scholarly journals Assessment of ampicillin removal efficiency from aqueous solution by polydopamine/zirconium(iv) iodate: optimization by response surface methodology

RSC Advances ◽  
2020 ◽  
Vol 10 (34) ◽  
pp. 20322-20337 ◽  
Author(s):  
Nafisur Rahman ◽  
Poornima Varshney

Polydopamine/zirconium(iv) iodate was prepared by incorporating polydopamine into zirconium iodate gel and studied as an effective adsorbent for ampicillin.

2015 ◽  
Vol 17 (2) ◽  
pp. 379-388 ◽  

<div> <p>Nitrate is a common groundwater pollutant all over the world. In some regions of Iran, its levels are high enough to cause serious problems to human health and the environment<span dir="RTL">.</span> The objectives of this work were to evaluate the efficiency of Fe-doped TiO<sub>2</sub> nanoparticles at removing nitrate from aqueous solutions under UV and solar radiation and to model nitrate removal using response surface methodology techniques. In this study, a response surface methodology based on the Box&ndash;Behnken design matrix was used to describe the process of nitrate removal from an aqueous solution with four independent parameters, namely Fe-doped TiO<sub>2</sub> (dose 1-2 g l<sup>-1</sup>), nitrate concentration (25-100 mg l<sup>-1</sup>), contact time (10-120 min), and pH (4-9). The results indicated that the removal efficiency of nitrate in the presence of ultraviolet and solar radiation was 56.5 % and 21.8%, respectively. The removal efficiency of nitrate increased with time and initial concentration of nitrate. Analysis of variance (ANOVA) indicated that the proposed model was essentially in accordance with the experimental results with the correlation coefficient R<sup>2 </sup>= 0.9237 and Adj-R<sup>2</sup> = 0.8347. Response surface methodology (RSM) proved to be a powerful statistical tool for investigating the operating conditions for nitrate removal under UV irradiation.</p> </div> <p>&nbsp;</p>


2020 ◽  
Vol 14 (2) ◽  
pp. 1 ◽  
Author(s):  
Ali Jawad ◽  
Mohd shafiq Bin Aazmi ◽  
Ali Jawad

Response surface methodology-Box–Behnken design (RSM-BBD) was employed to optimize the methyl orange (MO) dye removal efficiency from aqueous solution by cross-linked chitosan-tripolyphosphate/nano-titania composite (Chi-TPP/NTC). The influence of pertinent parameters, i.e. A: TiO2 loading (0- 50 %), B: dose (0.04-0.14 g), C: pH (4-10), and D: temperature (30-50 oC) on the MO removal efficiency were tested and optimized using RSM-BBD. The F-values of BBD model for MO removal efficiency was 93.4 (corresponding p-value < 0.0001). The results illustrated that the highest MO removal efficiency (87.27 %) was observed at the following conditions: TiO2 loading (50% TiO2), dose (0.09 g), pH 4.0, and temperature of 40 oC.  


2021 ◽  
Vol 45 (14) ◽  
pp. 6192-6205
Author(s):  
Haiqing Xu ◽  
Yuhang Gao ◽  
Qiantu Tao ◽  
Aiping Li ◽  
Zhanchao Liu ◽  
...  

The molecularly imprinted polymer prepared on the nanoreactor SBA-15 displayed excellent ordered mesoporous structure and superior adsorption property for salicylic acid.


2017 ◽  
Vol 76 (4) ◽  
pp. 776-784 ◽  
Author(s):  
Mijia Zhu ◽  
Jun Yao ◽  
Zhonghai Qin ◽  
Luning Lian ◽  
Chi Zhang

Wastewater produced from polymer flooding in oil production features high viscosity and chemical oxygen demand because of the residue of high-concentration polymer hydrolysed polyacrylamide (HPAM). In this study, steel slag, a waste from steel manufacturing, was studied as a low-cost adsorbent for HPAM in wastewater. Optimisation of HPAM adsorption by steel slag was performed with a central composite design under response surface methodology (RSM). Results showed that the maximum removal efficiency of 89.31% was obtained at an adsorbent dosage of 105.2 g/L, contact time of 95.4 min and pH of 5.6. These data were strongly correlated with the experimental values of the RSM model. Single and interactive effect analysis showed that HPAM removal efficiency increased with increasing adsorbent dosage and contact time. Efficiency increased when pH was increased from 2.6 to 5.6 and subsequently decreased from 5.6 to 9.3. It was observed that removal efficiency significantly increased (from 0% to 86.1%) at the initial stage (from 0 min to 60 min) and increased gradually after 60 min with an adsorbent dosage of 105.2 g/L, pH of 5.6. The adsorption kinetics was well correlated with the pseudo-second-order equation. Removal of HPAM from the studied water samples indicated that steel slag can be utilised for the pre-treatment of polymer-flooding wastewater.


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