2D Auxetic Material with Intrinsic Ferromagnetism: Copper Halide (CuCl2) Monolayer

Author(s):  
Haifei Qin ◽  
Jiao Chen ◽  
Bai Sun ◽  
Yongliang Tang ◽  
Yuxiang Ni ◽  
...  

The discovery of ferromagnetism in monolayer transition metal halides exemplified by CrI3 has opened a new venue in the field of two-dimensional (2D) magnetic materials, and more such 2D materials...

Author(s):  
Sai Manoj Gali ◽  
David Beljonne

Transition Metal Dichalcogenides (TMDCs) are emerging as promising two-dimensional (2D) materials. Yet, TMDCs are prone to inherent defects such as chalcogen vacancies, which are detrimental to charge transport. Passivation of...


Nanoscale ◽  
2021 ◽  
Author(s):  
Shiyao Wang ◽  
Nanxi Miao ◽  
Kehe Su ◽  
Vladislav A. Blatov ◽  
Junjie Wang

Intrinsic two-dimensional (2-D) magnets are promising materials for developing advanced spintronic devices. Few have already been synthesized from the exfoliation of the van der Waals magnetic materials. In this work,...


Author(s):  
Shiyao Wang ◽  
Mohammad Khazaei ◽  
Junjie Wang ◽  
Hideo Hosono

Two-dimensional (2-D) magnetic materials are promising to be ideal platforms for constructing novel spintronic devices. Until to now, most 2-D magnetic materials have mainly been achieved by the exfoliation of...


2019 ◽  
Vol 116 (42) ◽  
pp. 20844-20849 ◽  
Author(s):  
Cong Su ◽  
Zongyou Yin ◽  
Qing-Bo Yan ◽  
Zegao Wang ◽  
Hongtao Lin ◽  
...  

Two-dimensional van der Waals materials have rich and unique functional properties, but many are susceptible to corrosion under ambient conditions. Here we show that linear alkylamines n-CmH2m+1NH2, with m = 4 through 11, are highly effective in protecting the optoelectronic properties of these materials, such as black phosphorus (BP) and transition-metal dichalcogenides (TMDs: WS2, 1T′-MoTe2, WTe2, WSe2, TaS2, and NbSe2). As a representative example, n-hexylamine (m = 6) can be applied in the form of thin molecular monolayers on BP flakes with less than 2-nm thickness and can prolong BP’s lifetime from a few hours to several weeks and even months in ambient environments. Characterizations combined with our theoretical analysis show that the thin monolayers selectively sift out water molecules, forming a drying layer to achieve the passivation of the protected 2D materials. The monolayer coating is also stable in air, H2 annealing, and organic solvents, but can be removed by certain organic acids.


Nanoscale ◽  
2021 ◽  
Author(s):  
Zihao He ◽  
Xingyao Gao ◽  
Di Zhang ◽  
Ping Lu ◽  
Xuejing Wang ◽  
...  

Two-dimensional (2D) materials with robust ferromagnetic behavior have attracted great interest because of their potential applications in next-generation nanoelectronic devices. Aside from graphene and transition metal dichalcogenides, Bi-based layered oxide...


2020 ◽  
Vol 6 (1) ◽  
Author(s):  
Jinbo Pan ◽  
Yan-Fang Zhang ◽  
Jingda Zhang ◽  
Huta Banjade ◽  
Jie Yu ◽  
...  

Abstract Auxetic two-dimensional (2D) materials provide a promising platform for biomedicine, sensors, and many other applications at the nanoscale. In this work, utilizing a hypothesis-based data-driven approache, we identify multiple materials with remarkable in-plane auxetic behavior in a family of buckled monolayer 2D materials. These materials are transition metal selenides and transition metal halides with the stoichiometry MX (M = V, Cr, Mn, Fe, Co, Cu, Zn, Ag, and X = Se, Cl, Br, I). First-principles calculations reveal that the desirable auxetic behavior of these 2D compounds originates from the interplay between the buckled 2D structure and the weak metal–metal interaction determined by their electronic structures. We observe that the Poisson’s ratio is sensitive to magnetic order and the amount of uniaxial stress applied. A transition from positive Poisson’s ratio (PPR) to negative Poisson’s ratio (NPR) for a subgroup of MX compounds under large uniaxial stress is predicted. The work provides a guideline for the future design of 2D auxetic materials at the nanoscale.


Nanoscale ◽  
2018 ◽  
Vol 10 (47) ◽  
pp. 22429-22438 ◽  
Author(s):  
Yeoheung Yoon ◽  
Thi Anh Le ◽  
Anand P. Tiwari ◽  
Ikjoon Kim ◽  
Michel W. Barsoum ◽  
...  

MXenes – two dimensional, 2D, early transition metal, M, carbides and nitrides, X – are the latest addition to the 2D materials’ world.


2021 ◽  
Author(s):  
Mubashir A. Kharadi ◽  
Gul Faroz A. Malik ◽  
Farooq A. Khanday

2D materials like transition metal dichalcogenides, black phosphorous, silicene, graphene are at the forefront of being the most potent 2D materials for optoelectronic applications because of their exceptional properties. Several application-specific photodetectors based on 2D materials have been designed and manufactured due to a wide range and layer-dependent bandgaps. Different 2D materials stacked together give rise to many surprising electronic and optoelectronic phenomena of the junctions based on 2D materials. This has resulted in a lot of popularity of 2D heterostructures as compared to the original 2D materials. This chapter presents the progress of optoelectronic devices (photodetectors) based on 2D materials and their heterostructures.


2018 ◽  
Vol 6 (22) ◽  
pp. 10226-10232 ◽  
Author(s):  
Yangfan Shao ◽  
Mengmeng Shao ◽  
Yoshiyuki Kawazoe ◽  
Xingqiang Shi ◽  
Hui Pan

The development of two-dimensional (2D) materials with high conductivity and catalytic activity is important for the proposed hydrogen economy.


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