Transport properties of nitrile and carbonate solutions of [P66614][NTf2] ionic liquid, its thermal degradation and non-isothermal kinetics of decomposition

The electrical conductivity, density and diffusion coefficients of trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)amide ([P66614][NTf2]) ionic liquid and its binary solutions in acetonitrile, propionitrile, dimethyl and diethyl carbonates were measured in the temperature range...

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Non-isothermal kinetics of decomposition of AlNH4(SO4)2 · 12H2O by EGA-MS

Thermochimica Acta ◽

10.1016/0040-6031(96)02986-3 ◽

1996 ◽

Vol 287 (1) ◽

pp. 13-23 ◽

Cited By ~ 11

Author(s):

M. Kamruddin ◽

P.K. Ajikumar ◽

S. Dash ◽

R. Krishnan ◽

A.K. Tyagi ◽

...

Keyword(s):

Isothermal Kinetics ◽

Kinetics Of Decomposition ◽

Kinetics Of

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Non-isothermal kinetics of thermal degradation of chitin

Journal of Thermal Analysis and Calorimetry ◽

10.1007/s10973-012-2359-6 ◽

2012 ◽

Vol 111 (1) ◽

pp. 763-771 ◽

Cited By ~ 50

Author(s):

Velyana Georgieva ◽

Dilyana Zvezdova ◽

Lyubomir Vlaev

Keyword(s):

Thermal Degradation ◽

Isothermal Kinetics ◽

Kinetics Of

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Nitridation Isothermal Kinetics of In Situ β-Sialon Bonded Al2O3-C Refractories

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.697.572 ◽

2016 ◽

Vol 697 ◽

pp. 572-575

Author(s):

Xue Qing Yang ◽

Nai Peng ◽

Cheng Ji Deng

Keyword(s):

Activation Energy ◽

Apparent Activation Energy ◽

Isothermal Kinetics ◽

Nitridation Reaction ◽

Result Show ◽

Different Temperatures ◽

Two Stages ◽

Kinetics Of ◽

And Diffusion

The kinetics of in-situ β- Sialon bonded Al2O3-C (SAC) refractories were investigated by TGA techniques via isothermal nitridation experiments at different temperatures. The result show that the nitridation process of in-situ β-Sialon bonded Al2O3-C refractories can be divided into two stages: the nitridation reaction rate controlling stage in the first 10 min, and the apparent activation energy of nitridation reaction is 370 kJ/mol ; then the reaction is controlled by both chemical reaction and diffusion rate in the following 110 min, the apparent activation energy of nitridation reaction is 410 kJ/mol.

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A comparative study of non-isothermal kinetics of decomposition of calcium oxalate monohydrate

Journal of Analytical and Applied Pyrolysis ◽

10.1016/j.jaap.2007.12.003 ◽

2008 ◽

Vol 81 (2) ◽

pp. 253-262 ◽

Cited By ~ 200

Author(s):

L. Vlaev ◽

N. Nedelchev ◽

K. Gyurova ◽

M. Zagorcheva

Keyword(s):

Comparative Study ◽

Calcium Oxalate ◽

Calcium Oxalate Monohydrate ◽

Isothermal Kinetics ◽

Kinetics Of Decomposition ◽

Kinetics Of

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Study on the non-isothermal kinetics of decomposition of 4Na2SO4·2H2O2·NaCl

Journal of Thermal Analysis and Calorimetry ◽

10.1007/s10973-005-7127-4 ◽

2007 ◽

Vol 89 (2) ◽

pp. 531-536 ◽

Cited By ~ 7

Author(s):

Z. Hong-Kun ◽

T. Cao ◽

Zh. Dao-Sen ◽

X. Wen-Lin ◽

W. Ya-Qong ◽

...

Keyword(s):

Isothermal Kinetics ◽

Kinetics Of Decomposition ◽

Kinetics Of

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Effect of CO2 dissolution on electrical conductivity and self-diffusion coefficients of 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid

Fluid Phase Equilibria ◽

10.1016/j.fluid.2013.05.023 ◽

2013 ◽

Vol 357 ◽

pp. 76-79 ◽

Cited By ~ 7

Author(s):

Tatsuya Umecky ◽

Mitsuhiro Kanakubo ◽

Takashi Makino ◽

Takafumi Aizawa ◽

Akira Suzuki

Keyword(s):

Electrical Conductivity ◽

Ionic Liquid ◽

Diffusion Coefficients ◽

Self Diffusion

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Oxygen Exchange and Diffusion Coefficients of Strontium‐Doped Lanthanum Ferrites by Electrical Conductivity Relaxation

Journal of The Electrochemical Society ◽

10.1149/1.1837531 ◽

1997 ◽

Vol 144 (3) ◽

pp. 1060-1067 ◽

Cited By ~ 167

Author(s):

J. E. ten Elshof ◽

M. H. R. Lankhorst ◽

H. J. M. Bouwmeester

Keyword(s):

Electrical Conductivity ◽

Diffusion Coefficients ◽

Oxygen Exchange ◽

Conductivity Relaxation ◽

Electrical Conductivity Relaxation ◽

And Diffusion

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CO2 decomposition kinetics of YBa2Cu3O7−x via in situ electrical conductivity measurements

Journal of Materials Research ◽

10.1557/jmr.1991.1393 ◽

1991 ◽

Vol 6 (7) ◽

pp. 1393-1397 ◽

Cited By ~ 7

Author(s):

E.A. Cooper ◽

A.K. Gangopadhyay ◽

T.O. Mason ◽

U. Balachandran

Keyword(s):

Electrical Conductivity ◽

Volume Fraction ◽

Conductivity Measurements ◽

Impedance Measurements ◽

Kinetics Of Decomposition ◽

Rapid Formation ◽

Kinetics Of ◽

Gradual Decay ◽

Co2 Decomposition

In situ electrical conductivity measurements were employed to study the kinetics of decomposition of YBa2Cu3O7−x in flowing 5% CO2/95% O2 atmosphere at 815 °C. Three regimes could be observed in the decay of the conductivity with time, interpreted as corresponding to nucleation over the initial 5–10 min, rapid formation of Y2Cu2O5, BaCO3, and CuO between 10 min and 1 h, and finally transition to the formation of Y2BaCuO5, BaCO3, and CuO at longer times. The absence of dispersion in impedance measurements as a function of frequency together with the gradual decay of conductivity (roughly corresponding to the remaining volume fraction of YBa2Cu3O7−x) indicates that not all grain boundaries are involved in the decomposition process.

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