on thermal energy storage using metal-organic frameworks (MOFs)

2021 ◽  
Vol 34 ◽  
pp. 102179
Author(s):  
Nokubonga Makhanya ◽  
Bilainu Oboirien ◽  
Jianwei Ren ◽  
Nicholas Musyoka ◽  
Adriano Sciacovelli
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Metal Organic Frameworks ◽  
Recent Advances ◽  
Metal Organic

scholarly journals Degradation Mechanism of Porous Metal-Organic Frameworks by In Situ Atomic Force Microscopy

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 722
Author(s):  
Ioanna Christodoulou ◽  
Tom Bourguignon ◽  
Xue Li ◽  
Gilles Patriarche ◽  
Christian Serre ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Degradation Mechanism ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Force Microscopy ◽  
Atomic Force ◽  
Metal Organic ◽  
The Media ◽  
Ph Conditions

In recent years, Metal-Organic Frameworks (MOFs) have attracted a growing interest for biomedical applications. The design of MOFs should take into consideration the subtle balance between stability and biodegradability. However, only few studies have focused on the MOFs’ stability in physiological media and their degradation mechanism. Here, we investigate the degradation of mesoporous iron (III) carboxylate MOFs, which are among the most employed MOFs for drug delivery, by a set of complementary methods. In situ AFM allowed monitoring with nanoscale resolution the morphological, dimensional, and mechanical properties of a series of MOFs in phosphate buffer saline and in real time. Depending on the synthetic route, the external surface presented either well-defined crystalline planes or initial defects, which influenced the degradation mechanism of the particles. Moreover, MOF stability was investigated under different pH conditions, from acidic to neutral. Interestingly, despite pronounced erosion, especially at neutral pH, the dimensions of the crystals were unchanged. It was revealed that the external surfaces of MOF crystals rapidly respond to in situ changes of the composition of the media they are in contact with. These observations are of a crucial importance for the design of nanosized MOFs for drug delivery applications.

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