Achieving high energy density and discharge efficiency in multi-layered PVDF–PMMA nanocomposites composed of 0D BaTiO3 and 1D NaNbO3@SiO2

2020 ◽  
Vol 8 (21) ◽  
pp. 7211-7220 ◽  
Author(s):  
Qinzhao Sun ◽  
Jiping Wang ◽  
Lixue Zhang ◽  
Pu Mao ◽  
Shujuan Liu ◽  
...  

The choice of dielectric fillers and structure design play an important role in improving the energy storage properties of polymer-based nanocomposites.

2019 ◽  
Vol 7 (5) ◽  
pp. 2225-2232 ◽  
Author(s):  
Jing Gao ◽  
Yichi Zhang ◽  
Lei Zhao ◽  
Kai-Yang Lee ◽  
Qing Liu ◽  
...  

High energy density was achieved in lead-free La-doped AgNbO3 antiferroelectric ceramics.


2017 ◽  
Vol 5 (37) ◽  
pp. 9552-9558 ◽  
Author(s):  
Qibin Yuan ◽  
Fangzhou Yao ◽  
Yifei Wang ◽  
Rong Ma ◽  
Hong Wang

A relaxor ferroelectric ceramic for high energy storage applications based on 0.9BaTiO3–0.1Bi(Zn0.5Zr0.5)O3(0.9BT–0.1BZZ) was successfully fabricatedviaa conventional solid-state method.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5742
Author(s):  
Vignaswaran Veerapandiyan ◽  
Federica Benes ◽  
Theresa Gindel ◽  
Marco Deluca

Electrical energy storage systems (EESSs) with high energy density and power density are essential for the effective miniaturization of future electronic devices. Among different EESSs available in the market, dielectric capacitors relying on swift electronic and ionic polarization-based mechanisms to store and deliver energy already demonstrate high power densities. However, different intrinsic and extrinsic contributions to energy dissipations prevent ceramic-based dielectric capacitors from reaching high recoverable energy density levels. Interestingly, relaxor ferroelectric-based dielectric capacitors, because of their low remnant polarization, show relatively high energy density and thus display great potential for applications requiring high energy density properties. In this study, some of the main strategies to improve the energy density properties of perovskite lead-free relaxor systems are reviewed, including (i) chemical modification at different crystallographic sites, (ii) chemical additives that do not target lattice sites, and (iii) novel processing approaches dedicated to bulk ceramics, thick and thin films, respectively. Recent advancements are summarized concerning the search for relaxor materials with superior energy density properties and the appropriate choice of both composition and processing routes to match various applications’ needs. Finally, future trends in computationally-aided materials design are presented.


2021 ◽  
Author(s):  
Li Xiali ◽  
Liuwei Shi ◽  
Lei Chen ◽  
Wenyao Yang ◽  
Xiaoting Zha ◽  
...  

Abstract Ceramic/polymer nanocomposites have shown great potential in high energy storage density capacitors for pulsed power applications. However, due to the difference in surface energy between inorganic fillers and polymers, the discharge energy density and efficiency of nanocomposites are limited. In this article, the BaTiO3 (BT) nanowires (nws) modified with dopamine (Dopa) was introduced into aromatic polythiourea (ArPTU) polymer matrix as composite for high performance dielectrics. This is a new path about the introduction of a high dielectric constant ceramic into high dipole moment linear polymers (HDMLP), which produces the polymer composite with high energy storage density and high discharge efficiency. The composite ArPTU/BT nws shows an energy density of 7.5 Jžcm-3 and high efficiency more than 90 % is obtained under an electric field of 250 MVžm-1. It also has been found that the modification of BT nws with the dopamine reduces the dielectric loss of composite effectively due to the good synergistic effective between ArPTU and BT nws, and high stability of composite for energy storage is also achieved. This work provides an effective solution for achieving high energy storage density and high discharge efficiency in polymer dielectrics for practical capacitor applications.


2014 ◽  
Vol 602-603 ◽  
pp. 916-920
Author(s):  
Qian Zhang ◽  
Yong Zhang ◽  
Xiao Lin Liu ◽  
Xiao Zhen Song ◽  
Jia Zhu

The effect of Zr/Sn ratio on the dielectric and energy storage properties of lanthanum modified lead zirconate stannate titanate (PLZST) ceramics with compositions located near the boundary between antiferroelectric and ferroelectric phases was studied. Microstructural observation indicated that all the samples had a uniform morphology with pure perovskite phase and the average grain size reduced obviously with increasing Zr/Sn ratio. As the Zr/Sn ratio increased, the dielectric constant increased and the transition temperature Tm shifted to higher temperature. All the PLZST ceramics exhibited double hysteresis loops. The maximum polarization increased, while the switching field decreased when the Zr/Sn ratio increased. The variations of Zr/Sn ratio had little impact on remanent polarization. As a result, both charged energy density and discharged energy density increased with increasing Zr/Sn ratio. A high energy storage density of 1.75 J/cm3 was achieved in the PLZST ceramics with the Zr/Sn ratio of 82.5/7.5 at 9 kV/mm.


RSC Advances ◽  
2019 ◽  
Vol 9 (14) ◽  
pp. 7706-7717 ◽  
Author(s):  
Shuangshuang Yue ◽  
Baoquan Wan ◽  
Yunying Liu ◽  
Qiwei Zhang

The semiconductor properties of reduced barium titanate, with a high energy density of 9.7 J cm−3.


Author(s):  
Zhiqiang Luo ◽  
Silin Zheng ◽  
Shuo Zhao ◽  
Xin Jiao ◽  
Zongshuai Gong ◽  
...  

Benzoquinone with high theoretical capacity is anchored on N-plasma engraved porous carbon as a desirable cathode for rechargeable aqueous Zn-ion batteries. Such batteries display tremendous potential in large-scale energy storage applications.


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